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Microstructure and plastic deformation of orthorhombic titanium aluminides Ti2AlNb. III. Formation of transformation twins upon the B2 → O phase transformation

  • Structure, Phase Transformations, and Diffusion
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Abstract

X-ray diffraction and transmission electron microscopy were used to study the O-phase formation in the Ti-25.6% Al-13.9% Nb-0.3% Mo-0.3% Zr alloy upon the B2 → O phase transformation. The formation of pseudotwins is shown to be possible in the B2 phase in the Ti-Al-Nb alloys. It is found that the O phase upon the B2 → O phase transformation does not undergo twinning, and all twins observed in the alloy belong to the intermediate metastable B19 phase. The orthorhombic O phase is formed upon ordering inside the B19-phase twins and save their boundaries.

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References

  1. D. Banerjee, A. K. Gogia, T. K. Nandy, and V. A. Joshi, “A New Ordered Orthorhombic Phase in a Ti3Al-Nb Alloy,” Acta Metall. 36(4), 871–882 (1988).

    Article  CAS  Google Scholar 

  2. H. T. Kestner-Weykamp, C. H. Ward, T. F. Broderick, and M. J. Kaufman, “Microstructures and Phase Relationships in the Ti3Al-Nb System,” Scr. Metall. 23, 1697–1702 (1989).

    Article  CAS  Google Scholar 

  3. N. V. Kazantseva, B. A. Greenberg, S. L. Demakov, et al., “Microstructure and Plastic Deformation of Orthorhombic Ti2AlNb Aluminides: I. Formation of Polydomain Structure,” Fiz. Met. Metalloved. 93(3), 1–10 (2002) [Phys. Met. Metallogr. 93, 269–277 (2002)].

    Google Scholar 

  4. S. L. Demakov, L. S. Stepanov, and A. A. Popov, “Phase Transformations in an α2 Titanium Superalloy: I. Effects of the Quenching Temperature and Time at Quenching Temperature on the Phase Composition and Structure of the Alloy,” Fiz. Met. Metalloved. 86(5), 115–122 (1998) [Phys. Met. Metallogr. 86, 497–502 (1998)].

    CAS  Google Scholar 

  5. L. A. Bendersky, “Modulated Two-Domain Structure of the O Phase Formed in the Ti-25Al-12.5Nb (at. %) Alloy,” Scr. Metall. Mater. 29, 1645–1650 (1993).

    Article  CAS  Google Scholar 

  6. Y. H. Wen, Y. Wang, L. A. Bendersky, and L. Q. Chen, “Microstructural Evolution during the α2 → α2 + O Transformation in Ti-Al-Nb Alloys: Phase-Field Simulation and Experimental Validation,” Acta Mater. 48, 4125–4135 (2000).

    Article  CAS  Google Scholar 

  7. H. T. Kestner-Weykamp, D. R. Baker, D. M. Paxton, and M. J. Kaufman, “Continious Cooling Transformation in Ti3Al + Nb Alloys,” Scr. Metall. 24, 445–450 (1990).

    Article  Google Scholar 

  8. L. A. Bendersky, A. Roytburd, and W. J. Boettinger, “Phase Transformations in the (Ti,Al)3Nb Section of the Ti-Al-Nb System: I. Microstructural Predictions Based on a Subgroup Relations between Phases,” Acta Metal. Mater. 42(7), 2323–2335 (1994).

    Article  CAS  Google Scholar 

  9. L. A. Bendersky and W. J. Boettinger, “Phase Transformations in the (Ti, Nb)3Al Section of the Ti-Al-Nb System: II. Experimental TEM Study of Microstructures,” Acta Metall. Mater. 42(7), 2337–2352 (1994).

    Article  CAS  Google Scholar 

  10. K. Muraleedharan, T. K. Nandy, D. Banerjee, and S. Lele, “Transformations in a Ti-24Al-15Nb Alloy: Part II. A Composition Invariant β0O Transformation,” Metall. Trans. A 23A, 417–431 (1992).

