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The problem of a self-consistent description of the equilibrium distribution of particles in three states of aggregation

  • Proceedings of the All-Russia Seminar on the Structure of Liquids and Solutions
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Abstract

The possibility of unified self-consistent calculations of equilibrium distributions of molecules in three states of aggregation within the framework of the lattice gas model is considered. The corresponding approach was generalized to arbitrary pressures with including the compressibility of lattice structures. Closed equations were obtained for calculating thermodynamic functions (including an equation for the chemical potential of mixture components) in the continuum quasi-chemical approximation. Their use ensures equally accurate calculations of interphase equilibria in gas-liquid-solid systems and the determination of the triple and critical points. Possibilities for simplifying the equations by passing to the effective pair interaction potential, which takes into account averaged vibrations and volume accessible to the translational motion of molecules of commensurate sizes, are considered.

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  1. Karpov Research Institute of Physical Chemistry, ul. Vorontsovo pole 10, Moscow, 103064, Russia

    Yu. K. Tovbin

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Original Russian Text © Yu.K. Tovbin, 2006, published in Zhurnal Fizicheskoi Khimii, 2006, Vol. 80, No. 10, pp. 1753–1766.

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Tovbin, Y.K. The problem of a self-consistent description of the equilibrium distribution of particles in three states of aggregation. Russ. J. Phys. Chem. 80, 1554–1566 (2006). https://doi.org/10.1134/S0036024406100050

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  • DOI: https://doi.org/10.1134/S0036024406100050

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