Skip to main content
Log in

Cu-Zn-Al-O catalysts for the oxidative desulfurization of dibenzothiophene, a typical sulfur-containing compound of the diesel fraction

  • “Catalysis: From Science to Industry,” III International School-Conference for Young Scientists (Tomsk, October 26–30, 2014)
  • Published:
Kinetics and Catalysis Aims and scope Submit manuscript

Abstract

The possibility of oxidative desulfurization of dibenzothiophene dissolved in toluene as a model organosulfur compound of diesel fuel in the presence of catalytic CuZnAl compositions was studied. It was shown that the CuZnAl catalysts at 350–450°C ensure sulfur removal from the model fuel to the extent of up to 40–45%. Part of the sulfur is removed as SO2, and some sulfur is absorbed on the catalyst surface.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Stanislaus, A., Marafi, A., and Mohan, S.R., Catal. Today, 2010, vol. 153, p. 1.

    Article  CAS  Google Scholar 

  2. Ito, E. and Rob van Veen, J.A., Catal. Today, 2006, vol. 116, p. 446.

    Article  CAS  Google Scholar 

  3. Ismagilov, Z.R., Yashnik, S.A., Kerzhentsev, M.A., Parmon, V.N., Bourane, A., Al-Shahrani, F.M., Hajji, A.A., and Koseoglu, O.R., Catal. Rev. Sci. Eng., 2011, vol. 53, p. 199.

    Article  CAS  Google Scholar 

  4. Gao, L., Tang, Y., Xue, Q., Liu, Ye., and Lu, Y., Energy Fuels, 2009, vol. 23, p. 624.

    Article  CAS  Google Scholar 

  5. Lu, Y., Wang, Y., Gao, L., Chen, J., Mao, J., Xue, Q., Liu, Y., Wu, H., Gao, G., and He, M., ChemSusChem, 2008, vol. 1, p. 302.

    Article  CAS  Google Scholar 

  6. Baeza, P., Aguila, G., Vargas, G., Ojeda, J., and Araya, P., Appl. Catal., B, 2012, vols. 111–112, p. 133.

    Article  Google Scholar 

  7. US Patent 5753102, 1998.

  8. Gislason, J., Oil Gas J., 2001, vol. 99, p. 72.

    Google Scholar 

  9. Akyurtlu, J.F. and Akyurtlu, A., Gas Sep. Purif., 1995, vol. 9, no. 1, p. 17.

    Article  CAS  Google Scholar 

  10. Bu, X., Ying, Y., Ji, X., Zhang, C., and Peng, W., Fuel Process. Technol., 2007, vol. 88, p. 143.

    Article  CAS  Google Scholar 

  11. US Patent 0026072, 2013.

  12. Pearton, S.J., Norton, D.J., Ip, K., and Heo, Y.W., Mater. Sci., 2005, vol. 50, p. 293.

    CAS  Google Scholar 

  13. Marabelli, F., Parravicini, G.B., and Salghetti-Drioli, F., Phys. Rev. B: Condens. Matter, 1995, vol. 52, p. 1433.

    Article  CAS  Google Scholar 

  14. Lever, A.B.P., Inorganic Electron Spectroscopy, Amsterdam: Elsevier, 1984, vols. 1, 2.

    Google Scholar 

  15. Borgohain, K. and Mahamuni, S., J. Mater. Res., 2002, vol. 17, p. 1220.

    Article  CAS  Google Scholar 

  16. Mohaghegh, N., Tasviri, M., Rahimi, E., and Gholami, M.R., Mater. Sci. Semicond. Process., 2014, vol. 21, p. 167.

    Article  CAS  Google Scholar 

  17. El-Shobaky, G.A., Ahmed, A.S., Fagal, G.A., and Mokhtar, M., Thermochim. Acta, 1998, vol. 319, p. 67.

    Article  CAS  Google Scholar 

  18. Zawadzki, M., Staszak, W., López-Suárez, F.E., Illán-Gómez, M.J., and Bueno-López, A., Appl. Catal., A, 2009, vol. 371, p. 92.

    Article  CAS  Google Scholar 

  19. Shobaky, G.A., Fagal, G.A., and Mokhtar, M., Appl. Catal., A, 1997, vol. 155, p. 167.

    Article  Google Scholar 

  20. Rodriguez, J.A., Kim, J.Y., Hanson, J.C., Pérez, M., and Frenkel, A.I., Catal. Lett., 2003, vol. 85, p. 247.

    Article  CAS  Google Scholar 

  21. Tang, Y., Liu, Y., Zhu, P., Xue, Q., Chen, L., and Lu, Y., AIChE J., 2009, vol. 55, p. 3214.

    Article  Google Scholar 

  22. Ismagilov, Z.R., Khairulin, S.R., Kerzhentsev, M.A., Mazgarov, A.M., and Vildanov, A.F., Eurasian Chem. Technol. J., 1999, vol. 1, p. 49.

    CAS  Google Scholar 

  23. Ganesan, K. and Pillai, C.N., J. Catal., 1989, vol. 119, p. 13.

    Google Scholar 

  24. Cai, H., Krzywicki, A., and Oballa, M.C., Chem. Eng. Process., 2002, vol. 41, p. 199.

    Article  CAS  Google Scholar 

  25. Barbier, J., Appl. Catal., 1986, vol. 23, p. 225.

    Article  CAS  Google Scholar 

  26. Kim, S.C. and Shim, W.G., Environ.Technol., 2008, vol. 29, p. 535.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to A. V. Salnikov.

Additional information

Original Russian Text © S.A. Yashnik, M.A. Kerzhentsev, A.V. Salnikov, Z.R. Ismagilov, A. Bourane, O.R. Koseoglu, 2015, published in Kinetika i Kataliz, 2015, Vol. 56, No. 4, pp. 470–480.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Yashnik, S.A., Kerzhentsev, M.A., Salnikov, A.V. et al. Cu-Zn-Al-O catalysts for the oxidative desulfurization of dibenzothiophene, a typical sulfur-containing compound of the diesel fraction. Kinet Catal 56, 466–475 (2015). https://doi.org/10.1134/S0023158415040205

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0023158415040205

Keywords

Navigation