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Chemical sensors based on a hydrochemically deposited lead sulfide film for the determination of lead in aqueous solutions

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Abstract

Chemical sensors for determining lead in aqueous solutions are developed based on hydrochemically deposited lead sulfide (PbS) films; their composition and surface morphology are studied. The sensors are sensitive to lead to 31.5–32.5 mV/pc Pb with the limit of detection of the metal 1.5 × 10–8 M. The role of photoactivation and doping of films in increasing the sensitivity of the film sensor to lead is determined. The studied chemical sensors can be relatively easily regenerated by soaking in distilled water for 10–30 min; they have sufficiently high selectivity to lead in the presence of sodium, nickel, zinc, and cadmium salts in solution.

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References

  1. Vlasov, Yu., Legin, A., and Rudnitskaya, A., Sens. Actuators, B, 1997, vol. 44, p. 532.

    Article  CAS  Google Scholar 

  2. Zakharova, G.S. and Podval’naya, N.V., RF Patent 2470289, Byull. Izobret., 2012, no. 35.

  3. Kirsanov, D.O., Legin, A.V., Babain, V.A., Pol’shin, E.N., Rudnitskaya, A.M., Legin, K.A., and Seleznev, B.L., RF Patent 2315988, Byull. Izobret., 2008, no. 3.

  4. Dae-Sik, L., Chang-Hyun, S., Jun-Woo, L., Jeung-Soo, H., Duk-Dong, L., and Youn-Tae, K., Sens. Actuators, B, 2002, vol. 83, p. 250.

    Article  Google Scholar 

  5. Mourzina, Yu., Yoshinodu, T., Schubert, J., Luth, H., Iwasaki, H., and Schoning, M.J., Sens. Actuators, B, 2001, vol. 80, p. 136.

    Article  CAS  Google Scholar 

  6. Mourzina, Yu., Schoning, M.J., Schubert, J., Zander, W., Legin, A.V., Vlasov, Yu.G., Kordos, P., and Luth, H., Sens. Actuators, B, 2000, vol. 71, p. 13.

    Article  CAS  Google Scholar 

  7. Vlasov, Yu.G., Ermolenko, Yu.E., Legin, A.V., and Murzina, Yu.G., J. Anal. Chem., 1999, vol. 54, p. 476.

    CAS  Google Scholar 

  8. Kloock, J., Mourzina, Yu., Schubert, J., and Schoning, M., Sens. Actuators, B, 2002, vol. 85, p. 79.

    Article  Google Scholar 

  9. Martin, Y.M., Hermandez, Y.L., Adell, L., Rodrigues, A., and Lopez, F., Semicond. Sci. Technol., 1996, vol. 11, p. 1740.

    Article  CAS  Google Scholar 

  10. Gardona, M. and Harbeke, G., Phys. Rev. A: At., Mol., Opt. Phys., 1965, vol. 1237, p. 1467.

    Article  Google Scholar 

  11. Ivanov, D., Streltcov, V., and Fedotov, A., Phys. Solid State, 2005, vol. 1, p. 416.

    Google Scholar 

  12. Perna, G., Cappozi, V., Pagliara, S., Ambrico, M., and Lojacono, D., Thin Solid Films, 2001, vol. 387, p. 208.

    Article  CAS  Google Scholar 

  13. Wu, H., Fang, X., Sales, R., McAlister, D., and McCann, P.J., J. Vac. Sci. Technol., 1999, vol. 17, p. 1263.

    Article  CAS  Google Scholar 

  14. Schoning, M., Moursina, Yu., Schubert, J., Zander, W., Legin, A., Vlasov, Yu., and Luth, H., Sens. Actuators, B, 2001, vol. 78, p. 273.

    Article  CAS  Google Scholar 

  15. Markov, V.F. and Maskaeva, L.N., J. Anal. Chem., 2001, vol. 56, no. 8, p. 754.

    Article  CAS  Google Scholar 

  16. Markov, V.F., Vinogradova, T.V., Zarubin, I.V., and Maskaeva, L.N., Analitika Kontrol’, 2012, vol. 16, no. 4, p. 410.

