Abstract
The temperature curves of the ultimate high-frequency electroconductivity of water and acetonitrile were analyzed. The temperature curves of specific electroconductivity of aqueous 0.1 M sodium chloride solution and acetonitrile 0.1 M 1-butyl-3-methylimidazol trifluoromethane sulfonate were compared. The electroconductivity activation energy of solutions was found coinciding with the ultimate high-frequency electroconductivity activation energy of solvents within the experimental error. The specific electroconductivity of solutions was shown to increase at higher temperature in direct proportion to the ultimate high-frequency electroconductivity of solvents.
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Original Russian Text © V.V. Shcherbakov, Yu.M. Artemkina, N.V. Pleshkova, K.R. Seddon, 2009, published in Elektrokhimiya, 2009, Vol. 45, No. 8, pp. 986–988.
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Shcherbakov, V.V., Artemkina, Y.M., Pleshkova, N.V. et al. Ultimate high-frequency conductivity of solvent and electroconductivity of electrolyte solutions. Russ J Electrochem 45, 922–924 (2009). https://doi.org/10.1134/S1023193509080138
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DOI: https://doi.org/10.1134/S1023193509080138