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Composite polymer hydrogels

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Abstract

Methods of preparing and properties of composite hydrogels based on various hydrophilic polymers and their mixtures with inorganic nanosized additives are considered. The effect of the type of physical or covalent bonding between components on the formation of composite hydrogels and their characteristics is discussed. The biphasic character of composite hydrogels determines as a rule their advantages as supersorbents, membrane materials, living-tissue substitutes, drug carriers, and soft-contact-lens materials.

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References

  1. N. A. Plate, A. D. Litmanovich, and O. V. Noah, Macromolecular Reactions. Peculiarities, Theory, Experimental Approaches (Khimiya, Moscow, 1977; Wiley, New York, 1995).

    Google Scholar 

  2. A. B. Zezin and V. A. Kabanov, Usp. Khim. 51, 1447 (1982).

    CAS  Google Scholar 

  3. E. A. Bekturov and L. A. Bimendina, Interpolymer Complexes (Alma-Ata, 1977) [in Russian].

  4. V. A. Kabanov, Polymer Science, Ser. A 36, 143 (1994) [Vysokomol. Soedin., Ser. A 36, 183 (1994)].

    Google Scholar 

  5. V. A. Kabanov and A. B. Zezin, Itogi Nauki Tekh., Ser. Org. Khim. 5, 131 (1984).

    CAS  Google Scholar 

  6. Y. Osada and M. Sato, J. Polym. Sci., Part C: Polym. Lett. 14, 129 (1976).

    CAS  Google Scholar 

  7. T. Tsuchida and K. Abe, Adv. Polym. Sci. 45, 1 (1982).

    Article  Google Scholar 

  8. S. G. Starodubtsev and O. E. Filippova, Polymer Science, 34, 602 (1992) [Vysokomol. Soedin., Ser. B, 34, 72 (1992)].

    Google Scholar 

  9. X. Yu, A. Tanaka, K. Tanaka, and T. Tanaka, J. Chem. Phys. 97, 7805 (1992).

    Article  CAS  Google Scholar 

  10. O. E. Philippova, N. S. Karybiants, and S. G. Starodubtzev, Macromolecules 27, 2398 (1994).

    Article  CAS  Google Scholar 

  11. N. S. Karybiants, O. E. Philippova, S. G. Starodubtsev, and A. R. Khokhlov, Makromol. Chem. Phys. 197, 2373 (1996).

    Article  CAS  Google Scholar 

  12. F. Bordi, G. Paradossi, C. Rinaldi, and B. Ruzicka, Physica A (Amsterdam) 304, 119 (2002).

    CAS  Google Scholar 

  13. V. V. Khutoryanskiy, G. A. Mun, Z. S. Nurkeeva, and A. V. Dubolazov, Polym. Int. 53, 1382 (2004).

    Article  CAS  Google Scholar 

  14. D. Magnin, J. Lefebvre, E. Chornet, and S. Dumitriu, Carbohydr. Polym. 55, 437 (2004).

    Article  CAS  Google Scholar 

  15. R. Josephs and J. Feitelson, J. Polym. Sci., Part A 1, 3385 (1963).

    Article  Google Scholar 

  16. A. Michaels, in Encyclopedia of Polymer Science and Technology, 1969, Vol. 10, p. 765.

    Google Scholar 

  17. K. Y. Mi, K. S. Yong, M. L. Young, and S. C. Chong, Polymer 39, 3703 (1998).

    Article  Google Scholar 

  18. F. Yoshii, Y. Zhanshan, K. Isobe, et al., Radiat. Phys. Chem. 55, 133 (1999).

    Article  CAS  Google Scholar 

  19. C. Tranquilan-Aranilla, F. Yoshii, A. M. Dela Rosa, and K. Makuuchi, Radiat. Phys. Chem. 55, 127 (1999).

    Article  CAS  Google Scholar 

  20. I. R. Rodrigues, M. M. De Camargo Forte, D. S. Azambuja, and K. R. L. Castagno, React. Funct. Polym. 67, 708 (2007).

    Article  CAS  Google Scholar 

  21. R. Zhang, Polymer 46, 2443 (2005).

    Article  CAS  Google Scholar 

