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Structural regularities of the ionic complex [K(18C6)]3[In(NCS)6] · 2H2O

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Abstract

The associate [K(18C6)]3[In(NCS)6] · 2H2O was synthesized and structurally characterized. The structure was formed by the octahedral anions [In(NCS)6]3−, crystallographically independent cations [K(18C6)]+, and molecules of water of crystallization. The complex anion and one of the two cations formed polymeric chains (-In-NCS-K-) n . The second cation coordinated one of the sulfur atoms of the polymer chain.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    A. B. Ilyukhin & S. P. Petrosyants

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  1. A. B. Ilyukhin
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  2. S. P. Petrosyants
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Correspondence to S. P. Petrosyants.

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Original Russian Text © A.B. Ilyukhin, S.P. Petrosyants, 2010, published in Koordinatsionnaya Khimiya, 2010, Vol. 36, No. 8, pp. 563–568.

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Ilyukhin, A.B., Petrosyants, S.P. Structural regularities of the ionic complex [K(18C6)]3[In(NCS)6] · 2H2O. Russ J Coord Chem 36, 559–564 (2010). https://doi.org/10.1134/S1070328410080014

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  • DOI: https://doi.org/10.1134/S1070328410080014

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