Skip to main content
SpringerLink
Log in

Regularities of electrochemical behavior of polyaniline doped by electroactive anions

  • Published:
Russian Journal of Electrochemistry Aims and scope Submit manuscript

Abstract

Electrochemical potentiodynamic and potentiostatic synthesis is used to obtain polyaniline (PANI) modified by new electroactive anions: organic dianion of the diammonium salt of 2,2′-azinobis(3-ethylbenzothiazoline-6-sulfo acid) (ABTS) and inorganic ammonium hexachloroiridate dianion IrCl 2−6 (HCI). Electrochemical behavior of the modified PANI-ABTS and PANI-HCI polymers is studied by means of the meth ods of cyclic voltammetry (CV) and charge-discharge dependences. It is shown that modified PANI-ABTS and PANI-HCI remain electroactive at much higher potential sweep rates as compared to PANI doped by HSO −4 (PANI-sulfo). Electrochemical capacity values are calculated on the basis of the data of CVs and discharge curves and coulombic efficiency of the new polymers that exceeds significantly the corresponding values for PANI-sulfo. This effect is enhanced when the ABTS and HCI additives are introduced into the supporting electrolyte in all electrochemical processes.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Pron, A. and Rannou, P., Progr. Polym. Sci., 2002, vol. 27, p. 135.

    Article  CAS  Google Scholar 

  2. Zotti, G., Cattarin, S., and Comisso, N., J. Electroanal. Chem., 1988, vol. 239, p. 387.

    Article  CAS  Google Scholar 

  3. Vol’fkovich, Yu.M., Zolotova, T.K., Levi, M.D., and Letuchii, Ya.L., Elektrokhimiya, 1993, vol. 29, p. 994 [Russ. J. Electrochem. (Engl. Transl.), 1993, vol. 29, p. 856].

    Google Scholar 

  4. Aguirre, M.J. and Zagal, J.H., J. Appl. Electrochem., 1994, vol. 24, p. 1059.

    Google Scholar 

  5. Aguirre, M.J., Retamal, B.A., Ureta-Zanartu, M.S., Zagal, J.H., Cordova, R., Schrebler, R., and Biaggio, S.R., J. Electroanal. Chem., 1992, vol. 328, p. 349.

    Article  CAS  Google Scholar 

  6. Majidi, R., Kanemaguire, L.A.P., and Wallace, G.G., Aust. J. Chem., 1998, vol. 51, p. 23.

    Article  CAS  Google Scholar 

  7. Abd El-Rahman, H.A., Polym. Int., 1997, vol. 44, p. 481.

    Article  CAS  Google Scholar 

  8. Sahin, Y., Pekmez, K., and Yildiz, A., Synth. Met., 2002, vol. 129, p. 107.

    Article  CAS  Google Scholar 

  9. LaCroix, J.-C. and Diaz, A.F., Macromol. Chem. Macromol. Symp., 1987, vol. 8, p. 17.

    Article  CAS  Google Scholar 

  10. Komura, T., Mori, K., Yamaguchi, T., and Takahashi, K., Bull. Chem. Soc., 2000, vol. 73, p. 19.

    Article  CAS  Google Scholar 

  11. Motheo, A.J., Santos, J.R., Venancio, E.C., Mattoso, L.H.C., Polymer, 1998, vol. 39, p. 6977.

    Article  CAS  Google Scholar 

  12. Sun, L., Liu, H., Clark, R., and Yang, S.C., Synth. Met., 1997, vol. 84, p. 67.

    Article  CAS  Google Scholar 

  13. Ivanov, V.F., Gribkova, O.L., Cheberyako, K.V., Nekrasov, A.A., Tverskoi, V.A., and Vannikov, L.Ya., Elektrokhimiya, 2004, vol. 40, p. 339 [Russ. J. Electrochem. (Engl. Transl.), 2004, vol. 40, p. 299].

    Google Scholar 

  14. Liu, W., Anagnostopoulos, A., Bruno, F.F., Senecal, K., Kumar, J., Tripathy, S., and Samuelson, L., Synth. Met., 1999, vol. 101, p. 738.

    Article  CAS  Google Scholar 

  15. Samuelson, L., Liu, W., Nagarajan, R., Kumar, J., Bruno, F.F., Cholli, A., and Tripathy, S., Synth. Met., 2001, vol. 119, p. 271.

    Article  CAS  Google Scholar 

  16. Cheung, J.H., Stockton, W.B., and Rubner, M.F., Macromolecules, 1997, vol. 30, p. 2712.

    Article  CAS  Google Scholar 

  17. Abdullin, T.N., Nikitina, N.I., Evtyugin, G.A., Budnikov, G.K., and Mananova, L.Z., Elektrokhimiya, 2007, vol. 41, p. 1355 [Russ. J. Electrochem. (Engl. Transl.), 2007, vol. 43, p. 1284].