  22. I. C. Alupei, M. Popa, M. Hamcerencu, and M. J. M. Abadie, Eur. Polym. J. 38, 2313 (2002).

    Article  CAS  Google Scholar 

  23. A. Nakayama, A. Kakugo, J. P. Gong, et al., Adv. Funct. Mater. 14, 1124 (2004).

    Article  CAS  Google Scholar 

  24. A. Noshay and J. McGrath, Block Copolymers (Academic, New York, 1977; Mir, Moscow, 1980).

    Google Scholar 

  25. H. A. J. Battaerd and G. W. Tregear, Graft Copolymers (Wiley, New York; Khimiya, Leningrad, 1970).

    Google Scholar 

  26. G. Erdodi and J. P. Kennedy, Prog. Polym. Sci. 31, 1 (2006).

    Article  CAS  Google Scholar 

  27. A. Pourjavadi, M. Sadedhi, M. M. Hashemi, and H. Hosseinzadeh, e-Polymer, No. 057 (2006); http://www.e-polymers.org

  28. Y. Kaneko, S. Nakamura, K. Sakai, et al., Polym. Gels Networks 6, 333 (1998).

    Article  CAS  Google Scholar 

  29. S. Hirotsu, Adv. Polym. Sci. 110, 1 (1993).

    Article  CAS  Google Scholar 

  30. D. Kuckling, H. P. Adler, K. F. Arbdt, et al., Macromol. Chem. Phys. 220, 273 (2000).

    Article  Google Scholar 

  31. B. Tasdelen, N. Kayman-Apohan, Z. Misirli, et al., J. Appl. Polym. Sci. 97, 1115 (2005).

    Article  CAS  Google Scholar 

  32. D. Christova, S. Ivanova, B. Trzebicka, et al., e-Polymer, No. 042 (2003); http://www.e-polymers.org

  33. B. Yodhong, S. Mangkorn, J. Threeprom, et al., e-Polymer, No. 138 (2007); http://www.3-polymers.org

  34. G. A. Mun, Z. S. Nurkeeva, S. A. Dergunov, et al., React. Funct. Polym. 68, 389 (2008).

    Article  CAS  Google Scholar 

  35. M. R. Guilherme, A. F. Da Silva Rubira, G. Geuskens, and E. C. Muniz, React. Funct. Polym. 61, 233 (2004).

    Article  CAS  Google Scholar 

  36. M. R. Guilherme, G. M. Campese, E. Radovanovic, et al., J. Membr. Sci. 275, 187 (2006).

    Article  CAS  Google Scholar 

  37. G. Alonso, J. L. Rivera, A. M. Mendoza, and M. L. Mendez, e-Polymer, No. 150 (2007); http://www.e-polymers.org

  38. M. D. Kurkuri and T. M. Aminabhavi, J. Controlled Release 96, 9 (2004).

    Article  CAS  Google Scholar 

  39. S. J. Kim, S. G. Yoon, Y. M. Lee, and S. I. Kim, Sens. Actuators, B 88, 286 (2003).

    Article  Google Scholar 

  40. Y. M. Mohan, P. S. K. Murthy, J. Sreeramulu, and K. M. Raju, J. Appl. Polym. Sci. 98, 302 (2005).

    Article  CAS  Google Scholar 

  41. A. Bilia, V. Carelli, G. Di Colo, and E. Nannipieri, Int. J. Pharm. 130, 83 (1996).

    Article  CAS  Google Scholar 

  42. D. Myung, W. Koh, J. Ko, et al., Polymer 48, 5376 (2007).

    Article  CAS  Google Scholar 

  43. G. Burillo, M. Briones, and E. Adem, Nucl. Instrum. Methods Phys. Res., Sect. B 265, 104 (2007).

    Article  CAS  Google Scholar 

  44. E. Díez-Peña, I. Quijada-Garrido, and J. M. Barrales-Rienda, Polymer 43, 4341 (2002).

    Article  Google Scholar 

  45. B. Guo, J. Yuan, and Q. Gao, e-Polymers, No. 082 (2006); http://www.e-polymers.org

  46. M. Ilavský, G. Mamytbekov, L. Hanyková, and K. Dusek, Eur. Polym. J. 38, 875 (2002).

    Article  Google Scholar 

  47. S. S. Ivanchev, O. N. Primachenko, V. N. Pavlyuchenko, and S. Ya. Khaikin, Zh. Prikl. Khim. (St.-Petersburg) 81, 1134 (2008).

    Google Scholar 

  48. S. S. Ivanchev, V. N. Pavlyuchenko, O. N. Primachenko, et al., Preprint No. 2770 (St. Petersburg Inst. of Nuclear Physics, Russian Academy of Sciences, 2008).

