Skip to main content
SpringerLink
Log in

Hydrothermal synthesis, crystal structure, and thermal analysis of a Novel trinuclear manganese complex: Mn3(C12H8N2)2(C10H11O5)6

  • Published:
Russian Journal of Coordination Chemistry Aims and scope Submit manuscript

Abstract

A novel trinuclear manganese(II) complex, Mn3(C12H8N2)2(C10H11O5)6 (I), has been hydrothermally synthesized and characterized by single-crystal X-ray diffraction. The crystal belongs to the monoclinic system, space group P21/n, with cell parameters a = 12.1935(7), b = 19.0249(11), c = 18.0515(10)Å, β = 105.0430(10)°, V = 4044.1(4)Å3, Z = 2. Two of the three manganese atoms in the crystal structure are crystallographically equivalent and adopt N2O4 coordination mode, whereas the remaining manganese atom adopts O6 coordination mode, which forms a nearly regular octahedron. The experimental result of thermal analysis shows that complex I remains stable below 300°C.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Shaikh, N., Goswami, S., Panja, A., et al., Inorg. Chem., 2004, vol. 43, p. 5908.

    Article  CAS  Google Scholar 

  2. Fan, Y., Li, G.H., Shi, Z., et al., J. Solid State Chem., 2004, vol. 177, p. 4346.

    Article  CAS  Google Scholar 

  3. Liu, X.Y., Riera, V., Ruiz, M.A., et al., Organometallics, 1996, vol. 15, p. 974.

    Article  CAS  Google Scholar 

  4. Wang, X.Y., Gan, L., Zhang, S.W., et al., Inorg. Chem., 2004, vol. 43, p. 4615.

    Article  CAS  Google Scholar 

  5. Ma, S.Q. and Zhou, H.C., Chem. Commun., 2010, vol. 1, p. 44.

    Article  Google Scholar 

  6. Jiang, D.M., Mallat, T., Meier, D.M., et al., J. Catal., 2009, vol. 270, p. 26.

    Article  Google Scholar 

  7. Stock, N., Rauscher, M., and Bein, T., J. Solid State Chem., 2004, vol. 177, p. 642.

    Article  CAS  Google Scholar 

  8. Bai, Y., Gao, H., Dang, D.B., et al., J. Mol. Struct., 2009, vol. 934, p. 53.

    Article  CAS  Google Scholar 

  9. Nicolau, M.P.M., Bárcia, P., Gallegos, J.M., et al., J. Phys. Chem., C, 2009, vol. 113, p. 13173.

    Article  CAS  Google Scholar 

  10. Amel’chenkova, E.V., Denisova, T.O., and Nefedov, S.E., Mendeleev Commun., 2004, vol. 14, p. 103.

    Article  Google Scholar 

  11. Terazzi, E., Bourgogne, C., Welter, R., et al., Angew. Chem. Int. Ed., 2008, vol. 47, p. 490.

    Article  CAS  Google Scholar 

  12. Sheldrick, G.M., Acta Crystallogr., Sect. A: Found. Crystallogr., 1990, vol. 46, p. 467.

    Article  Google Scholar 

  13. Sheldrick, G.M., SHELXS-97, Göttingen (Germany): Univ. of Göttingen, 1997.

    Google Scholar 

  14. Sheldrick, G.M., SHELX-97, Göttingen (Germany): Univ. of Göttingen, 1997.

    Google Scholar 

  15. Kumari, N., Prajapati, R., and Hayashidab, O., Polyhedron, 2010, vol. 29, p. ?. 2758.

    Article  Google Scholar 

  16. Wang, R.H., Gao, E.Q., and Hong, M.C., Inorg. Chem., 2003, vol. 42, p. 5487.

    Google Scholar 

  17. Ji, J.W. and Han, Z.B., Russ. J. Coord. Chem., 2010, vol. 36, p. 41.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Faculty of Material Science and Chemistry Engineering, China University of Geosciences, Wuhan, 430074, P.R. China

    L. Zhang, C. Wang, X. Wu, H. Chen & H. Fei

Authors
  1. L. Zhang
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. C. Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. X. Wu
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. H. Chen
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. H. Fei
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to X. Wu.

Additional information

The article is published in the original.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Zhang, L., Wang, C., Wu, X. et al. Hydrothermal synthesis, crystal structure, and thermal analysis of a Novel trinuclear manganese complex: Mn3(C12H8N2)2(C10H11O5)6 . Russ J Coord Chem 37, 382–387 (2011). https://doi.org/10.1134/S1070328411040129

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070328411040129

Keywords

Search

Navigation