Skip to main content
SpringerLink
Log in

Syntheses and structures of nine-coordinate NH4[HoIII(Edta)(H2O)3] · 1.5H2O, (NH4)4[Ho III2 (Dtpa)2] · 9H2O, and (NH4)3[HoIII(Ttha)] · 5H2O complexes

  • Published:
Russian Journal of Coordination Chemistry Aims and scope Submit manuscript

Abstract

The three title complexes, NH4[HoIII(Edta)(H2O)3] · 1.5H2O (I) (H4Edta = ethylenedianine-N,N,N′,N′-tetraacetic acid), (NH4)4[Ho III2 (Dtpa)2] · 9H2O (II) (H5Dtpa = diethylenetriamine-N,N,N′,N″,N″-entaacetic acid), and (NH4)3[HoIII(Ttha)] · 5H2O (III) (H6 Ttha = triethylenetetramine-N,N,N′,N″,N‴,N‴-hexaacetic acid), have been prepared and characterized by FT-IR, elemental analyses, and single-crystal X-ray diffraction technique. Complex I has a nine-coordinate mononuclear structure with distorted monocapped square antiprismatic conformation and its crystal structure belongs to orthorhombic system and Fdd2 space group. The crystal data are as follows: a = 19.343(9), b = 35.125(17), c = 12.364(6) Å, V = 8400(7) Å3, Z = 16, M = 552.26, ρcalcd = 1.747 g cm−3 μ = 3.828 mm−1, and F(000) = 4368. Complex II has a binuclear nine-coordinate pseudomonocapped square antiprismatic conformation and its crystal structure belongs to triclinic system and space P1 group. The crystal data are as follows: a = 9.7637(16), b = 9.9722(16), c = 12.945(2) Å, α= 85.853(2)°, β = 77. 140(2)°, γ = 77.140(2)°, V = 1198.4(3) Å3, Z = 1, M = 1340.80, ρcalcd = 1.858 g cm−3, μ = 3.380 mm−1, and F(000) = 674. As for complex III, it also has nine-coordinate mononuclear structure with distorted tricapped trigonal prism and its crystal structure belongs to monoclinic system andP21/c space group. The crystal data are as follows: a = 10.349(3), b = 12.760(4), c = 23.142(7) Å, β = 91.020(6)°, V = 3055.6(16) Å3, Z = 2, M = 797.55, ρcalcd = 1.734 g cm−3, μ = 2.674 mm−1, and F(000) = 1624. The results showed that although the ligands are different from one another in the shape and the numbers of coordination atoms, they all have nine-coordinate structures. However, one of them has binuclear structure and the other two have mononuclear structures because of the difference of the ligands.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Zhang, S.Z. and Shan, X.Q., Environ. Pollut., 2001, vol. 112, no. 3, p. 395.

