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Synthesis and crystal structure of [Na2(μ-H2O)(H2O)CB[5]]Cl2 · 6H2O, [Na3(μ-H2O)4(H2O)4(CNPy@CB[6])]Cl3 · 8H2O, and [Rb2(μ-H2O)2(CNPy@CB[6])]Cl · 8H2O

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Abstract

The chain coordination polymers [Na2(μ-H2O)(H2O)CB[5]]Cl2 · 6H2O (I), [Na3(μ-H2O)4(H2O)4(CNPy@CB[6])]Cl3 · 8H2O (II), and [Rb2(μ-H2O)2(CNPy@CB[6])]Cl2 · 8H2O (III) were prepared by heating (110°C) of a mixture of sodium or rubidium chloride, cucurbit[n]uril (CB[n], where n = 5, 6), 4-cyanopyridine, and water. According to X-ray diffraction data, binding of polynuclear cations with CB[n] in I–III occurs through coordination of the oxygen atoms of the cucurbit[n]uril portals to alkali metal atoms. Complexes I–III of the above composition isolated to the solid phase as supramolecular compounds with CB[n] were structurally characterized for the first time.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. akademika Lavrent’eva 3, Novosibirsk, 630090, Russia

    E. A. Kovalenko, D. Yu. Naumov & V. P. Fedin

  2. Fakultät für Chemie, Universität Bielefeld, Bielefeld, Germany

    A. Müller

Authors
  1. E. A. Kovalenko
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  2. D. Yu. Naumov
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  3. V. P. Fedin
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  4. A. Müller
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Correspondence to V. P. Fedin.

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Dedicated to Professor Vladimir Fedorov on the occasion of his 75th birthday

Original Russian Text © E.A. Kovalenko, D.Yu. Naumov, V.P. Fedin, A. Müller, 2012, published in Koordinatsionnaya Khimiya, 2012, Vol. 38, No. 3, pp. 165–170.

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Kovalenko, E.A., Naumov, D.Y., Fedin, V.P. et al. Synthesis and crystal structure of [Na2(μ-H2O)(H2O)CB[5]]Cl2 · 6H2O, [Na3(μ-H2O)4(H2O)4(CNPy@CB[6])]Cl3 · 8H2O, and [Rb2(μ-H2O)2(CNPy@CB[6])]Cl · 8H2O. Russ J Coord Chem 38, 153–158 (2012). https://doi.org/10.1134/S1070328412020054

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  • DOI: https://doi.org/10.1134/S1070328412020054

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