Skip to main content
SpringerLink
Log in

Unexpected participation of nucleophiles in the reaction of palladium(II) acetate with divalent 3d metals

  • Published:
Kinetics and Catalysis Aims and scope Submit manuscript

Abstract

The kinetics of reactions of palladium(II) acetate with cobalt(II), nickel(II), and copper(II) acetates were studied by spectrophotometry. These reactions produce heterobimetallic complexes PdII(μ-OOCMe)4MII(OH2)(HOOCMe)2, where M = Co, Ni, or Cu. These reactions are very slow in carefully dehydrated (<0.01% H2O) acetic acid, but are considerably enhanced by water or acetonitrile. Our data indicate that the activation of the kinetically inert ring structure of the initial palladium complex Pd3(μ-OOCMe)6 by means of the nucleophilic attack of an H2O or acetonitrile molecule is the key step of the reaction mechanism.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Okamoto, H., J. Phase Equilib., 2001, vol. 22, p. 364.

    Article  CAS  Google Scholar 

  2. Sinfelt, J.H., Bimetallic Catalysts: Discoveries, Concepts and Applications, New York: Wiley, 1983.

    Google Scholar 

  3. Heemeier, M., Carlsson, A.F., Naschitzki, M., Schmal, M., Baumer, M., and Freund, H.-J., Angew. Chem., Int. Ed. Engl., 2002, vol. 41, p. 4073.

    Article  CAS  Google Scholar 

  4. Fernandez, J.L., Walsh, D.A., and Bard, A.J., J. Am. Chem. Soc., 2005, vol. 127, p. 357.

    Article  CAS  Google Scholar 

  5. Kozitsyna, N.Yu., Nefedov, S.E., Cherkashina, N.V., Ikorskii, V.N., Vargaftik, M.N., and Moiseev, I.I., Izv. Akad. Nauk, Ser. Khim., 2005, p. 2149.

  6. Kozitsyna, N.Yu., Nefedov, S.E., Vargaftik, M.N., and Moiseev, I.I., Mendeleev Commun., 2005, vol. 15, p. 223.

    Article  Google Scholar 

  7. Kozitsyna, N.Yu., Nefedov, S.E., Dolgushin, F.M., Cherkashina, N.V., Vargaftik, M.N., and Moiseev, I.I., Inorg. Chim. Acta, 2006, vol. 359, p. 2072.

    Article  CAS  Google Scholar 

  8. Nefedov, S.E., Kozitsyna, N.Yu., Vargaftik, M.N., and Moiseev, I.I., Polyhedron, 2009, vol. 28, p. 172.

    Article  CAS  Google Scholar 

  9. Tkachenko, O.P., Stakheev, A.Yu., Kustov, L.M., Mashkovsky, I.V., Berg, M., Grunert, W., Kozitsyna, N.Yu., Dobrokhotova, Zh.V., Zhilov, V.I., Nefedov, S.E., Vargaftik, M.N., and Moiseev, I.I., Catal. Lett., 2006, vol. 112, p. 155.

    Article  CAS  Google Scholar 

  10. Kozitsyna, N.Yu., Nefedov, S.E., Dobrokhotova, Zh.V., Ikorskii, V.N., Stolyarov, I.P., Vargaftik, M.N., and Moiseev, I.I., Ros. Nanotekhnol., 2008, vol. 3, nos. 3–4, p. 100.

    Google Scholar 

  11. Stephenson, T.A., Morehouse, S.M., Powell, A.R., Heffer, J.P., and Wilkinson, G., J. Chem. Soc., 1965, p. 3632.

  12. Perrin, D.D. and Armarego, W.L.F., Purification of Laboratory Chemicals, Oxford: Pergamon, 1998.

    Google Scholar 

  13. Akhmadullina, N.S., Cherkashina, N.V., Kozitsyna, N.Yu., Stolarov, I.P., Perova, E.V., Gekhman, A.R., Nefedov, S.E., Vargaftik, M.N., and Moiseev, I.I., Inorg. Chim. Acta, 2009 (available online, doi: 10.1016/j.ica2008.09.042).

  14. Hendriks, C.F., van Beek, H.C.A., and Heertjes, P.M., Ind. Eng. Chem. Res., 1979, vol. 18, p. 43.

    Article  CAS  Google Scholar 

  15. Bakhmutov, V.I., Berry, J.E., Cotton, F.A., Ibragimov, S., and Murillo, C.A., J. Chem. Soc., Dalton Trans., 2005, p. 1989.

Download references

Author information

Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, 119991, Russia

    N. S. Akhmadullina, N. V. Cherkashina, N. Yu. Kozitsyna, A. E. Gekhman & M. N. Vargaftik

Authors
  1. N. S. Akhmadullina
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. N. V. Cherkashina
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. N. Yu. Kozitsyna
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. E. Gekhman
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. M. N. Vargaftik
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to N. S. Akhmadullina.

Additional information

Original Russian Text © N.S. Akhmadullina, N.V. Cherkashina, N.Yu. Kozitsyna, A.E. Gekhman, M.N. Vargaftik, 2009, published in Kinetika i Kataliz, 2009, Vol. 50, No. 3, pp. 417–421.

To the 80 birthday of Academician I.I. Moiseev.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Akhmadullina, N.S., Cherkashina, N.V., Kozitsyna, N.Y. et al. Unexpected participation of nucleophiles in the reaction of palladium(II) acetate with divalent 3d metals. Kinet Catal 50, 396–400 (2009). https://doi.org/10.1134/S0023158409030094

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0023158409030094

Keywords

Search

Navigation