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Electrochemical Properties of the closo-Decaborate Anion [B10H10]2– and a New Method for Preparation of the [B20H18]2– Anion

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Abstract

The work is devoted to the theoretical and experimental study of the electrochemical characteristics of the closo-decaborate anion. The regions of electrochemical transformations of the [B10H10]2– anion for non-aqueous solvents of different structures (acetonitrile, dichloromethane, and tetrahydrofuran) have been studied by the method of cyclic voltammetry. It has been shown that, under the conditions of anodic oxidation, a dimerization product, the [B20H18]2– anion, is formed. For the synthesis of octadecahydroeicosaborate anion, electrochemical synthesis has been used for the first time.

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ACKNOWLEDGMENTS

The research was carried out using the equipment of the Center for Collective Use of the Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, functioning within the framework of the State Assignment of the Kurnakov Institute in the field of fundamental scientific research.

Funding

The study was supported by the Russian Foundation for Basic Research (project nos. 19-29-08047 and 20-33-70217).

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    V. V. Voinova, I. N. Klyukin, A. P. Zhdanov, K. Yu. Zhizhin & N. T. Kuznetsov

  2. Saint Petersburg State University, Institute of Chemistry, 199034, St. Petersburg, Russia

    A. S. Novikov

  3. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    A. Ya. Koz’menkova

Authors
  1. V. V. Voinova
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  2. I. N. Klyukin
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  3. A. S. Novikov
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  4. A. Ya. Koz’menkova
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  5. A. P. Zhdanov
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  6. K. Yu. Zhizhin
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Correspondence to I. N. Klyukin or A. P. Zhdanov.

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Translated by V. Avdeeva

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Voinova, V.V., Klyukin, I.N., Novikov, A.S. et al. Electrochemical Properties of the closo-Decaborate Anion [B10H10]2– and a New Method for Preparation of the [B20H18]2– Anion. Russ. J. Inorg. Chem. 66, 295–304 (2021). https://doi.org/10.1134/S0036023621030190

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