Abstract
The fabrication of photoand thermostable periodic structures from silver nanoparticles in polymer plates (cross-linked oligourethanemethacrylate impregnated with silver precursors Ag(hfac) and Ag(fod) dissolved in the supercritical carbon dioxide) is studied. The process is based on the local (depending on the irradiated spot size) photochemical decomposition of the silver precursors in the polymer matrix that initiates the atomic aggregation and creation of silver nanoparticles with the plasmon resonance in absorption in the spectral range 420–430 nm. The third-harmonic radiation of a Nd:YAG laser (355 nm) and the Kr+-laser (521 nm) radiation are employed for the recording of periodic structures with submillimeter and micron resolutions. The photosensitivity of the polymer matrices impregnated with the silver precursors to the UV and visible radiation is discussed.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
A. D. Pomogailo, A. C. Rozenberg, and E. I. Uflyand, Metal Nanoparticles in Polymers (Chemistry, Moscow, 2000) [in Russian].
A. Convertino, A. Valentini, and R. Cingolani, Appl. Phys. Lett. 75, 732 (1999).
A. Convertino, A. Capobianchi, A. A. Valentini, and E. N. M. Cirillo, Adv. Mater. 15, 1103 (2003).
V. K. Khanna, Defence Sci. J. 58, 608 (2008).
S. N. Shtykov and T. Yu. Rusanova, Ros. Khim. Zh. LII, 92 (2008).
S. M. Nie and S. R. Emory, Science 275, 1102 (1997).
G. B. Sergeev, Nanochemistry (Mosc. Gos. Univ., Moscow, 2007) [in Russian].
S. Qu, H. Zeng, C. Zhao, J. Qiu, and C. Zhu, Chem. Phys. Lett. 384, 382 (2004).
A. I. Cooper, J. Mater. Chem. 2007, 46 (2000)
S. G. Kazarian, Polymer Sci., Ser. C 42, 78 (2000).
E. N. Sobol, V. N. Bagratashvili, V. K. Popov, A. E. Sobol, E. E. Said-Galiev, and L. N. Nikitin, Zh. Fiz. Khim. 72, 23 (1998) [Phys. Chem. A 72, 17 (1988)].
E. N. Sobol, V. N. Bagratashvili, A. E. Sobol, and S. M. Howdl, Dokl. Akad. Nauk 356, 777 (1997).
V. N. Bagratashvili, Yu. S. Zavorotny, V. K. Popov, A. O. Rybaltovsky, S. I. Tsypina, and P. V. Chernov, Perspekt. Mater. 1, 35 (2002).
A. Yu. Taraeva, V. I. Gerasimova, Yu. S. Zavorotny, A. O. Rybaltovsky, and V. N. Bagratashvili, Sverhkrit. Flyuidy Teor. Prakt. 3, 59 (2008).
A. O. Rybaltovsky, A. A. Aksenov, V. N. Bagratashvili, V. I. Gerasimova, V. V. Zosimov, V. K. Popov, A. B. Solov’eva, and P. S. Timashev, Sverhkrit. Flyuidy Teor. Prakt. 3, 50 (2008).
M. A. Hugh and V. J. Krukonis, Supercritical Fluid Extraction Principles and Practice, 2nd ed. (Boston, 1994).
M. O. Galyamov, R. A. Vinokur, L. N. Nikitin, E. E. Said-Galiev, A. R. Khohlov, and K. Shaumburg, Vysokomolek. Soed. R 44, 946 (2002) [Polymer. Sci., Ser. A 44, 581 (2002)].
A. O. Rybaltovsky, A. A. Aksenov, V. I. Gerasimova, Yu. S. Zavorotny, V. K. Popov, V. V. Zosimov, and V. N. Bagratashvili, Sverhkrit. Flyuidy Teor. Prakt. 3, 74 (2008).
V. I. Gerasimova, Yu. S. Zavorotny, A. O. Rybaltovsky, A. Yu. Taraeva, S. I. Tsypina, and V. N. Bagratashvili, Opt. Spektrosk. 98, 633 (2005) [Opt. Spectrosc. 98, 564 (2005)].
P. T. Dao and A. J. J. Twarowski, Chem. Phys. 85, 6823 (1986).
M. T. Berry, P. S. May, and H. Xu, J. Phys. Chem. 100, 9216 (1996).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © Astro, Ltd., 2010.
Rights and permissions
About this article
Cite this article
Bagratashvili, V.N., Minaev, N.V., Rybaltovsky, A.A. et al. Laser fabrication of periodic microstructures from silver nanoparticles in polymer films. Laser Phys. 20, 139–143 (2010). https://doi.org/10.1134/S1054660X09180017
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1054660X09180017