  49. D. J. Highgate, US Patent No. 7318972 (2008).

  50. D. J. Highgate and J. A. Lloyd, US Patent No. 7318888 (2008).

  51. D. J. Highgate, J. A. Lloyd, S. Bourne, and R. L. Smith, WO Patent No. 124915 (2005).

  52. D. J. Highgate, K. V. Lovell, and J. A. Horsfall, WO Patent No. 131758 (2006).

  53. D. Kim and K. Park, Polymer 45, 189 (2004).

    Article  CAS  Google Scholar 

  54. Y. M. Mohan and K. E. Geckeler, React. Funct. Polym. 67, 144 (2007).

    Article  CAS  Google Scholar 

  55. G. R. Mahdavinia, A. Pourjavadi, and M. J. Zohuriaan-Mehr, J. Appl. Polym. Sci. 99, 1615 (2005).

    Article  CAS  Google Scholar 

  56. Y. H. Bae and S. W. Kim, Adv. Drug Delivery Rev. 11, 109 (1993).

    Article  CAS  Google Scholar 

  57. B. C. Kim, G. Spinks, C. O. Too, et al., React. Funct. Polym. 44, 31 (2000).

    Article  CAS  Google Scholar 

  58. H. Masunaga, K. Sasaki, and I. Akiba, e-Polymers, No. 022 (2006); http://www.e-polymers.org

  59. J. Scherble, R. Thomann, B. Ivan, and R. Mulhaupt, J. Polym. Sci., Part B: Polym. Phys. 39, 1429 (2001).

    Article  CAS  Google Scholar 

  60. A. Domjan, G. Erdoedi, M. Wilhelm, et al., Macromolecules 36, 9107 (2003).

    Article  CAS  Google Scholar 

  61. K. Suevegh, A. Domjan, Gy. Vanko, et al., Macromolecules 31, 7770 (1998).

    Article  CAS  Google Scholar 

  62. T. Kiguchi, H. Aota, and A. Matsumoto, J. Appl. Polym. Sci. 94, 1198 (2004).

    Article  CAS  Google Scholar 

  63. M. Doura, Y. Naka, H. Aota, and A. Matsumoto, Macromolecules 36, 8477 (2003).

    Article  CAS  Google Scholar 

  64. M. Doura, Y. Naka, H. Aota, and A. Matsumoto, Macromolecules 38, 5955 (2005).

    Article  CAS  Google Scholar 

  65. N. Bruns, J. Scherble, L. Hartmann, et al., Macromolecules 38, 2431 (2005).

    Article  CAS  Google Scholar 

  66. J. C. Tiller, L. Hartmann, and J. Scherble, Surf. Coat. Int., B1 88, 49 (2005).

    Article  CAS  Google Scholar 

  67. J. C. Tiller, C. Sprich, and L. Hartmann, J. Controlled Release 103, 355 (2005).

    Article  CAS  Google Scholar 

  68. B. Keszler, J. P. Kennedy, and P. W. Mackey, J. Controlled Release 25, 115 (1993).

    Article  CAS  Google Scholar 

  69. D. Christova, R. Velichkova, E. J. Goethals, and F. E. Du Prez, Polymer 43, 4585 (2002).

    Article  CAS  Google Scholar 

  70. P. Adriaensens, L. Storme, R. Carleer, et al., Macromolecules 35, 3965 (2002).

    Article  CAS  Google Scholar 

  71. K. Cosaert, E. Eeckhout, E. Goethals, et al., Polym. Int. 51, 1231 (2002).

    Article  CAS  Google Scholar 

  72. S. R. Walraedt and E. J. Goethals, Polym. Int. 38, 89 (1995).

    Article  CAS  Google Scholar 

  73. M. A. Lagutina, G. V. Rakova, N. V. Yarygina, et al., Polymer Science, Ser. A 44, 811 (2002) [Vysokomol. Soedin., Ser. A 44, 1295 (2002)].

    Google Scholar 

  74. G. V. Rakova, M. A. Lagutina, S. A. Dubrovskii, and K. S. Kazanskii, Polymer Science, Ser. B 44, 135 (2002) [Vysokomol. Soedin., Ser. B 44, 872 (2002)].

