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Selective Synthesis of Manganese Dioxide Polymorphs by the Hydrothermal Treatment of Aqueous KMnO4 Solutions

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Abstract

The hydrothermal treatment of neutral and acidified KMnO4 solutions at concentration of 0.037–0.093 mol/L and temperature of 120, 170, and 220°С for 24 h leads to selective synthesis of three different manganese dioxide modifications: α-MnO2, δ-MnO2, and β-MnO2. The temperature of hydrothermal treatment and medium acidity has been shown to affect considerably the phase composition of KMnO4 reduction products and reaction yield. The obtained samples of MnO2 have been characterized by X-ray diffraction, scanning electron microscopy, Raman spectroscopy, and diffuse reflectance spectroscopy.

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Funding

This work was supported by the Russian Science Foundation (project no. 16-13-10339) using facility of the Shared Facility Center, Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, supported by the State Assignment for the Kurnakov Institute of General and Inorganic Chemistry, RAS, in the field of fundamental research.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences, 119991, Moscow, Russia

    A. A. Egorova, T. M. Bushkova, A. D. Yapryntsev, S. Yu. Kottsov & A. E. Baranchikov

  2. Moscow State University, 119991, Moscow, Russia

    I. V. Kolesnik & S. Yu. Kottsov

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  1. A. A. Egorova
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  2. T. M. Bushkova
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  3. I. V. Kolesnik
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  4. A. D. Yapryntsev
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Correspondence to A. E. Baranchikov.

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Translated by I. Kudryavtsev

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Egorova, A.A., Bushkova, T.M., Kolesnik, I.V. et al. Selective Synthesis of Manganese Dioxide Polymorphs by the Hydrothermal Treatment of Aqueous KMnO4 Solutions. Russ. J. Inorg. Chem. 66, 146–152 (2021). https://doi.org/10.1134/S0036023621020066

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