Abstract
The data on molecular light scattering, adiabatic compressibility, and molar volume were used to study the special features of the microheterogeneous structure of solutions of cyclohexane, 1,4-dioxane, and morpholine in chlorobenzene at 25°C. The local structure of chlorobenzene experienced rearrangement close to a 0.03 solute mole fractions concentration in all the three systems. Up to a 0.1 mole fractions concentration, the structure of solutions was determined by the solvation of solute molecules. At medium concentrations, microheterogeneity was caused by agglomerates in the first system and agglomerates and conglomerates in the other two systems.
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Original Russian Text © A.I. Abramovich, L.V. Lanshina, 2010, published in Zhurnal Fizicheskoi Khimii, 2010, Vol. 84, No. 7, pp. 1269–1275.
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Abramovich, A.I., Lanshina, L.V. The microheterogeneous structure of solutions of cyclohexane, 1,4-dioxane, and morpholine in chlorobenzene. Russ. J. Phys. Chem. 84, 1147–1153 (2010). https://doi.org/10.1134/S0036024410070125
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DOI: https://doi.org/10.1134/S0036024410070125