Abstract
Model samples of nanostructures are synthesized with the use of transition metals, with a different number of d electrons and sp elements of groups II and III with a different number of valence p electrons, as modifiers. The activity of nanostructure synthesis is investigated depending on the addition of sp elements. A procedure is developed for determining the atomic magnetic moment of the d metals and the change in the distances between atoms of the metal and the sp element via the parameters of the X-ray photoelectron spectrum of transition metals, which allows the degree of hybridization of valence electrons in the chemical bond of adjacent atoms (Me-X) to be determined. As a result of the investigation the laws of nanoform growth are found which facilitate the development of new directions in the synthesis of nanostructures with unique properties.
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Original Russian Text © I.N. Shabanova, N.S. Terebova, 2012, published in Poverkhnost’. Rentgenovskie, Sinkhrotronnye i Neitronnye Issledovaniya, 2012, No. 11, pp. 12–17.
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Shabanova, I.N., Terebova, N.S. Investigation of the formation of the electron structure of metallocarbonic nanoforms. J. Surf. Investig. 6, 882–886 (2012). https://doi.org/10.1134/S1027451012110092
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DOI: https://doi.org/10.1134/S1027451012110092