    Google Scholar 

  18. DeLongchamp, D. and Hammond, P.T., Adv. Mater., 2001, vol. 13, p.1455.

    Article  Google Scholar 

  19. Men’shikova, I.M., Pyshkina, O.A., and Men’shikov, E.A., Vysokomol. Soedin., 2009, vol. 51, no. 6, p. 1008.

    Google Scholar 

  20. Barisci, J.N., Innis, R.S., Maguire, L.A.R., Norris, L.D., and Wallace, G.G., Synth. Met., 1997, vol. 84.

  21. Odin, C. and Nechtschein, M., Synth. Met., 1991, vols. 41–43, p. 2943.

    Article  Google Scholar 

  22. Odin, C. and Nechtschein, M., Synth. Met., 1993, vols. 55–57, p. 1287.

    Article  Google Scholar 

  23. Rudzinski, W.E., Lozano, L., and Walker, M., J. Electrochem. Soc., 1990, vol. 137, p. 3132.

    Article  CAS  Google Scholar 

  24. Kalaji, M., Nyholm, L., and Peter, L.M., J. Electroanal. Chem., 1991, vol. 313, p. 271.

    Article  CAS  Google Scholar 

  25. Grande, H. and Otero, T.F., Electrochim. Acta, 1999, vol. 44, p. 1893.

    Article  CAS  Google Scholar 

  26. Otero, T.F. and Grande, H., J. Electroanal. Chem., 1996, vol. 414, p. 171.

    Article  Google Scholar 

  27. Tezuka, Y., Aoki, K., Yajima, H., and Ishii T., J. Electroanal. Chem., 1997, vol. 425, p. 167.

    Article  CAS  Google Scholar 

  28. Teragishi, Y. and Aoki, K., J. Electroanal. Chem., 1999, vol. 473, p. 132.

    Article  CAS  Google Scholar 

  29. Elektrokhimiya polimerov (Electrochemistry of Polymers), Tarasevich, M.R. and Orlov, S.B., Eds., Moscow: Nauka, 1990, p. 131.

    Google Scholar 

  30. Fraoua, K., Delamar, M., and Andrieux, C.P., Synth. Met., 1998, vol. 97, p. 91.

    Article  CAS  Google Scholar 

  31. Sintez kompleksnykh soedinenii metallov platinovoi gruppy (Synthesis of Complex Compounds of Platinum Group Metals), Chernyaev, I.I., Ed., Moscow: Nauka, 1964, p. 251.

    Google Scholar 

  32. Abalyaeva, V.V. and Efimov, O.N., Elektrokhimiya, 2010, vol. 46, p. 605 [Russ. J. Electrochem. (Eng. Transl.), 2010, vol. 46, p. 571].

    Google Scholar 

  33. Abalyaeva, V.V. and Efimov, O.N., Elektrokhimiya, 2011, vol. 47, no. 11 [Russ. J. Electrochem. (Eng. Transl.), 2011, vol. 47, no. 11].

  34. Abalyaeva, V.V., Kulikov, A.V., and Efimov, O.N., Vysokomol. Soed., Ser. Khim., 1997, vol. 39, p. 216.

    CAS  Google Scholar 

  35. Lapkovski, M. and Vieil, E., Synth. Met., 2000, vol. 109, p. 199.

    Article  Google Scholar 

  36. Hao, Q., Lei, W., Xia, X., Yan, Z., Yang, X., Lu, I., and Wang, X., Electrochim. Acta, 2010, vol. 58, p. 632.

    Article  Google Scholar 

  37. Khomenko, V., Frackowiak, T., and Beguin, F., Electrochim. Acta, 2005, vol. 50, p. 2499.

    Article  CAS  Google Scholar 

  38. Park, J.M., Ko, J.M., Park, O.O., and Kim D.-W., J. Power Sources, 2002, vol. 105, p. 20.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow oblast, 142432, Russia

    V. V. Abalyaeva & O. N. Efimov

Authors
  1. V. V. Abalyaeva
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. O. N. Efimov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to V. V. Abalyaeva.

Additional information

Original Russian Text © V.V. Abalyaeva, O.N. Efimov, 2011, published in Elektrokhimiya, 2011, Vol. 47, No. 11, pp. 1397–1406.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Abalyaeva, V.V., Efimov, O.N. Regularities of electrochemical behavior of polyaniline doped by electroactive anions. Russ J Electrochem 47, 1307–1316 (2011). https://doi.org/10.1134/S1023193511110036

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1023193511110036

Keywords

Search

Navigation