Abstract
We studied the kinetics of glucose hydrogenation over a catalyst containing Ru nanoparticles in a super-cross-linked polystyrene matrix. Two hydrogenation pathways, whose rates differ by several orders of magnitude (“fast” and “slow” pathways), were found. The first pathway includes the reaction of glucose from its aqueous solution with hydrogen sorbed on the catalyst’s metal, and the second one includes the reaction of sorbed substrate with hydrogen occurring on the catalyst support due to spillover. A mathematical description of the reaction pathways was proposed, and the most probable scheme of the process was suggested. The role of hydrogen spillover in the kinetics of the occurring processes was considered.
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Chen, B., Dingerdissen, U., Krauter, J.G.E., Lansink Rotgerink, H.G.J., Möus, K., Ostgard, D.J., Panster, P., Riermeier, T.H., Seelbald, S., Tacke, T., and Trauthwein, H., Appl. Catal., A, 2005, vol. 280, no. 1, p. 17.
Maris, E.P., Kenchie, W.C., Oleshko, V., and Davis, R.J., J. Phys. Chem. B, 2006, vol. 110, p. 7869.
Ahmed, M.J., Khadom, A.A., and Kadhum, A.A.H., Eur. J. Sci. Res., 2009, vol. 130, no. 2, p. 294.
Elliot, D.C., Peterson, K.L., Muzatko, D.S., Alderson, E.V., and Hart, T.R., Appl. Biochem. Biotechnol., 2004, vol. 113, p. 807.
Cortright, R.D., Davda, R.R., and Dumesic, J.A., Nature, 2002, vol. 418, p. 964.
Castoldi, M.C.M., Camara, L.D.T., and Aranda, D.A.G., React. Kinet. Catal. Lett., 2009, vol. 98, p. 83.
Crezee, E., Hoffer, B.W., Berger, R.J., Makkee, M., Kapteijn, F., and Moulijn, J.A., Appl. Catal., A, 2003, vol. 251, p. 1.
Kusserow, B., Schimpf, S., and Claus, P., Adv. Synth. Catal., 2003, vol. 345, p. 289.
Hoffer, B.W., Crezee, E., Mooijman, P.R.M., van Langeveld, A.D., Kapteijn, F., and Moulijn, J.A., Catal. Today, 2003, vol. 79–80, p. 35.
Gallezot, P., Nicolaus, N., Flèche, G., Fuertes, P., and Perrard, A., J. Catal., 1998, vol. 180, p. 51.
Van Gorp, K., Boerman, E., Cavenaghi, C.V., and Berden, P.H., Catal. Today, 1999, vol. 52, p. 349.
Rozanov, V.V., Chem. Rev., 1997, vol. 66, no. 2, p. 117.
Prins, R., Chem. Rev., 2012, vol. 112, p. 2714.
Xiang, Zh., Lan, J., Cao, D., Shao, X., Wang, W., and Broom, D.P., J. Phys. Chem. C, 2009, vol. 113, no. 34, p. 15106.
Reyhani, S.Z., Mortazavi, S., Mirershadi, A.Z., Moshfegh, P.P., and Nozad Golikand, A., J. Phys. Chem. C, 2011, vol. 115, p. 6994.
Sifontes Herrera, V.A., Oladele, O., Kordas, K., Ernen, K., Mikkola, J.-P., Murzin, D.Yu., and Salmi, T., J. Chem. Technol. Biotechnol., 2011, vol. 86, p. 658.
Besson, M. and Gallezot, P., Catal. Today, 2003, vol. 81, p. 547.
Chen, L., Cooper, A.C., Pez, G.P., and Cheng, H., J. Phys. Chem. C, 2007, vol. 111, p. 18995.
Wang, Z., Yang, F.H., and Yang, R.T., J. Phys. Chem., vol. 114, p. 1601.
Sha, X., Knippenberg, M.T., Cooper, A.C., Pez, G.P., and Cheng, H., J. Phys. Chem., vol. 112, p. 17465.
Qingquan, L., Macromol. Chem. Phys., 2010, vol. 211, p. 1012.
Germain, J., Fréchet, J.M.J., and Svec, F., Polym. Mater. Sci. Eng., 2007, vol. 97, p. 272.
Ganz, E. and Dornfeld, M., J. Phys. Chem. C, 2012, vol. 116, p. 3661.
Pastukhov, A.V., Tsyurupa, M.P., and Davankov, V.A., J. Polym. Sci., Part B: Polym. Phys., 1999, vol. 37, p. 2324.
Tsyurupa, M.P. and Davankov, V.A., J. Polym. Sci., Polym. Chem. Ed., 1980, vol. 18, no. 4, p. 1399.
Davankov, V.A. and Tsyurupa, M.P., React. Polym., 1990, vol. 13, p. 27.
Bronstein, L.M., Matveeva, V.G., and Sulman, E.M., in Nanoparticles and Catalysis, Astruć, Ed., Weinheim: Wiley-VCH, 2007, p. 93.
Sermon, P.A. and Bond, G.C., J. Chem. Soc., Faraday Trans., 1976, vol. 1, no. 72, p. 745.
Shmid, R. and Sapunov, V.N., Search for Chemical Reaction Pathways, Weinheim: Chemie, 1982.
Thomas, J.M. and Thomas, W.J., Principles and Practice of Heterogeneous Catalysis, Weinheim: VCH, 1996.
Germain, J., Fréchet, J.M.J., and Svec, F., Chem. Commun., 2009, p. 1526.
Wang, L. and Yang, R.T., Energy Environ. Sci., 2008, vol. 1, p. 268.
Wisniak, J., Hershkowitz, M., and Stein, S., Ind. Eng. Chem. Res., 1974, vol. 13, no. 4, p. 232.
Wisniak, J. and Simon, R., Ind. Eng. Chem. Res., 1979, vol. 18, no. 1, p. 50.
Nakano, K. and Kusonoki, K., Chem. Eng. Commun., 1985, vol. 34, p. 99.
Gaidai, N.A., Kazantsev, R.V., Nekrasov, N.V., Shulgax, Yu.M., Ivleva, I.N., and Kiperman, S.L., React. Kinet. Catal. Lett., 2002, vol. 75, no. 1, p. 55.
Saeys, M., Reyniers, M.-F., Thybaut, J.W., Neurock, M., and Marin, G.B., J. Catal., 2005, vol. 236, p. 129.
Saeys, M., Reyniers, M.-F., Neurock, M., and Marin, G.B., J. Phys. Chem. B, 2005, vol. 109, no. 6, p. 2064.
Sermon, P.A. and Bond, G.C., Catal. Rev., 1973, vol. 8, p. 211.
Li, Y., Yang, F.H., and Yang, R.T., J. Phys. Chem. C, 2007, vol. 111, no. 8, p. 3405.
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Original Russian Text © V.G. Matveeva, V.N. Sapunov, M.E. Grigor’ev, M.B. Lebedeva, E.M. Sul’man, 2014, published in Kinetika i Kataliz, 2014, Vol. 55, No. 6, pp. 712–722.
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Matveeva, V.G., Sapunov, V.N., Grigor’ev, M.E. et al. Kinetics of D-glucose hydrogenation over a Ru-containing heterogeneous catalyst. Kinet Catal 55, 695–704 (2014). https://doi.org/10.1134/S002315841406010X
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DOI: https://doi.org/10.1134/S002315841406010X