    Article  CAS  Google Scholar 

  2. Zhou, J., Wang, L.F., Wang, J.Y., et al., J. Inorg. Biochem., 2001, vol. 8, no. 1, p. 41.

    Article  CAS  Google Scholar 

  3. Akaboshia, M., Suminoa, T., Tanakaa, Y., et al., J. Radio Nucl. Chem., 1997, vol. 217, no. 2, p. 179.

    Article  Google Scholar 

  4. Lauffer, R.B., Chem. Rev., 1987, vol. 87, no. 5, p. 901.

    Article  CAS  Google Scholar 

  5. Richardson, F.S., Chem. Rev., 1982, vol. 82, no. 5, p. 541.

    Article  CAS  Google Scholar 

  6. Sledge, C.B., Zuckerman, J.D., and Shortkroff, S., J. Bone Joint Surg. Am., 1987, vol. 69, no. 13, p. 970.

    CAS  Google Scholar 

  7. Miyoshi, K., Wang, J., and Mizuta, T., Inorg. Chim. Acta., 1995, vol. 228, no. 2, p. 165.

    Article  CAS  Google Scholar 

  8. Miyoshi, K., Wang, J., and Mizuta, T., Inorg. Chim. Acta, 1995, vol. 230, no. 1, p. 119.

    Article  Google Scholar 

  9. Mizuta, T., Wang, J., and Miyoshi, K., Inorg. Chim. Acta, 1993, vol. 203, no. 2, p. 249.

    Article  CAS  Google Scholar 

  10. Mizuta, T., Wang, J., and Miyoshi, K., Bull. Chem. Soc. Jpn., 1993, vol. 66, no. 17, p. 3662.

    Article  CAS  Google Scholar 

  11. Mizuta, T., Wang, J., and Miyoshi, K., Bull. Chem. Soc. Jpn., 1993, vol. 66, no. 12, p. 2547.

    Article  CAS  Google Scholar 

  12. Mizuta, T., Wang, J., and Miyoshi, K., Chem. Lett., 1995, vol. 33, no. 8, p. 721.

    Google Scholar 

  13. Wang, R.Y., Li, J.R., Jin, T.Z., et al., Polyhedron, 1997, vol. 16, no. 8, p. 1361.

    Article  CAS  Google Scholar 

  14. Chen, Y., Ma, B.Q., Liu, Q.D., et al., Inorg. Chem. Commun., 2000, vol. 319, p. 3.

    Google Scholar 

  15. Chen, D.F., Yang, W.C., and Wang, R.Y., Acta Chim. Sinica, 1997, vol. 55, no. 7, p. 672.

    CAS  Google Scholar 

  16. Wang, J., Liu, Z.R., Zhang, X.D., et al., Chin. Rare Met., 2003, vol. 22, no. 4, p. 241.

    CAS  Google Scholar 

  17. Wang, J., Ling, X., Zhang, X.D., et al., Chin. J. Inorg. Chem., 2002, vol. 18, no. 5, p. 509.

    CAS  Google Scholar 

  18. Wang, J., Zhang, X.D., and Ma, R., Chem. Res. Chin. Univ., 2002, vol. 18, no. 3, p. 237.

    Google Scholar 

  19. Wang, J., Liu, Z.R., Zhang, X.D., et al., J. Mol. Struct., 2003, vol. 644, no. 1–3, p. 29.

    Article  CAS  Google Scholar 

  20. Guggenberger, L.J., Muetterties, E.L., J. Am. Chem. Soc., 1976, vol. 98, p. 7221.

    Article  CAS  Google Scholar 

  21. Wang, J., Zhang, X.D., Jia, W.G., et al., Russ. J. Coord. Chem., 2004, vol. 30, no. 2, p. 130.

    Article  CAS  Google Scholar 

  22. Wang, J., Zhang, X.D., Liu, Z.R., et al., J. Mol. Struct., 2002, vol. 613, no. 1–3, p. 189.

    Article  CAS  Google Scholar 

  23. Inomata, Y., Sunakawa, T., and Howell, F.S., J. Mol. Struct., 2003, vol. 648, no. 1–2, p. 81.

    Article  CAS  Google Scholar 

  24. Wang, J., Zhang, X.D., and Jia, W.G., Chin. Rare Earth, 2002, vol. 8, no. S1, p. 765.

    Google Scholar 

  25. Wang, R.Y., Zhang, H.J., Jin, T.Z., et al., Chem. J. Chin. Univ., 1999, vol. 20, no. 2, p. 176.

    Google Scholar 

  26. Wang, J., Zhang, X.D., and Ma, R., Acta Chim. Sinica (in Chinese), 2002, vol. 60, no. 3, p. 536.

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Liaoning University, Shenyang, 110036, P.R. China

    X. F. Wang, X. Zh. Liu, J. Wang, Zh. H. Zhang, W. Sun, Y. M. Kong & X. D. Zhang

Authors
  1. X. F. Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. X. Zh. Liu
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. J. Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Zh. H. Zhang
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. W. Sun
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Y. M. Kong
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. X. D. Zhang
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to J. Wang.

Additional information

The text was submitted by the authors in English.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Wang, X.F., Liu, X.Z., Wang, J. et al. Syntheses and structures of nine-coordinate NH4[HoIII(Edta)(H2O)3] · 1.5H2O, (NH4)4[Ho III2 (Dtpa)2] · 9H2O, and (NH4)3[HoIII(Ttha)] · 5H2O complexes. Russ J Coord Chem 34, 134–145 (2008). https://doi.org/10.1134/S1070328408020097

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070328408020097

Keywords

Search

Navigation