Skip to main content
SpringerLink
Log in

Synthesis, crystal structure and properties of a new heptamolybdate (NH4)6H2[Cu(C2O4)2(Mo7O24)] · 9H2O

  • Published:
Russian Journal of Coordination Chemistry Aims and scope Submit manuscript

Abstract

An interesting heptamolybdate (NH4)6H2[Cu(C2O4)2(Mo7O24)] · 9H2O (I) was prepared by convenational method in an aqueous solution and characterized by IR spectroscopy, elemental analysis, thermogravimetric analysis, X-ray photoelectron spectroscopy and single-crystal X-ray diffraction. Crystal data for I: monoclinic, space group P21/m with a = 10.1460(5), b = 18.2616(9), c = 10.4994(5) Å, β = 94.3410(10)°, and Z = 2. X-ray structure analysis revealed the complexes to contain a copper center in an octahedral coordination mode bound to two [C2O4]2− anios via the oxygen atoms and two oxygen atoms of the new heptamolybdate species. The zigzag chain structure of I is constructed by [Cu(C2O4)2(Mo7O24)] units via Mo-O-Cu-O-Mo linkers.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Pope, M.T., Heteropoly and Isopoly Oxometalates, New York: Springer, 1983.

    Google Scholar 

  2. Pope, M.T. and Muller, A., Angew. Chem. Int. Ed. Engl., 1991, vol. 30, p. 34.

    Article  Google Scholar 

  3. Wu, P., Li, F.Q., Ge, N., et al., Eur. J. Inorg. Chem., 2004, p. 2819.

  4. Chen, L.J., Xia, C.K., Zhang, Q.Z., et al., Inorg. Chem. Commun., 2005, vol. 8, p. 858.

    Article  CAS  Google Scholar 

  5. Liao, J.H., Juang, J.S., and Lan, Y.C., Cryst. Growth Des., 2006, vol. 6, p. 354.

    Article  CAS  Google Scholar 

  6. Coué, V., Dessapt, R., Doeuff, M.B., et al., Inorg. Chem., 2007, vol. 46, p. 2824.

    Article  Google Scholar 

  7. Zapf, P.J., Warren, C.J., Haushalter, R.C., et al., Chem. Commun., 1997, p. 1543.

  8. Hagrman, D., Warren, C.J., Haushalter, R.C., et al., Chem. Mater., 1998, vol. 10, p. 3294.

    Article  CAS  Google Scholar 

  9. Lü, J., Shen, E.H., Yuan, M., et al., Inorg. Chem., 2003, vol. 42, p. 6956.

    Article  Google Scholar 

  10. Hagrman, D., Hagrman, P., and Zubieta, J., Inorg. Chim. Acta, 2000, vol. 212, p. 300.

    Google Scholar 

  11. Burkholder, E. and Zubieta, J., Inorg. Chim. Acta, 2005, vol. 358, p. 116.

    Article  CAS  Google Scholar 

  12. Wang, X.L., Guo, Y.Q., Li, Y.G., et al., Inorg. Chem., 2003, vol. 42, p. 4135.

    Article  CAS  Google Scholar 

  13. Xu, J.Q., Wang, R.Z., Wang, G.Y., et al., Chem. Commun., 1999, p. 983.

  14. Wang, X.J., Kang, B.S., Su, C., et al., Polyhedron, 1999, vol. 18, p. 3371.

    Article  CAS  Google Scholar 

  15. Mccarron, E.M., Whitney, J.F., and Chase, D.B., Inorg. Chem., 1984, vol. 23, p. 3275.

    Article  CAS  Google Scholar 

  16. Han, Z.G., Ma, H.Y., Peng, J., et al., Inorg. Chem. Commun., 2004, vol. 7, p. 182.

    Article  CAS  Google Scholar 

  17. Tian, C.H., Sun, Z.G., Li, J., et al., Inorg. Chem. Commun., 2007, vol. 10, p. 757.

    Article  CAS  Google Scholar 

  18. Niu, J.Y., You, X.Z., Fun, H.K., et al., Polyhedron, 1996, vol. 15, p. 1003.

    Article  CAS  Google Scholar 

  19. Li, T.H., Lü, J., Gao, S.Y., et al., Inorg. Chem. Commun., 2007, vol. 10, p. 1342.

    Article  CAS  Google Scholar 

  20. Khenkin, A.M., Shimon, L.J.W., and Neumann, R., Inorg. Chem., 2003, vol. 42, p. 3331.

    Article  CAS  Google Scholar 

  21. Koo, B.K. and Lee, U., Inorg. Chim. Acta, 2006, vol. 359, p. 2067.

    Article  CAS  Google Scholar 

  22. Allis, D.G., Burkholder, E., and Zubieta, J., Polyhedron., 2004, vol. 23, p. 1145.

    Article  CAS  Google Scholar 

  23. Wu, C.D., Lu, C.Z., Zhuang, H.H., et al., Inorg. Chem., 2002, vol. 41, p. 5636.

    Article  CAS  Google Scholar 

  24. Sheldrick, G.M., SHELXTL-97, Program for Crystal Structure Solution, Göttingen (Germany): Univ. of Göttingen, 1997.

    Google Scholar 

  25. Evans, H.T., Gatehouse, B., and Leverett, M.P., Dalton Trans., 1975, p. 505.

  26. Brownand, I.D. and Altermatt, D., Acta. Crystallogr., B, 1985, vol. 41, p. 244.

    Article  Google Scholar 

  27. Yang, L.H., Li, J.Q., Yu, X., et al., Chin. J. Nonferrous Met., 2008, vol. 18, p. 1211.

    CAS  Google Scholar 

  28. Nefedov, V.I., Firsov, M.N., and Shaplygin, I.S., J. Electron Spectrosc. Relat. Phenom., 1982, vol. 26, p. 65.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Basic Experiment Teaching Center, Henan University, Kaifeng, Henan, 475004, P.R. China

    J. Li, Y. Liu & J. Luo

  2. Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, Henan, 475004, P.R. China

    J. Luo, J. W. Zhao, P. T. Ma & J. Y. Niu

Authors
  1. J. Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Y. Liu
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. J. Luo
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. J. W. Zhao
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. P. T. Ma
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. J. Y. Niu
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to J. Li.

Additional information

The article is published in the original.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Li, J., Liu, Y., Luo, J. et al. Synthesis, crystal structure and properties of a new heptamolybdate (NH4)6H2[Cu(C2O4)2(Mo7O24)] · 9H2O. Russ J Coord Chem 37, 849–853 (2011). https://doi.org/10.1134/S107032841110006X

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S107032841110006X

Keywords

Search

Navigation