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Photomagnetic effect in molecular magnets based on nitrosyl complexes of ruthenium and rare-earth ions

  • Magnetism and Ferroelectricity
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Abstract

The magnetic properties of new bifunctional molecular magnets based on nitrosyl complexes of ruthenium and thiacalix[4]arenes of rare-earth ions (Gd3+, Dy3+) have been investigated. A photoinduced decrease in the magnetization of the molecular magnet with rare-earth ions Gd3+ and the absence of a photomagnetic effect in crystals with rare-earth ions Dy3+ have been revealed at a temperature of 2 K. It has been found that, in the sample containing Dy3+ ions, the magnetization deviates by 6% from the calculated value for noninteracting ions. A comparison of the results obtained for two groups of isostructural samples, which differ only in the type of rare-earth ions, has demonstrated that the observed deviation of the magnetization is caused by the interaction of the orbital moment of the Dy3+ ions with the crystal field.

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, pr. Akademika Semenova 1, Chernogolovka, Moscow oblast, 142432, Russia

    R. B. Morgunov, A. I. Dmitriev, F. B. Mushenok, É. B. Yagubskiĭ & L. A. Kushch

  2. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center, Russian Academy of Sciences, ul. Akademika Arbuzova 8, Kazan, 420088, Tatarstan, Russia

    A. R. Mustafina, V. A. Burilov, A. T. Gubaĭdullin, A. I. Konovalov & I. S. Antipin

  3. Graduated School of Science, Osaka City University, Osaka, Japan

    Y. Tanimoto

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  1. R. B. Morgunov
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Correspondence to R. B. Morgunov.

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Original Russian Text © R.B. Morgunov, A.I. Dmitriev, F.B. Mushenok, É.B. Yagubskiĭ, L.A. Kushch, A.R. Mustafina, V.A. Burilov, A.T. Guba3dullin, A.I. Konovalov, I.S. Antipin, Y. Tanimoto, 2009, published in Fizika Tverdogo Tela, 2009, Vol. 51, No. 10, pp. 1975–1980.

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Morgunov, R.B., Dmitriev, A.I., Mushenok, F.B. et al. Photomagnetic effect in molecular magnets based on nitrosyl complexes of ruthenium and rare-earth ions. Phys. Solid State 51, 2095–2100 (2009). https://doi.org/10.1134/S1063783409100175

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