Abstract
The reaction of trans-[RuNO(NH3)4(OH)]Cl2 with nitric acid has been studied. Reaction products have been identified by IR spectroscopy, NMR, mass spectrometry, powder and single-crystal X-ray diffraction, and chemical analysis. Synthesis methods have been developed for amminenitrosoruthenium complexes containing outer-sphere and coordinated nitrate ions: trans-[RuNO(NH3)4(H2O)](NO3)3 (I), trans-[RuNO(NH3)4(NO3)](NO3)2 (II), and fac-[RuNO(NH3)2(NO3)3] (III). Complex II has two polymorphs: monoclinic and tetragonal. The latter has been studied by X-ray crystallography.
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Original Russian Text © E.V. Kabin, V.A. Emel’yanov, V.A. Vorob’yev, N.I. Alferova, S.V. Tkachev, I.A. Baidina, 2012, published in Zhurnal Neorganicheskoi Khimii, 2012, Vol. 57, No. 8, pp. 1225–1233.
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Kabin, E.V., Emel’yanov, V.A., Vorob’yev, V.A. et al. Reaction of trans-[RuNO(NH3)4(OH)]Cl2 with nitric acid and synthesis of ammine(nitrato)nitrosoruthenium complexes. Russ. J. Inorg. Chem. 57, 1146–1153 (2012). https://doi.org/10.1134/S0036023612050105
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DOI: https://doi.org/10.1134/S0036023612050105