    Google Scholar 

  17. Markov, V.F., Maskaeva, L.N., Zarubin, I.V., and Zamaraeva, N.V., Voda: Khim. Ekol., 2012, no. 6, p. 80.

    Google Scholar 

  18. Chen, S. and Liu, W., Mater. Chem. Phys., 2006, vol. 98, p. 183.

    Article  CAS  Google Scholar 

  19. Mathews, N.R., Angeles-Chavez, C., Cortes-Jacome, M.A., and Toledo-Antonio, J.A., Electrochim. Acta, 2013, vol. 99, p. 76.

    Article  CAS  Google Scholar 

  20. Pawar, S.B., Shaikh, J.S., Devan, R.S., Ma, Y.R., Haranath, D., Bhosale, P.N., and Patil, P.S., Appl. Surf. Sci., 2011, vol. 258, p. 1869.

    Article  CAS  Google Scholar 

  21. Jana, S., Thapa, R., Maity, R., and Chattopadhyay, K.K., Phys. E, 2008, vol. 40, p. 3121.

    Article  CAS  Google Scholar 

  22. Fernandez-Lima, F.A., Gonzalez-Alfaro, Y., Larramendi, E.M., and Foseca-Filho, H.D., Maia de Costa, M.E.H., Freire, F.L., Jr., Prioli, R., Avillez, R.R., Silveira, E.F., Calzadilla, O., Melo, O., Pedrero, E., and Hernandez, E., Mater. Sci. Eng., B, 2007, vol. 136, p. 187.

    Article  CAS  Google Scholar 

  23. Ekoniks. www.econix.com. Cited July 27, 2016.

  24. Marco, R., Cattral, R., Liesegang, J., and Nymberg, G., Anal. Chem., 1992, vol. 64, p. 594.

    Article  Google Scholar 

  25. Vlasov, Yu., Bychkov, E., and Medvedev, M., Anal. Chim. Acta, 1986, vol. 185, p. 137.

    Article  CAS  Google Scholar 

  26. Vlasov, Yu.G., Ermolenko, Yu.E., and Ischakova, O.F., Zh. Anal. Khim., 1979, vol. 34, no. 8, p. 1522

    CAS  Google Scholar 

  27. Damaskin, B.B., Vvedenie v electrokhimicheskuyu kinetiku (Introduction to Electrochemical Kinetics), Moscow: Vysshaya Shkola, 1983.

    Google Scholar 

  28. Promavtomatika. www.npo-proma.ru. Cited July 27, 2016.

  29. SoyuzKhimprom. www.shp-lab.ru. Cited July 27, 2016.

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Authors and Affiliations

  1. Institute of Chemical Technology, Ural Federal University, Yekaterinburg, 620002, Russia

    I. V. Zarubin, V. F. Markov, L. N. Maskaeva & N. V. Zarubina

  2. Ural Institute of State Fire-Fighting Service, Ministry of Emergency Situations of Russia, Yekaterinburg, 620062, Russia

    V. F. Markov & L. N. Maskaeva

  3. Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences, Yekaterinburg, 620990, Russia

    M. V. Kuznetsov

Authors
  1. I. V. Zarubin
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  2. V. F. Markov
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  3. L. N. Maskaeva
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  4. N. V. Zarubina
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  5. M. V. Kuznetsov
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Correspondence to N. V. Zarubina.

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Original Russian Text © I.V. Zarubin, V.F. Markov, L.N. Maskaeva, N.V. Zarubina, M.V. Kuznetsov, 2017, published in Zhurnal Analiticheskoi Khimii, 2017, Vol. 72, No. 3, pp. 266–272.

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Zarubin, I.V., Markov, V.F., Maskaeva, L.N. et al. Chemical sensors based on a hydrochemically deposited lead sulfide film for the determination of lead in aqueous solutions. J Anal Chem 72, 327–332 (2017). https://doi.org/10.1134/S1061934817030145

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  • DOI: https://doi.org/10.1134/S1061934817030145

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