Abstract
The FeS–PbS system was studied by differential thermal, X-ray powder diffraction, and micro-structural analyses and microhardness measurements. It was determined that the FeS–PbS system is a quasibinary section and is of the eutectic type. The coordinates of the eutectic point are 45 mol % PbS and 1123 K. Narrow solubility regions based on the initial components form.
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References
O. Kubaschewski, IRON—Binary Phase Diagrams (Springer, Berlin, 1982).
O. Kubaschewski, ASM International, Ed. by H. O. Komoto (1993), p. 364.
F. Gronvold and S. Stolen, J. Chem. Thermodyn. 24, 913 (1992).
C. W. Bale and J. M. Toguri, Canad. Metall. 15, 305 (1976).
R. G. Arnold, Econ. Geol. 66, 1121 (1971).
G. H. Moh and E. Kullerud, Phase Relations at Low Temperatures: The Fe–S System (Carnegie Inst., Washington, DC, 1964).
M. Kanda, N. Hasegawa, K. Itagaki, and A. Yazawa, Thermochim. Acta 109, 271 (1986).
V. S. Sudavtsova, N. O. Sharkina, and V. G. Kudin, Russ. J. Phys. Chem. 75, 1061 (2001).
P. Walder and A. D. Pelton, J. Phase Equilib. Diffus. 26, 23 (2005).
R. Sharma, J. Lin, and Y. Chang, Metall. Trans. 18, 237 (1987).
G. V. Samsonov and S. V. Drozdova, Sulfides (Metallurgiya, Moscow, 1972) [in Russian].
T. N. Komarova, Izv. Fiz.-Khim. In-ta Irkutsk. Un-te 27, 23 (1986).
Xiu Zhilang, Liu Suwen, and Xu Fengxin, J. Alloys Comp. 457, 9 (2008).
O. I. Vlasenko, S. M. Levitskii, and Ts. A. Kriskov, Fiz. Khim. Tverd. Tela 7, 660 (2006).
Ya. A. Ugai, Introduction to Semiconductor Chemistry (Vysshaya shkola, Moscow, 1975) [in Russian].
E. T. Tikgodan, Trans. AIME 242, 1665 (1968).
S. Ban-ya and J. Chipman, Trans. AIME 242, 940 (1968).
G. M. Mehrotra and J. B. Wagner, Proc. Electrochem. Soc. 86, 150 (1986).
K. K. Avetisyan and G. I. Gnatishenko, Izv. Akad. Nauk Kaz. SSR. Ser. Gorn. Dela Met. Stroit. Stroim, No. 6, 11 (1956).
H. Eriç and M. Timuçin, Metall. Trans. 12B, 493 (1981).
J. E. Dutrizac, Can. J. Chem. 58, 739 (1980).
H. Johto and P. Takinen, J. Miner. Met. Mater. Soc. 51, 205 (2012).
P. Taskinen, Proc. of the EMC, June 26–29, 2011, Dusseldorf, Germany, p. 1127.
M. B. Vargas, Metallurgia 31, 131 (1979).
R. Skala, I. Cisarova, and M. Drabek, Am. Mineral. 91, 917 (2006).
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Russian Text © U.A. Gasanova, O.M. Aliev, I.B. Bakhtiyarly, Sh.G. Mamedov, 2019, published in Zhurnal Neorganicheskoi Khimii, 2019, Vol. 64, No. 2, pp. 196–200.
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Gasanova, U.A., Aliev, O.M., Bakhtiyarly, I.B. et al. The FeS–PbS System. Russ. J. Inorg. Chem. 64, 242–246 (2019). https://doi.org/10.1134/S0036023619020074
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DOI: https://doi.org/10.1134/S0036023619020074