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Preparation, Structure, and Dielectric and Magnetic Properties of SrFe2/3W1/3O3 Ceramics

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Abstract

Polycrystalline samples of SrFe2/3W1/3O3 (SFWO) ceramic were obtained by solid-phase reactions with subsequent sintering using conventional ceramic technology. X-ray diffraction analysis showed that at room temperature, the SFWO ceramic is single-phase and has a perovskite-type structure with tetragonal symmetry and parameters a = 3.941(9) Å, c = 3.955(6) Å, and c/a = 1.0035. In studying the magnetic properties and the Mössbauer effect in SFWO ceramics, it is found that the material is a ferrimagnet, and the iron ions are only in the valence state of Fe3+. It is suggested that in the temperature range of T = 150–210°C, a smeared phase transition from a cubic (paraelectric) phase to a tetragonal (ferroelectric) phase takes place in SFWO with decreasing temperature.

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Authors and Affiliations

  1. Research Institute of Physics, South Federal University, Rostov-on-Don, 344090, Russia

    A. V. Pavlenko, A. V. Turik, L. A. Shilkina, S. P. Kubrin, L. A. Reznichenko & I. N. Andryushina

  2. Southern Scientific Center, Russian Academy of Sciences, Rostov-on-Don, 344006, Russia

    A. V. Pavlenko

  3. Smart Materials Research Center, Southern Federal University, Rostov-on-Don, 344090, Russia

    Yu. V. Rusalev

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  1. A. V. Pavlenko
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  2. A. V. Turik
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  3. L. A. Shilkina
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  4. S. P. Kubrin
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  5. Yu. V. Rusalev
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  6. L. A. Reznichenko
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  7. I. N. Andryushina
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Correspondence to A. V. Pavlenko.

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Original Russian Text © A.V. Pavlenko, A.V. Turik, L.A. Shilkina, S.P. Kubrin, Yu.V. Rusalev, L.A. Reznichenko, I.N. Andryushina, 2018, published in Fizika Tverdogo Tela, 2018, Vol. 60, No. 3, pp. 510–514.

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Pavlenko, A.V., Turik, A.V., Shilkina, L.A. et al. Preparation, Structure, and Dielectric and Magnetic Properties of SrFe2/3W1/3O3 Ceramics. Phys. Solid State 60, 515–519 (2018). https://doi.org/10.1134/S1063783418030216

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  • DOI: https://doi.org/10.1134/S1063783418030216

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