    Google Scholar 

  75. T. K. Georgiou, M. Vamvakaki, and C. S. Patrickios, Polymer 45, 7341 (2004).

    Article  CAS  Google Scholar 

  76. E. Loizou, A. I. Triftaridou, T. K. Georgiou, et al., Biomacromolecules 4, 1150 (2003).

    Article  CAS  Google Scholar 

  77. M. R. Simmons, E. N. Yamasaki, and C. S. Patrickios, Macromolecules 33, 3176 (2000).

    Article  CAS  Google Scholar 

  78. S. Yamashita, K. Kodama, Y. Ikeda, and S. Kohjiya, J. Polym. Sci., Part A: Polym. Chem. 31, 2437 (1993).

    Article  CAS  Google Scholar 

  79. Y. Ikeda, K. Kodama, K. Kajiwara, and S. Kohjiya, J. Polym. Sci., Part B: Polym. Phys. 33, 387 (1995).

    Article  CAS  Google Scholar 

  80. G. Erdoedi and B. Ivan, Chem. Mater. 16, 959 (2004).

    Article  CAS  Google Scholar 

  81. G. Erdodi, A. Janecska, and B. Ivan, Polym. Networks Group Rev. Ser. 2, 73 (1999).

    CAS  Google Scholar 

  82. H. S. Mansur, R. L. Orefice, and A. A. P. Mansur, Polymer 45, 7193 (2004).

    Article  CAS  Google Scholar 

  83. R. E. Bambury and D. Seelye, US Patent No. 5070215 (1991).

  84. Y.-C. Lai, US Patent No. 6359024 (2002).

  85. Y.-C. Lai, G. D. Friends, and J. Valint, US Patent No. 5352714 (1994).

  86. M. P. Nandu, R. S. Bawa, and Y.-C. Lai, US Patent No. 5,260,000 (1993).

  87. Y.-C. Lai and P. L. Valint, Jr., J. Appl. Polym. Sci. 61, 2051 (1998).

    Article  Google Scholar 

  88. J. Kunzler and R. Ozark, US Patent No. 5321108 (1994).

  89. B. Tighe, in Silicone Hydrogels: The Rebirth of Continuons Wear Contact Lenses, Ed. by D. Sweeney (Oxford, 2000), p. 1.

  90. J. Valint, US Patent No. 5,135,297 (1992).

  91. G. L. Grobe, J. R. Valint, J. R. Ammon, and J. A. McGee, US Patent No. 6200626 (2001).

  92. J. R. Valint, G. L. Grobe, J. R. Ammon, and M. J. Mooreheaf, US Patent No. 2003/0039748 (2003).

  93. I. Barakat, Ph. Dubois, Ch. Grandfils, and R. Jerome, J. Polym. Sci., Part A: Polym. Chem. 37, 2401 (2005).

    Article  Google Scholar 

  94. F. E. Du Prez, E. J. Goethals, R. Schué, et al., Polym. Int. 46, 117 (1999).

    Article  Google Scholar 

  95. M. Licht, R. Schmidt, A. Hansmann, and S. Herrman, DE Patent No. 2518904 (1975).

  96. N. A. Peppas and L. Brannon-Peppas, J. Membr. Sci. 48, 281 (1990).

    Article  CAS  Google Scholar 

  97. C. Plesse, F. Vidal, C. Gauthier, et al., Polymer 48, 696 (2007).

    Article  CAS  Google Scholar 

  98. C. Erbil, E. Kazancioglu, and N. Uyanik, Eur. Polym. J. 40, 1145 (2004).

    Article  CAS  Google Scholar 

  99. J. S. Turner and J.-L. Cheng, Macromolecules 36, 1962 (2003).

    Google Scholar 

  100. N. L. Vlasova, G. V. Grigoryan, V. F. Danilichev, et al., RF Patent No. 2 269 552 (2006).

  101. E. V. Boiko, N. L. Vlasova, V. F. Danilichev, et al., Glaz, No. 5, 2 (2004).

  102. N. A. Chekina, V. N. Pavlyuchenko, V. F. Danilichev, et al., Polym. Adv. Technol. 17, 872 (2006).

    Article  CAS  Google Scholar 

  103. N. A. Chekina, V. N. Pavlyuchenko, N. L. Vlasova, and S. S. Ivanchev, in Proceedings of European Polymer Congress 2005, Moscow, 2005, p. 93.

  104. S. S. Ivanchev, V. N. Pavlyuchenko, N. A. Chekina, et al., in Proceedings of 8 International Symposium on Polymers for Advanced Technologies, Budapest, 2005, p. 36.

  105. V. F. Danilichev, S. F. Novikov, and V. N. Pavlyuchenko, Sovrem. Optometriya, No. 3, 24 (2007).

  106. A. C. Maiden, D. G. Vanderlaan, D. C. Turner, et al., US Patent No. 6367929 (2002).

  107. D. J. Vanderlaan, D. J. Ford, A. Alli, et al., WO Patent No. 03/022322 (2003).

  108. L. Dzhons and K. Damblton, Sovrem. Optometriya, No. 3, 12 (2007).

  109. S. Ivanchev, V. Pavlyuchenko, O. Primachenko, and A. Bobasheva, in Proceedings of European Polymer Congress, Portoroz, 2007, p. 106.

