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Structure and magnetic properties of the copper(II) complexes with diacyl hydrazides of salicylic acid

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Abstract

The structures and results of the static magnetic susceptibility investigation of the copper(II) binuclear complex with salicylic acid diacyl hydrazide (H2L), [Cu2(L)(Py)4] (I), and the copper(II) trinuclear complex with diacyl dihydrazide of salicylic and glutaric acids (H6L′), [Cu3(L′)(Py)4] · 2Py (II), are described. The exchange antiferromagnetic interactions between the paramagnetic centers with the exchange interaction parameter −2J = 119 cm−1 for dimer I and 14 cm−1 for trinuclear complex II are detected.

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Authors and Affiliations

  1. Taurida National V.I. Vernadsky University, akad. Vernadsky ave., 4, Simferopol, Ukraine

    V. F. Shul’gin, E. A. Sarnit & O. V. Konnik

  2. Institute of Organic Chemistry, National Academy of Sciences of Ukraine, ul. Murmanskaya 5, Kiev, 02660, Ukraine

    E. B. Rusanov

  3. Institute “International Tomography Center,” Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    A. S. Bogomyakov & V. I. Ovcharenko

  4. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    V. V. Minin

Authors
  1. V. F. Shul’gin
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  2. E. A. Sarnit
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  3. O. V. Konnik
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  4. E. B. Rusanov
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  5. A. S. Bogomyakov
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  6. V. I. Ovcharenko
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  7. V. V. Minin
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Corresponding author

Correspondence to V. F. Shul’gin.

Additional information

Original Russian Text © V.F. Shul’gin, E.A. Sarnit, O.V. Konnik, E.B. Rusanov, A.S. Bogomyakov, V.I. Ovcharenko, V.V. Minin, 2012, published in Koordinatsionnaya Khimiya, 2012, Vol. 38, No. 1, pp. 46–51.

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Shul’gin, V.F., Sarnit, E.A., Konnik, O.V. et al. Structure and magnetic properties of the copper(II) complexes with diacyl hydrazides of salicylic acid. Russ J Coord Chem 38, 44–49 (2012). https://doi.org/10.1134/S1070328411120074

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  • DOI: https://doi.org/10.1134/S1070328411120074

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