Skip to main content
SpringerLink
Log in

Synthesis and physicochemical properties of polysiloxane functionalized with aminoacetic acid groups

  • Physical Chemistry of Surface Phenomena
  • Published:
Russian Journal of Physical Chemistry A Aims and scope Submit manuscript

Abstract

Polysiloxane functionalized with aminoacetic acid groups was synthesized using sol–gel technology. Elemental analysis and FTIR spectroscopy were used to determine the composition of the polysiloxane show that it is a mesoporous material with a developed surface (109.4 m2/g). It was found that the selective properties of carboxymethylated polysiloxane towards transition metal ions simultaneously present in an ammonium acetate solution change in the order Zn < Cu > Ni > Co > Pb > Cd. It was shown that the sorption of copper(II) ions by carboxymethylated aminopropylpolysiloxane with particle sizes of 50–71 μm reaches its maximum level within 2 h; the rate-limiting step of the process is the chemical reaction between the ions and the polysiloxane functional groups; and the pseudo-second-order model is the best way of describing sorption.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. T. I. Tikhomirova, M. V. Luk’yanova, V. I. Fadeeva, et al., Zh. Anal. Khim. 48, 73 (1993).

    CAS  Google Scholar 

  2. N. N. Matorina, L. V. Shepetyuk, L. V. Karlina, et al., Zh. Fiz. Khim. 52, 1709 (1978).

    CAS  Google Scholar 

  3. E. B. Trostyanskaya and G. Z. Nefedova, Zh. Anal. Khim. 20, 775 (1985).

    Google Scholar 

  4. G. I. Tsizin, A. A. Formanovskii, I. V. Mikhura, et al., Zh. Neorg. Khim. 35, 960 (1990).

    CAS  Google Scholar 

  5. Yu. G. Yatluk, D. V. Eremin, L. K. Neudachina, and Yu. A. Skorik, Russ. Chem. Bull. 53, 2730 (2004).

    Article  CAS  Google Scholar 

  6. Yu. G. Yatluk, N. A. Zhuravlev, O. V. Koryakova, L. K. Neudachina, and Yu. A. Skorik, Russ. Chem. Bull. 54, 1836 (2005).

    Article  CAS  Google Scholar 

  7. P. N. Nesterenko and O. A. Shpigun, Russ. J. Coord. Chem. 28, 726 (2002).

    Article  CAS  Google Scholar 

  8. A. A. El-Nasser and R. V. Parish, J. Chem. Soc., Dalton Trans., 3463 (1999).

    Google Scholar 

  9. J. J. Yang, I. M. El-Nahhal, and G. E. Maciel, J. Non-Cryst. Solids 204, 105 (1996).

    Article  CAS  Google Scholar 

  10. I. M. El-Nahhal, F. R. Zaggout, and N. M. El-Ashgar, Anal. Lett. 33, 3373 (2000).

    Article  CAS  Google Scholar 

  11. L. K. Neudachina, N. V. Lakiza, A. V. Pestov, V. A. Osipova, L. V. Adamova, and E. M. Gorbunova, Glass Phys. Chem. 37, 537 (2011).

    Article  CAS  Google Scholar 

  12. K. Safa, A. Bahadori, S. Tofangdarzadeh, and M. H. Nasirtabrizi, J. Iran. Chem. Soc. 5, 37 (2008).

  13. L. Bois, A. Bonhomme, A. Ribes, et al., Colloids Surf. A 221, 221 (2003).

    Article  CAS  Google Scholar 

  14. D. Brown, A. Floyd, and M. Sainsbury, Organic Spectroscopy (Longman, London, 1978).

    Google Scholar 

  15. S. Brunauer, L. S. Deming, W. E. Deming, and E. Teller, J. Am. Chem. Soc. 62, 1723 (1940).

    Article  CAS  Google Scholar 

  16. S. Gregg and K. Sing, Adsorption, Surface Area, and Porosity (Academic, New York, 1982).

    Google Scholar 

  17. S. Brunauer, P. H. Emmett, and E. Teller, J. Am. Chem. Soc. 60, 309 (1938).

    Article  CAS  Google Scholar 

  18. L. K. Neudachina, A. Ya. Golub, Yu. G. Yatluk, V. A. Osipova, Yu. A. Berdyugin, E. M. Gorbunova, L. V. Adamova, O. V. Koryakova, and M. V. Kuznetsov, Inorg. Mater. 47, 435 (2011).

