Skip to main content
SpringerLink
Log in

Chromatographic and adsorption properties of the mixed stationary phase poly(1-trimethylsilyl-1-propyne)/poly(1-phenyl-1-propyne)

  • Articles
  • Published:
Journal of Analytical Chemistry Aims and scope Submit manuscript

Abstract

Adsorption and chromatographic properties of the mixed stationary phase poly-(1-trimethylsilyl-1-propyne)/poly(1-phenyl-1-propyne) (PTMSP/PPP) composed as 97: 3 by weight have been investigated by methods of low-temperature nitrogen adsorption and gas chromatography on packed columns. The resultant phase has uniform mesoporous structure. The chromatographic properties of the mixed phase are significantly different from the properties of the original porous polymers PTMSP and PPP. The adsorbent obtained by modifying Chromosorb P NAW with a mixture of polymers provides the selective separation of chlorosubstituted, saturated, and aromatic hydrocarbons.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Merkel, T.C., Gupta, R.P., Turk, B.S., and Freeman, B.D., J. Membr. Sci., 2001, vol. 19, p. 85.

    Article  Google Scholar 

  2. Berezkin, V.G., Popova, T.P., Shiryaeva, V.E., Kozlov, S.P., and Vlasenko, E.V., Zavod. Lab., Diagn. Mater., 2003, vol. 69, no. 10, p. 3.

    CAS  Google Scholar 

  3. Berezkin, V.G., Popova, T.P., Shiryaeva, V.E., et al., Izv. Ross. Akad. Nauk, Ser.: Khim., 2002, no. 5, p. 765.

  4. Berezkin, V.G., Mukhina, V.P., Korolev, A.A., Fatkullina, A.F., and Seroshtan, V.A., Zavod. Lab., Diagn. Mater., 2004, vol. 70, no. 5, p. 9.

    CAS  Google Scholar 

  5. Shao, L., Samseth, J., and Hagg, M.-B., J. Appl. Polymer Sci., 2009, vol. 113, p. 3078.

    Article  CAS  Google Scholar 

  6. Evlampieva, N.P., Yakimanskii, A.V., and Ryumtsev, E.I., Vysokomol. Soedin., B, 2006, vol. 48, no. 2, p. 376 [Polymer Sci., B (Engl. Transl.), vol. 48, no. 1–2, p. 51].

    Google Scholar 

  7. Khodzhaeva, V.L., Zaikin, V.G., and Khotimskii, V.S., Izv. Ross. Akad. Nauk, Ser.: Khim., 2003, no. 6, p. 1261.

  8. Grishchenko, E.I. Mikhailova, N.A., et al., Opt. Zh., 2003, vol. 70, no. 10, p. 30.

    Google Scholar 

  9. Giacinti, B.M., Ghisellini, M., et al., J. Mol. Struct., 2005, vol. 739, p. 75.

    Article  Google Scholar 

  10. Morliere, N., Vallieres, C., Perrin, L., and Roizard, D., J. Membr. Sci., 2006, vol. 270, p. 123.

    Article  CAS  Google Scholar 

  11. Starannikova, L., Khodzhaeva, V., and Yampolskii, Y., J. Membr. Sci., 2004, vol. 244, p. 183.

    Article  CAS  Google Scholar 

  12. Morisato, A., Shen, H.C., et al., J. Polymer Sci. B, 1996, vol. 34, p. 2209.

    Article  CAS  Google Scholar 

  13. Nagai, K., Mori, M., Watanabe, T., and Nakagawa, T., J. Polymer Sci. B, 1997, vol. 35, p. 119.

    Article  CAS  Google Scholar 

  14. Toy, L.G., Freeman, B.D., and Spontak, R.J., Macromolecules, 1997, vol. 30, p. 4766.

    Article  CAS  Google Scholar 

  15. Belotserkovskaya, V.Yu. and Yakovleva, E.Yu., Zh. Fiz. Khim., 2010, vol. 84, no. 2, p. 363 [Russ. J. Phys. Chem. (Engl. Transl.), vol. 84, no. 2, p. 307].

    Google Scholar 

  16. Yakovleva, E.Yu., Belotserkovskaya, V.Yu., Fadeeva, V.P., Litvak, G.S., Paukshtis, E.A., and Babushkin, D.E., Zh. Fiz. Khim., 2009, vol. 83, no. 5, p. 972 [Russ. J. Phys. Chem. (Engl. Transl.), vol. 83, no. 5, p. 849].

    Google Scholar 

  17. Supina, W.G., The Packed Column in Gas Chromatography, Supelco (USA): Pelefonte, 1974.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, pr. Lavrent’eva 5, Novosibirsk, 630090, Russia

    E. Yu. Yakovleva & V. Yu. Belotserkovskaya

Authors
  1. E. Yu. Yakovleva
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. Yu. Belotserkovskaya
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Original Russian Text © E.Yu. Yakovleva, V.Yu. Belotserkovskaya, 2011, published in Zhurnal Analiticheskoi Khimii, 2011, Vol. 66, No. 6, pp. 647–651.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Yakovleva, E.Y., Belotserkovskaya, V.Y. Chromatographic and adsorption properties of the mixed stationary phase poly(1-trimethylsilyl-1-propyne)/poly(1-phenyl-1-propyne). J Anal Chem 66, 629–633 (2011). https://doi.org/10.1134/S1061934811060219

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1061934811060219

Keywords

Search

Navigation