Abstract
The kinetics of growth of a new nanosized phase in a binary diffusion couple during isothermal annealing has been investigated with allowance made for the size dependence of kinetic coefficients. It has been demonstrated using this approach that the exponent of the growth rate of the new phase can be non-monotonic in time and that the growth of the new phase at intermediate stages can be either retarded or accelerated.
Similar content being viewed by others
References
V. I. Dybkov, Kinetics of Solid-Phase Chemical Reactions: Growth of Layers of Chemical Compounds in Binary Heterogeneous Systems (Naukova Dumka, Kiev, 1992) [in Russian].
Ya. E. Geguzin, Diffusion Zone (Nauka, Moscow, 1979) [in Russian].
A. M. Gusak, O. O. Bogatyrev, T. V. Zaporozhets, A. O. Koval’chuk, S. V. Kornienko, G. V. Lutsenko, Yu. O. Lyashenko, and A. S. Shirinyan, Models of Solid-Phase Reactions (Cherkassy National University, Cherkassy, Ukraine, 2004) [in Russian].
U. Gösele and K. N. Tu, J. Appl. Phys. 53, 3252 (1982).
B. Ya. Pines and É. F. Chaĭkovskiĭ, Fiz. Tverd. Tela (Leningrad) 1, 946 (1959) [Sov. Phys. Solid State 1, 864 (1959)].
B. A. Gurov, B. A. Kartashkin, and Yu. É. UgastÉ, Interdiffusion in Multiphase Metallic Systems (Nauka, Moscow, 1981) [in Russian].
C. Wagner, Z. Phys. Chem., Abt. B 21, 25 (1933).
Ya. I. Frenkel’ and M. I. Sergeev, Zh. Éksp. Teor. Fiz. 9, 189 (1939).
G. V. Kidson, J. Nucl. Mater. 3, 21 (1961).
K. H. Prakash and T. Sritharan, J. Electron. Mater. 32, 939 (2003).
B. Ya. Lyubov, The Kinetic Theory of Phase Transformations (Metallurgiya, Moscow, 1969) [in Russian].
B. B. Straumal, A. A. Mazilkin, S. G. Protasova, A. A. Myatiev, P. B. Straumal, and B. Baretzky, Acta Mater. 56, 6246 (2008).
A. S. Shirinyan and M. Wautelet, Nanotechnology 15, 1720 (2004).
W. P. Tong, N. P. Tao, Z. B. Wang, and J. Lu, Science (Washington) 299, 686 (2003).
A. V. Serebryakov, Metallofiz. Noveĭshie Tekhnol. 13, 115 (1991).
K. Barmak, C. Michaelsen, and G. Lucadamo, J. Mater. Res. 12, 133 (1997).
I. D. Morokhov, V. I. Petinov, L. I. Trusov, and V. F. Petrunin, Usp. Fiz. Nauk 133(4), 653 (1981) [Sov. Phys.—Usp. 24 (4), 295 (1981)].
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © A.S. Shirinyan, 2010, published in Fizika Tverdogo Tela, 2010, Vol. 52, No. 6, pp. 1191–1198.
Rights and permissions
About this article
Cite this article
Shirinyan, A.S. Reactive diffusion in a binary solid-state nanosystem. Phys. Solid State 52, 1267–1275 (2010). https://doi.org/10.1134/S1063783410060235
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1063783410060235