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Trialkyl Triphenyl Phosphonium Dicyanodibromoaurates [Ph3PAlk][Au(CN)2Br2], Alk = CH2C6H4(OH)-2, CH2C6H11-cyclo, CH2Ph, CH2C6H4CN-4

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Abstract

The crystalline yellow complexes [Ph3PAlk][Au(CN)2Br2], where Alk = CH2C6H4(OH)-2 (I), CH2C6H11-cyclo (II ⋅ 1/2PhH), CH2Ph (III), CH2C6H4CN-4 (IV), have been synthesized from potassium dicyanodibromoaurate and alkyl triphenyl phosphonium chlorides in water and structurally characterized by X-ray diffraction. Crystals of complexes I–IV contain tetrahedral alkyl triphenyl phosphonium cations (CPC, 104.8(2)°–114.1(2)°; P–C, 1.782(6)–1.825(5) Å). In square [Au(CN)2Br2]– anions, the CAuC and BrAuBr trans-angles are 178.8(2)°–180.0(5)° and 178.38(3)°–180.00(3)°, and the Au–C and Au–Br bonds are 2.001(7)–2.205(9) Å and 2.4086(14)–2.4276(18) Å, respectively. The crystal structures are formed by weak hydrogen bonds N⋅⋅⋅Н–С and strong bonds N⋅⋅⋅Н–О in complex I and contacts Br⋅⋅⋅Н–С in dicyano-dibromides I, III, and IV.

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Funding

The National South Ural State Research University is grateful to the Ministry of Science and Higher Education of the Russian Federation for financial support (grant no. 4.6151.2017/8.9).

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  1. National South Ural State Research University, 454080, Chelyabinsk, Russia

    V. V. Sharutin, O. K. Sharutina, N. M. Tarasova & A. N. Efremov

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  1. V. V. Sharutin
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  2. O. K. Sharutina
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  3. N. M. Tarasova
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  4. A. N. Efremov
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Correspondence to N. M. Tarasova.

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Translated by E. Glushachenkova

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Sharutin, V.V., Sharutina, O.K., Tarasova, N.M. et al. Trialkyl Triphenyl Phosphonium Dicyanodibromoaurates [Ph3PAlk][Au(CN)2Br2], Alk = CH2C6H4(OH)-2, CH2C6H11-cyclo, CH2Ph, CH2C6H4CN-4. Russ. J. Inorg. Chem. 65, 169–175 (2020). https://doi.org/10.1134/S0036023620020151

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