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Temperature dependence of the band gap of Cu2ZnSnS4 single crystals

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Abstract

The transmittance spectra of Cu2ZnSnS4 single crystals grown by the technique of chemical gastransport reactions are studied in the region of the fundamental absorption edge in the temperature range T = 20 to 300 K. From the experimental spectra, the band gap of the compound is determined and the temperature dependence of the band gap is established. It is found that the band gap increases, as temperature is increased. It is shown that the temperature dependence is adequately described by the corresponding theoretical expression.

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References

  1. T. K. Todorov, J. Tang, S. Bag, O. Gunawan, T. Gokmen, Yu. Zhu, and D. B. Mitzi, Adv. Energ. Mater. 4, 1 (2012).

    Google Scholar 

  2. G. Brammertz, M. Buffiere, S. Oueslati, H. El Anzeery, K. Messaoud, S. Sahayaraj, C. Koble, M. Meuris, and J. Poortmans, Appl. Phys. Lett. 103, 163904 (2013).

    Article  ADS  Google Scholar 

  3. I. Repins, C. Beall, N. Vora, C. de Hart, D. Kuciauskas, P. Dippo, B. To, J. Mann, W. C. Hsu, A. Goodrich, and R. Noufi, Sol. Energy Mater. Sol. Cells 101, 154 (2012).

    Article  Google Scholar 

  4. S. Ozaki and T. Namba, Phys. Status Solidi C 9, 2403 (2012).

    Article  ADS  Google Scholar 

  5. J. He, L. Sun, Sh. Chen, Ye. Chen, P. Yang, and J. Chu, J. Alloys Compd. 511, 129 (2012).

    Article  Google Scholar 

  6. F. Gao, S. Yamazoe, T. Maeda, K. Nakanishi, and T. Wada, Jpn. J. Appl. Phys. 51, 28 (2012).

    Google Scholar 

  7. P. M. P. Salome, J. Malaquias, P. A. Fernandes, M. S. Ferreira, A. F. da Cunha, J. P. Leitao, J. C. Gonzalez, and F. M. Matinaga, Sol. Energy Mater. Sol. Cells 101, 147 (2012).

    Article  Google Scholar 

  8. H. Matsushita, T. Ichikawa, and A. Katsui, J. Mater. Sci. 40, 2003 (2005).

    Article  ADS  Google Scholar 

  9. L. Guen and W. S. Glaunsinger, J. Solid State Chem. 35, 35 (1980).

    Article  Google Scholar 

  10. R. Nitsche, D. F. Sargent, and P. Wild, J. Cryst. Growth 1, 52 (1967).

    Article  ADS  Google Scholar 

  11. D. Colombara, S. Delsante, G. B orzone, J. M. Mitchels, K. C. Molloy, L. H. Thomas, B. G. Mendis, C. Y. Cummings, F. Marken, and L. M. Peter, J. Cryst. Growth 364, 101 (2013).

    Article  ADS  Google Scholar 

  12. Yu. I. Ukhanov, Optical Properties of Semiconductors (Nauka, Moscow, 1977) [in Russian].

    Google Scholar 

  13. I. V. Bodnar and S. A. Pavlyukovets, Semiconductors 45, 1395 (2011).

    Article  ADS  Google Scholar 

  14. I. V. Bodnar, S. A. Pavlyukovets, A. V. Danil’chik, and E. V. Lutsenko, J. Appl. Spectrosc. 78, 755 (2011).

    Article  ADS  Google Scholar 

  15. S. Levchenko, D. Dumcenco, Y. P. Wang, Y. S. Huang, C. H. Ho, E. Arushanov, V. Tezlevan, and K. K. Tiong, Opt. Mater. 34, 1362 (2012).

    Article  ADS  Google Scholar 

  16. R. Passler, Phys. Status Solidi B 200, 155 (1997).

    Article  ADS  Google Scholar 

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Correspondence to I. V. Bodnar.

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Original Russian Text © I.V. Bodnar, 2015, published in Fizika i Tekhnika Poluprovodnikov, 2015, Vol. 49, No. 5, pp. 596–598.

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Bodnar, I.V. Temperature dependence of the band gap of Cu2ZnSnS4 single crystals. Semiconductors 49, 582–585 (2015). https://doi.org/10.1134/S106378261505005X

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  • DOI: https://doi.org/10.1134/S106378261505005X

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