    CAS  Google Scholar 

  11. P. K. Sagar, D. Banerjee, K. Muraleedharan, and Y. V. R. K. Prasad, “High-Temperature Deformation Processing of Ti-24Al-20Nb,” Metall. Trans. A 27A, 2593–2604 (1996).

    CAS  Google Scholar 

  12. J. W. Cahn, “Thermodynamic and Structural Changes in Deformation Twinning of Alloys,” Acta Metall. 25, 1021–1026 (1977).

    Article  CAS  Google Scholar 

  13. J. W. Christian and D. E. Laughlin, “The Deformation Twinning of Superlattice Structures Derived from Disordered BCC or FCC Solid Solutions,” Acta Metall. 36(7), 1617–1642 (1988).

    Article  Google Scholar 

  14. A. T. Paxton, “The Impossibility of Pseudotwinning in B2 Alloys,” Acta Metall. Mater. 43(5), 2133–2136 (1995).

    Article  ADS  CAS  Google Scholar 

  15. D. Banerjee, T. K. Nandy, and A. K. Gogia, “Site Occupation in the Ordered Beta Phase of Ternary Ti-Al-Nb Alloys,” Scr. Metall. 21, 597–600 (1987).

    Article  CAS  Google Scholar 

  16. X. Ren and M. Hagiwara, “Displacive Precursor Phenomena in Ti-22Al-27Nb Intermetallic Compound Prior to Diffusional Transformation,” Acta Mater. 49, 3971–3980 (2001).

    Article  CAS  Google Scholar 

  17. K. Muraleedharan, S. V. Nagender Naidu, and D. Banerjee, “Orthorhombic Distortions of the α2 Phase in Ti3Al-Nb Alloys: Artifacts and Facts,” Scr. Metall. 24, 27–32 (1990).

    Article  CAS  Google Scholar 

  18. C. J. Boehlert, B. S. Majumdar, V. Seetharaman, and D. B. Miracle, “The Microstructural Evolution in Ti-Al-Nb O + BCC Orthorhombic Alloys,” Metall. Mater. Trans. A 30A, 2305–2323 (1999).

    Article  CAS  Google Scholar 

  19. N. V. Kazantseva, B. A. Greenberg, N. P. Gulyaeva, et al., “Microstructure and Plastic Deformation of Orthorhombic Aluminides Ti2AlNb: II. Structure and Phase Transformations upon Severe Plastic Deformation,” Fiz. Met. Metalloved. 96(4), 23–32 (2003) [Phys. Met. Metallogr. 96, 368–377 (2003)].

    CAS  Google Scholar 

  20. V. G. Pushin, V. V. Kondrat’ev, and V. N. Khachin, Pretransition Phenomena and Martensitic Transformations (Ural. Otd. Ross. Akad. Nauk, Ekaterinburg, 1998) [in Russian].

    Google Scholar 

  21. Direct Electron-Microscopic Study of Two-Phase Titanium Alloys. Preparation of Samples and Indexing of Electron-Diffraction Patterns. Methodical Recommendation (VILS, 1975) [in Russian].

  22. Electron-Microscopic Study of Internal Structure of α Phase in Titanium Alloys (Analysis of Electron-Diffraction Patterns of Twin Crystals of α Phase). Methodical Recommendation (VILS, 1975), [in Russian].

  23. L. M. Utevskii, Diffraction Electron Microscopy in Physical Metallurgy (Metallurgiya, Moscow, 1973) [in Russian].

    Google Scholar 

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Original Russian Text © N.V. Kazantseva, S.L. Demakov, A.A. Popov, 2007, published in Fizika Metallov i Metallovedenie, 2007, Vol. 103, No. 4, pp. 395–405.

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Kazantseva, N.V., Demakov, S.L. & Popov, A.A. Microstructure and plastic deformation of orthorhombic titanium aluminides Ti2AlNb. III. Formation of transformation twins upon the B2 → O phase transformation. Phys. Metals Metallogr. 103, 378–387 (2007). https://doi.org/10.1134/S0031918X07040102

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  • DOI: https://doi.org/10.1134/S0031918X07040102

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