  110. Encyclopedia of Polymers, Ed. by V. A. Kargin (Sovetskaya Entsiklopediya, Moscow, 1972) [in Russian].

    Google Scholar 

  111. D. Liang-Chang, Y. Qi, and A. S. Hoffman, J. Controlled Release 19, 171 (1992).

    Article  Google Scholar 

  112. P. Chetoni, G. Di Colo, M. Grandi, et al., Eur. J. Pharm. Biopharm. 46, 125 (1998).

    Article  CAS  Google Scholar 

  113. B. Oh, D. Vissers, Z. Zhang, et al., J. Power Sources 119, 442 (2003).

    Article  CAS  Google Scholar 

  114. J. Erdodi and J. P. Kennedy, J. Polym. Sci., Part A: Polym. Chem. 43, 3491 (2005).

    Article  CAS  Google Scholar 

  115. S. K. Siddhanta and R. Gangopadhyay, Polymer 46, 2993 (2005).

    Article  CAS  Google Scholar 

  116. L. M. Lira and S. I. Cordoba de Torresi, Electrochem. Commun. 7, 717 (2005).

    Article  CAS  Google Scholar 

  117. C. Dispenza, G. Fiandaca, C. Lo Presti, et al., Radiat. Phys. Chem. 76, 1371 (2007).

    Article  CAS  Google Scholar 

  118. S. Brahim, D. Narinesingh, and A. Guiseppi-Elie, Biosens. Bioelectron. 17, 53 (2002).

    Article  CAS  Google Scholar 

  119. K. Gilmore, A. J. Hodgson, B. Luan, et al., Polym. Gels Networks 2, 135 (1994).

    Article  CAS  Google Scholar 

  120. C. J. Small, C. O. Too, and G. G. Wallace, Polym. Gels Networks 5, 135 (1997).

    Article  Google Scholar 

  121. B. C. Kim, G. Spinks, C. O. Too, et al., React. Funct. Polym, 44, 31 (2000).

    Article  CAS  Google Scholar 

  122. K. Xu, J. Wang, S. Xiang, et al., Comput. Sci. Technol. 67, 3480 (2007).

    Article  CAS  Google Scholar 

  123. N. A. Churochkina, S. G. Starodoubtsev, and A. R. Khokhlov, Polym. Gels Networks 6, 205 (1998).

    Article  CAS  Google Scholar 

  124. Y. Xiang, Z. Peng, and D. Chen, Eur. Polym. J. 42, 2125 (2006).

    Article  CAS  Google Scholar 

  125. K. V. Durme, B. V. Mele, W. Loos, and F. E. Du Prez, Polymer 46, 9851 (2005).

    Article  CAS  Google Scholar 

  126. Y. Ma, Y. Lin, Y. Jiang, et al., e-Polymers, No. 146 (2007); http://www.e-polymers.org

  127. V. A. Danilichev, S. S. Ivanchev, S. A. Novikov, et al., Sovrem. Optometriya, No. 9, 11 (2007).

  128. Y. Xiang and D. Chen, Eur. Polym. J. 43, 4178 (2007).

    Article  CAS  Google Scholar 

  129. V. Thomas, M. M. Yallapu, B. Sreedhar, and S. K. Bajpai, J. Colloid Interface Sci. 315, 389 (2007).

    Article  CAS  Google Scholar 

  130. P. S. K. Murthy, Y. M. Mohan, K. Varaprasad, et al., J. Colloid Interface Sci. 318, 217 (2008).

    Article  CAS  Google Scholar 

  131. Y. M. Mohan, K. Lee, T. Premkumar, and K. E. Geckeler, Polymer 48, 158 (2007).

    Article  CAS  Google Scholar 

  132. D. Guowei, K. Adriane, X. Z. Chen, et al., Int. J. Pharm. 328, 78 (2007).

    Article  CAS  Google Scholar 

  133. T.-Y. Liu, S.-H. Hu, K.-H. Liu, et al., J. Controlled Release 126, 228 (2008).

    Article  CAS  Google Scholar 

  134. C. Menager, O. Sandre, J. Mangili, and V. Cabuil, Polymer 45, 2475 (2004).

    Article  CAS  Google Scholar 

  135. S. Starodubtsev, E. Lavrentyeva, A. Khokhlov, et al., in Proceedings of European Polymer Congress 2005, Moscow, 2005, p. 96.

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Original Russian Text © V.N. Pavlyuchenko, S.S. Ivanchev, 2009, published in Vysokomolekulyarnye Soedineniya, Ser. A, 2009, Vol. 51, No. 7, pp. 1075–1095.

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Pavlyuchenko, V.N., Ivanchev, S.S. Composite polymer hydrogels. Polym. Sci. Ser. A 51, 743–760 (2009). https://doi.org/10.1134/S0965545X09070013

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