Skip to main content
SpringerLink
Log in

Thermal and plasmochemical activation of the zirconia-supported copper catalyst for ethanol dehydrogenation

  • Chemical Kinetics and Catalysis
  • Published:
Russian Journal of Physical Chemistry A Aims and scope Submit manuscript

Abstract

It was shown that copper-containing nanocomposites based on t-zirconium dioxide 5% Cu/t-ZrO2 can be activated using preliminary treatments in high-frequency (HF) hydrogen plasma and critical low-temperature treatments. The increased activity was explained by the formation of many active centers due to the creation of additional t-zirconia defects as a result of the redistribution of copper ions on its surface before the reductive treatment.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. T. Yamaguchi, Catal. Today 20, 199 (1994).

    Article  CAS  Google Scholar 

  2. N. Shimodaa, Sh. Umehara, et al., Appl. Catal. A 507, 56 (2015).

    Article  Google Scholar 

  3. I. Rossettia, J. Lassoa, et al., Appl. Catal. B 150–151, 257 (2014).

    Article  Google Scholar 

  4. V. Nichelea, M. Signorettoa, et al., Appl. Catal. B 150–151, 12 (2014).

    Article  Google Scholar 

  5. K. T. Jung and A. T. Bell, Catal. Lett. 80, 63 (2002).

    Article  CAS  Google Scholar 

  6. J. B. Ko, Ch. M. Bac, Yu. Sh. Jung, and D. H. Kim, Catal. Lett. 105, 157 (2005).

    Article  CAS  Google Scholar 

  7. J. P. Breen and J. R. H. Ross, Catal. Today 51, 521 (1999).

    Article  CAS  Google Scholar 

  8. H. Purnama, T. Ressler, and R. E. Jentoft, Appl. Catal., A 259, 83 (2004).

    Article  CAS  Google Scholar 

  9. Qiulin Zhanga, Lisi Xua, and Ping Ninga, Appl. Surf. Sci. 317, 955 (2014).

    Article  Google Scholar 

  10. Seung Ju Han, Ji Hwan Song, Yongju Bang, et al., Int. J. Hydrogen Energy 41, 2554 (2016).

    Article  Google Scholar 

  11. A. Kubacka, M. Fernández-Garcia, et al., Appl. Catal., A 518, 2 (2016).

    Article  CAS  Google Scholar 

  12. I. C. Freitas, S. Damyanova, et al., J. Mol. Catal. A: Chem. 381, 26 (2014).

    Article  CAS  Google Scholar 

  13. A. G. Sato, D. P. Volanti, et al., Catal. Commun. 26, 122 (2012).

    Article  CAS  Google Scholar 

  14. Yueqin Songa, Jing Tiana, et al., Catal. Today 212, 108 (2013).

    Article  Google Scholar 

  15. Hua Huang, Weizhen Li, et al., Catal. Today 183, 58 (2012).

    Article  CAS  Google Scholar 

  16. A. I. Pylinina and I. I. Mikhalenko, Theor. Exp. Chem. 49, 65 (2013).

    Article  CAS  Google Scholar 

  17. A. I. Pylinina and I. I. Mikhalenko, Mendeleev Commun. 22, 150 (2012).

    Article  CAS  Google Scholar 

  18. Xiaosu Donga, Feng Lia, Ning Zhao, et al., Appl. Catal. B 191, 8 (2016).

    Article  Google Scholar 

  19. I. V. Deinega, L. Yu. Dolgikh, and L. A. Staraya, Poverkhnost, No. 1 (16) (2009).

    Google Scholar 

  20. S. G. Chuklina, A. I. Pylinina, L. I. Podzorova, et al., Russ. J. Phys. Chem. A (2016, in press).

    Google Scholar 

  21. L. I. Podzorova, S. A. Titov, A. Ilychyova, et al., Inorg. Mater.: Appl. Res. 7, 74 (2016).

    Article  Google Scholar 

  22. E. A. Platonov, N. N. Lobanov, N. A. Galimova, I. A. Protasova, and V. D. Yagodovskii, Russ. J. Phys. Chem. A 86, 1196 (2012).

    Article  CAS  Google Scholar 

  23. V. D. Yagodovskii, Russ. J. Phys. Chem. A 89, 2022 (2015).

    Article  CAS  Google Scholar 

  24. I. I. Ivanova, E. E. Knyazeva, I. V. Dobryakova, et al., RF Patent No. 2393992 (2009).

    Google Scholar 

  25. V. M. Gryaznov, V. D. Yagodovskii, and V. I. Shimulis, Kinet. Katal. 2, 22 (1961).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Peoples’ Friendship University of Russia, Moscow, 117198, Russia

    S. G. Chuklina & A. I. Pylinina

  2. Institute of Theoretical and Experimental Physics, National Research Center “Kurchatov Institute”, Moscow, 123182, Russia

    V. V. Khoroshilov

Authors
  1. S. G. Chuklina
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. I. Pylinina
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. V. Khoroshilov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to S. G. Chuklina.

Additional information

Original Russian Text © S.G. Chuklina, A.I. Pylinina, V.V. Khoroshilov, 2017, published in Zhurnal Fizicheskoi Khimii, 2017, Vol. 91, No. 5, pp. 821–825.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Chuklina, S.G., Pylinina, A.I. & Khoroshilov, V.V. Thermal and plasmochemical activation of the zirconia-supported copper catalyst for ethanol dehydrogenation. Russ. J. Phys. Chem. 91, 862–865 (2017). https://doi.org/10.1134/S0036024417050090

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036024417050090

Keywords

Search

Navigation