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Interpretation of the IR spectra of aluminum, gallium, and indium tris(acetylacetonates)

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Abstract

The IR spectra of M(Acac)3 (M = Al, Ga, and In; Acac−1 is the acetylacetonate ion) and their isotope-substituted analogs were calculated by the Hartree-Fock-Roothaan method. The results obtained and available literature data were used to assign the absorption bands. A correlation was found between the force constants of the M-O bond and the stability constants of the complexes M(Acac)3.

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Authors and Affiliations

  1. Institute of Physics and Information Technology, Far East State University, Vladivostok, Russia

    S. N. Slabzhennikov, O. B. Ryabchenko & L. A. Kuarton

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  1. S. N. Slabzhennikov
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  2. O. B. Ryabchenko
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  3. L. A. Kuarton
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Additional information

Original Russian Text © S.N. Slabzhennikov, O.B. Ryabchenko, L.A. Kuarton, 2006, published in Koordinatsionnaya Khimiya, 2006, Vol. 32, No. 8, pp. 570–576.

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Slabzhennikov, S.N., Ryabchenko, O.B. & Kuarton, L.A. Interpretation of the IR spectra of aluminum, gallium, and indium tris(acetylacetonates). Russ J Coord Chem 32, 545–551 (2006). https://doi.org/10.1134/S1070328406080021

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  • DOI: https://doi.org/10.1134/S1070328406080021

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