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Hexamethylenetetrammonium dodecahydro-closo-dodecaborate: Synthesis and study

  • Synthesis and Properties of Inorganic Compounds
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Abstract

The reaction of dodecahydro-closo-dodecaboric acid with hexamethylenetetramine (urotropin) was studied by potentiometric titration, chemical and X-ray diffraction analyses, thermogravimetry, and IR and X-ray photoelectron spectroscopy. The donor-acceptor bond with acid H+ cations involves only one of the nitrogen donor atoms of hexamethylenetetramine. The product (C6H12N4H)2B12H12 is isolated as a finely crystalline, easily filterable, and poorly soluble precipitate. A saturated solution of the product contains no more than 0.4 g of the salt per 100 g.

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Authors and Affiliations

  1. Institute of Chemistry, Far East Division, Russian Academy of Sciences, pr. Stoletiya Vladivostoka 159, Vladivostok, 690022, Russia

    V. I. Saldin, M. A. Karpenko, L. N. Ignat’eva, Yu. M. Nikolenko & V. M. Buznik

  2. Institute of Problems of Chemical Physics, Chernogolovka Branch, Russian Academy of Sciences, Chernogolovka, Moscow oblast, 142432, Russia

    Yu. M. Mikhailov

Authors
  1. V. I. Saldin
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  2. M. A. Karpenko
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  3. L. N. Ignat’eva
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  4. Yu. M. Nikolenko
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  5. V. M. Buznik
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  6. Yu. M. Mikhailov
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Additional information

Original Russian Text © V.I. Saldin, M.A. Karpenko, L.N. Ignat’eva, Yu.M. Nikolenko, V.M. Buznik, Yu.M. Mikhailov, 2009, published in Zhurnal Neorganicheskoi Khimii, 2009, Vol. 54, No. 1, pp. 15–19.

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Saldin, V.I., Karpenko, M.A., Ignat’eva, L.N. et al. Hexamethylenetetrammonium dodecahydro-closo-dodecaborate: Synthesis and study. Russ. J. Inorg. Chem. 54, 13–16 (2009). https://doi.org/10.1134/S0036023609010033

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  • DOI: https://doi.org/10.1134/S0036023609010033

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