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Hydrodeoxygenation of Palmitic and Stearic Acids on Phosphide Catalysts Obtained In Situ in Reaction Medium

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Abstract

Unsupported phosphide catalysts of composition Ni2P and CoP are prepared in situ in the reaction medium from oil-soluble precursors in the course of hydrodeoxygenation of palmitic and stearic acids. The obtained catalysts are characterized by X-ray powder diffraction and X-ray photoelectron spectroscopy; they show high activity in the hydrodeoxygenation of model substrates. After 6 h of the hydrodeoxygenation reactions, the conversion of palmitic acid reaches 93 and 92% and the conversion of stearic acid is as high as 94 and 91% in the presence of nickel phosphide and cobalt phosphide, respectively. It is shown that the catalyst formed in situ can be isolated and recycled.

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  1. https://www.uop.com/processing-solutions/renewables/green-diesel.

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Funding

This work was carried out within the State Program of TIPS RAS

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Authors and Affiliations

  1. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 119991, Moscow, Russia

    M. A. Golubeva & A. L. Maksimov

  2. Faculty of Chemistry, Moscow State University, 119991, Moscow, Russia

    A. L. Maksimov

Authors
  1. M. A. Golubeva
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  2. A. L. Maksimov
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Correspondence to M. A. Golubeva.

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CONFLICT OF INTEREST

A.L. Maximov is the editor-in-chief of the journal Petroleum Chemistry; M.A. Golubeva declares that there is no conflict of interest.

ADDITIONAL INFORMATION

M.A. Golubeva, ORCID: http://orcid.org/0000-0002-3741-7833

A.L. Maximov, ORCID: http://orcid.org/0000-0001-9297-4950

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Translated by V. Avdeeva

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Golubeva, M.A., Maksimov, A.L. Hydrodeoxygenation of Palmitic and Stearic Acids on Phosphide Catalysts Obtained In Situ in Reaction Medium. Pet. Chem. 59, 1326–1330 (2019). https://doi.org/10.1134/S0965544119120041

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