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Crystal structures of some crystal hydrates of binary molybdates

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Abstract

The structures of a series of binary molybdates with the lithium cation LiM(MoO4) · H2O (M = K+, Na+, Rb+, NH +4 ) are analyzed and compared. Except for LiNa(MoO4) · 2H2O, in all other compounds the lithium cations have a tetrahedral coordination formed by the oxygen atoms of the water molecules and molybdate groups. The structure of LiNa(MoO4) · 2H2O was found to contain a unique coordination polyhedron of lithium, i.e., a trigonal bipyramid formed by the O atoms of the water molecules and oxo anions.

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References

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Authors and Affiliations

  1. Kabardino-Balkar State Agricultural Academy, ul. Tolstogo 185, Nalchik, 360004, Russia

    D. D. Makitova

  2. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow oblast, 142432, Russia

    V. V. Tkachev & L. O. Atovmyan

Authors
  1. D. D. Makitova
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  2. V. V. Tkachev
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  3. L. O. Atovmyan
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Additional information

Original Russian Text © D.D. Makitova, V.V. Tkachev, L.O. Atovmyan, 2007, published in Koordinatsionnaya Khimiya, 2007, Vol. 33, No. 10, pp. 785–786.

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Makitova, D.D., Tkachev, V.V. & Atovmyan, L.O. Crystal structures of some crystal hydrates of binary molybdates. Russ J Coord Chem 33, 772–773 (2007). https://doi.org/10.1134/S1070328407100107

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  • DOI: https://doi.org/10.1134/S1070328407100107

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