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The thermodynamic properties of Ln2BaO4 (Ln = Sm, Dy, Ho)

  • Chemical Thermodynamics and Thermochemistry
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Abstract

The thermodynamic properties of the Ln2BaO4 phases (Ln = Dy, Ho, Sm) were studied by the electromotive force method with a fluoride electrolyte (890–1180 K), solution calorimetry in 1.07 N hydrochloric acid at 298.15 K, and differential scanning calorimetry (298–860 K). The experimental data were jointly processed, and the thermodynamic functions of the compounds over the temperature range 298–1200 K were calculated.

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Authors and Affiliations

  1. Faculty of Chemistry, Moscow State University, Leninskie gory, Moscow, 119899, Russia

    I. A. Uspenskaya, Z. S. Vakhovskaya, M. M. Efremova, M. L. Kovba, A. L. Emelina, Yu. V. Goryushkina, L. A. Tiflova, A. A. Popova & A. S. Monaenkova

  2. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    Zh. V. Dobrokhotova

Authors
  1. I. A. Uspenskaya
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  2. Z. S. Vakhovskaya
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  3. M. M. Efremova
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  4. M. L. Kovba
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  5. A. L. Emelina
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  6. Zh. V. Dobrokhotova
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  7. Yu. V. Goryushkina
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  8. L. A. Tiflova
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  9. A. A. Popova
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  10. A. S. Monaenkova
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Additional information

Original Russian Text © I.A. Uspenskaya, Z.S. Vakhovskaya, M.M. Efremova, M.L. Kovba, A.L. Emelina, Zh.V. Dobrokhotova, Yu.V. Goryushkina, L.A. Tiflova, A.A. Popova, A.S. Monaenkova, 2006, published in Zhurnal Fizicheskoi Khimii, 2006, Vol. 80, No. 4, pp. 622–627.

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Uspenskaya, I.A., Vakhovskaya, Z.S., Efremova, M.M. et al. The thermodynamic properties of Ln2BaO4 (Ln = Sm, Dy, Ho). Russ. J. Phys. Chem. 80, 529–534 (2006). https://doi.org/10.1134/S0036024406040078

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  • DOI: https://doi.org/10.1134/S0036024406040078

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