    Article  CAS  Google Scholar 

  19. J. C. P. Vaghetti, M. Zat, K. R. S. Bentes, et al., J. Anal. At. Spectrom. 18, 376 (2003).

    Article  CAS  Google Scholar 

  20. F. A. Pavan, T. M. H. Costa, and E. V. Benvenutti, Colloids Surf. A 226, 95 (2003).

    Article  CAS  Google Scholar 

  21. L. T. Arenas, J. C. P. Vaghetti, C. C. Moro, et al., Mater. Lett. 58, 895 (2004).

    Article  CAS  Google Scholar 

  22. E. P. Barrett, L. G. Joyner, and P. P. Halenda, J. Am. Chem. Soc. 73, 373 (1938).

    Article  Google Scholar 

  23. Chemistry of Graft Surface Compounds, Ed. by G. V. Lisichkin (Fizmatlit, Moscow, 2003) [in Russian].

  24. A. S. Zasukhin, L. K. Neudachina, Yu. G. Yatluk, L. V. Adamova, V. A. Osipova, E. M. Gorbunova, Yu. S. Moskaleva, and T. Yu. Larina, Russ. J. Phys. Chem. A 85, 478 (2011).

    Article  CAS  Google Scholar 

  25. N. V. Lakiza, L. K. Neudachina, Yu. G. Yatluk, et al., Analit. Kontrol’ 9, 391 (2005).

    Google Scholar 

  26. L. K. Neudachina, Yu. G. Yatluk, N. V. Baranova, A. V. Pestov, A. A. Vshivkov, A. Yu. Plekhanova, and M. V. Zorina, Russ. Chem. Bull. 55, 828 (2006).

    Article  CAS  Google Scholar 

  27. L. K. Neudachina, N. V. Lakiza, and Yu. G. Yatluk, Analit. Kontrol’ 10, 64 (2006).

    Google Scholar 

  28. L. K. Neudachina, A. V. Pestov, N. V. Baranova, and V. A. Startsev, Analit. Kontrol’ 15, 238 (2011).

    Google Scholar 

  29. G. V. Myasoedova and S. B. Savvin, Chelating Sorbents (Nauka, Moscow, 1984) [in Russian].

    Google Scholar 

  30. H. Irving and R. J. Williams, J. Chem. Soc., 3192 (1953).

    Google Scholar 

  31. The Chemist’s Reference Book, Ed. by B. N. Nikol’skii (Khimiya, Leningrad, 1965), Vol. 3 [in Russian].

  32. M. Rhasi, J. Desbrieres, A. Tolaimate, et al., Polymer 43, 1267 (2002).

    Article  Google Scholar 

  33. Yu. A. Kokotov and V. A. Pasechnik, Equilibria and Kinetics of Ion Exchange (Khimiya, Leningrad, 1970) [in Russian].

    Google Scholar 

  34. W. Rieman and H. Walton, Ion Exchange in Analytical Chemistry (Pergamon, Oxford, 1970).

    Google Scholar 

  35. Y. S. Ho, Scientometrics 59, 171 (2004).

    Article  CAS  Google Scholar 

  36. Y. S. Ho and G. McKay, Process Safety Environ. Protect. 76, 332 (1998).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Ural Federal University, Yekaterinburg, 620002, Russia

    N. V. Lakiza & L. K. Neudachina

Authors
  1. N. V. Lakiza
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. L. K. Neudachina
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to N. V. Lakiza.

Additional information

Original Russian Text © N.V. Lakiza, L.K. Neudachina, 2016, published in Zhurnal Fizicheskoi Khimii, 2016, Vol. 90, No. 7, pp. 1072–1077.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Lakiza, N.V., Neudachina, L.K. Synthesis and physicochemical properties of polysiloxane functionalized with aminoacetic acid groups. Russ. J. Phys. Chem. 90, 1450–1455 (2016). https://doi.org/10.1134/S0036024416070165

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036024416070165

Keywords

Search

Navigation