Abstract
Kinetics of alkaline hydrolysis of 4-nitrophenyl esters of tetracoordinated phosphorus acids in micellar solutions of aminomethylated calix[4]resorcinarene containing sulfonatoethylene groups on the lower rim of the macrocycle, 4-aza-1-hexadecyl-azoniabicyclo[2.2.2]octane bromide and their mixtures was investigated spectrophotometrically. It is established that the catalytic effect of aggregates depends on the concentration of calixarene and surfactants, pH, presence of lanthanum salt and reaches more than two orders of magnitude. The parameters of the catalyzed reactions and their dependence on the composition are determined.
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Original Russian Text © R.R. Kashapov, T.N. Pashirova, E.P. Zhiltsova, S.S. Lukashenko, A.Yu. Ziganshina, L.Ya. Zakharova, 2012, published in Zhurnal Fizicheskoi Khimii, 2012, Vol. 86, No. 2, pp. 256–261.
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Kashapov, R.R., Pashirova, T.N., Zhiltsova, E.P. et al. Supramolecular systems based on aminomethylated calix[4]resorcinarene and a cationic surfactant: Catalysts of the hydrolysis of esters of phosphorus acids. Russ. J. Phys. Chem. 86, 200–204 (2012). https://doi.org/10.1134/S003602441201013X
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DOI: https://doi.org/10.1134/S003602441201013X