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Isomerization of [In(H2O)3Cl3] · 18C6. Crystal structure of [mer-In(H2O)3Cl3] · 18C6 and [fac-In(H2O)3Cl3] · 18C6 · 2H2O

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Abstract

The complex [mer-In(H2O)3Cl3] · 18C6 (I) was isolated from the InCl3-H2O-Solv-18C6 solutions (Solv = MeOH, EtOH, THF). The second crystallization from mother solutions resulted in [fac-In(H2O)3Cl3] · 18C6 · 2H2O (II). The crystal and molecular structures of isomers I, II were identified by the powder X-ray diffraction, IR, and X-ray diffraction methods. Although complexes I, II have different compositions, they have the chain structure. The thermal decomposition of complexes I, II was studied.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemisry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    A. B. Ilykhin, Zh. V. Dobrokhotova & S. P. Petrosyants

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  1. A. B. Ilykhin
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  2. Zh. V. Dobrokhotova
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  3. S. P. Petrosyants
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Correspondence to S. P. Petrosyants.

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Original Russian Text © A.B. Ilykhin, Zh.V. Dobrokhotova, S.P. Petrosyants, 2008, published in Koordinatsionnaya Khimiya, 2008, Vol. 34, No. 9, pp. 651–656.

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Ilykhin, A.B., Dobrokhotova, Z.V. & Petrosyants, S.P. Isomerization of [In(H2O)3Cl3] · 18C6. Crystal structure of [mer-In(H2O)3Cl3] · 18C6 and [fac-In(H2O)3Cl3] · 18C6 · 2H2O. Russ J Coord Chem 34, 641–646 (2008). https://doi.org/10.1134/S1070328408090029

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  • DOI: https://doi.org/10.1134/S1070328408090029

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