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Immobilization of phosphomolybdic acid on the surface of mesoporous silica functionalized with alkylammonium groups

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Abstract

Silica containing protonated 3-aminopropyl groups has been synthesized by a template method using Pluronic 123 as a surfactant in an acidic medium at a hydrochloric acid concentration of 1.72 M. The X-ray diffraction data have indicated that the obtained sample has a highly ordered hexagonal structure, which agrees with the large specific surface area and sorption pore volume (S sp = 880 m2/g, V s = 1.28 cm3/g) typical of SBA-15 materials. However, transmission electron microscopy data show that this material contains two phases, with one of them being similar to SBA-15 mesoporous silica and the other belonging to socalled “honeycomb foams.” An ion-exchange reaction has been employed to immobilize phosphomolybdic acid H3[P(Mo3O10)4] on the pore surface, and the fact of immobilization has been confirmed by IR and TGA data. This functionalization significantly reduces the S sp and V s values of the sample but has no effect on isotherm pattern, thereby attesting to retaining the silica structure after the modification.

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Authors and Affiliations

  1. Chuiko Institute of Surface Chemistry, National Academy of Sciences of Ukraine, General Naumov str. 17, Kyiv, 03164, Ukraine

    V. V. Sliesarenko, O. A. Dudarko, A. K. Matkovskii, G. R. Yurchenko & Yu. L. Zub

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  1. V. V. Sliesarenko
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  2. O. A. Dudarko
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  3. A. K. Matkovskii
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  4. G. R. Yurchenko
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  5. Yu. L. Zub
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Correspondence to V. V. Sliesarenko.

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Original Russian Text © V.V. Sliesarenko, O.A. Dudarko, A.K. Matkovskii, G.R. Yurchenko, Yu.L. Zub, 2014, published in Kolloidnyi Zhurnal, 2014, Vol. 76, No. 3, pp. 397–402.

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Sliesarenko, V.V., Dudarko, O.A., Matkovskii, A.K. et al. Immobilization of phosphomolybdic acid on the surface of mesoporous silica functionalized with alkylammonium groups. Colloid J 76, 366–371 (2014). https://doi.org/10.1134/S1061933X14020124

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  • DOI: https://doi.org/10.1134/S1061933X14020124

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