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H-bonding of complex indium thiocyanates with crown ether molecules

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Abstract

Supramolecular ensembles [In(H2O)4(NCS)2][In(H2O)2(NCS)4] · 2(18C6) (I) and [In(H2O)3(NCS)3] · 18C6 (II) are synthesized and identified by the data of elemental analyses, IR spectra, and X-ray structure analysis for structure I and X-ray phase analysis for structure II. In spite of specific features of the H-bonding of the 18C6 molecules with the cationic, molecular, or anionic indium complexes, chain motives are observed in structures I and II.

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References

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    S. P. Petrosyants & A. B. Ilyukhin

Authors
  1. S. P. Petrosyants
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  2. A. B. Ilyukhin
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Correspondence to S. P. Petrosyants.

Additional information

Original Russian Text © S.P. Petrosyants, A.B. Ilyukhin, 2009, published in Koordinatsionnaya Khimiya, 2009, Vol. 35, No. 4, pp. 307–310.

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Petrosyants, S.P., Ilyukhin, A.B. H-bonding of complex indium thiocyanates with crown ether molecules. Russ J Coord Chem 35, 302–306 (2009). https://doi.org/10.1134/S1070328409040113

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  • DOI: https://doi.org/10.1134/S1070328409040113

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