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The radical-cation salt (DOEO)4[HgBr4] · TCE: Synthesis, structure and conductivity

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An Erratum to this article was published on 01 December 2006

Abstract

Crystals of a new radical-cation salt (DOEO)4[HgBr4] · TCE (I) (DOEO = (1,4-dioxanediyl-2,3-dithio)ethylenedioxotetrathiafulvalene, TCE = 1,1,2-trichloroethane) were synthesized by electrocrystallization method at constant current (i=5×10−6 A/cm2). Crystal structure was studied at room (293 K) and low (30 K) temperatures and was found to consist of the radical-cation layers alternating along the z-axis with tetrahedral HgBr 2−4 anions and TCE molecules. The anion is disordered over three positions at room and over two positions at low temperatures with occupancy factors 87, 11, 2 and 98, 2%, respectively. The poorly occupied positions of the anion are overlapped with positions of the TCE molecule disordered over two equally occupied positions. The DOEO ethylene groups disordered at 293 K were found ordered at 30 K. The conductivity of I exhibits the following peculiarity: in a temperature interval of 120–140 K, the temperature dependence of resistivity has a pronounced maximum.

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Authors and Affiliations

  1. Institute of Problems of Technology of Microelectronics and Special-Purity Materials, Russian Academy of Sciences, Chernogolovka, Moscow oblast, Russia

    A. A. Bardin

  2. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow oblast, 142432, Russia

    A. I. Kotov, G. V. Shilov, L. I. Buravov & E. B. Yagubskii

  3. Institute of Solid-State Physics, Russian Academy of Sciences, Chernogolovka, Moscow oblast, 142432, Russia

    S. S. Khasanov

  4. Department of Chemistry, University of Resnais, France

    L. Ochab

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  1. A. A. Bardin
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  4. G. V. Shilov
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  5. L. I. Buravov
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  7. E. B. Yagubskii
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Additional information

Original Russian Text © A.A. Bardin, A.I. Kotov, S.S. Khasanov, G.V. Shilov, L.I. Buravov, L. Ochab, E.B. Yagubskii, 2006, published in Koordinatsionnaya Khimiya, 2006, Vol. 32, No. 2, pp. 88–100.

An erratum to this article is available at http://dx.doi.org/10.1134/S1070328406120104.

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Bardin, A.A., Kotov, A.I., Khasanov, S.S. et al. The radical-cation salt (DOEO)4[HgBr4] · TCE: Synthesis, structure and conductivity. Russ J Coord Chem 32, 82–93 (2006). https://doi.org/10.1134/S1070328406020023

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  • DOI: https://doi.org/10.1134/S1070328406020023

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