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Synthesis, Composition, and Magnetic Properties of Cadmium-Doped Lanthanum Ferrite Nanopowders

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Abstract—

Nanocrystalline La1 – xCdxFeO3 (x = 0, 0.05, 0.1, 0.15, 0.2) powders with a narrow homogeneity range (xmax = 0.09 according to X-ray microanalysis and X-ray diffraction data) have been synthesized via coprecipitation followed by thermal annealing at 950°C for 1 h. The addition of Cd2+ cations leads to a decrease in average crystallite size from 10–70 nm at x = 0 to 5–60 nm at x = 0.1 (according to transmission electron microscopy data). The synthesized nanocrystals have ferrimagnetic properties.

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REFERENCES

  1. Haye, E., Capon, F., Barrat, S., Boulet, P., Andre, E., Carteret, C., and Bruyere, S., Properties of rare-earth orthoferrites perovskite driven by steric hindrance, J. Alloys Compd., 2016, vol. 657, pp. 631–638.https://doi.org/10.1016/j.jallcom.2015.10.135

    Article  CAS  Google Scholar 

  2. Markova-Velichkova, M., Lazarova, T., Tumbalev, V., Ivanov, G., Kovacheva, D., Stefanov, P., and Naydenov, A., Complete oxidation of hydrocarbons on YFeO3 and LaFeO3 catalysts, Chem. Eng. J., 2013, vol. 231, pp. 236–244.https://doi.org/10.1016/j.cej.2013.07.029

    Article  CAS  Google Scholar 

  3. Yuan, X., Sun, Y., and Xu, M., Effect of Gd substitution on the structure and magnetic properties of YFeO3 ceramics, J. Solid State Chem., 2012, vol. 196, pp. 362–366.https://doi.org/10.1016/j.jssc.2012.06.042

    Article  CAS  Google Scholar 

  4. Zhang, Y., Yang, J., Xu, J., Gao, Q., and Hong, Z., Controllable synthesis of hexagonal and orthorhombic YFeO3 and their visible-light photocatalytic activities, Mater. Lett., 2012, vol. 81, pp. 1–4.https://doi.org/10.1016/j.matlet.2012.04.080

    Article  CAS  Google Scholar 

  5. Marenkin S.F., Fedorchenko I.V., Izotov A.D., and Vasil’ev M.G., Physicochemical principles underlying the synthesis of granular semiconductor–ferromagnet magnetic structures exemplified by AIIGeAs2 (AII = Zn, Cd), Inorg. Mater., 2019, vol. 55, no. 9, pp. 865–872. https://doi.org/10.1134/S0020168519090061

    Article  Google Scholar 

  6. Novotortsev, V.M., Palkina, K.K., Mikhailov, S.G., Molchanov, A.V., Ochertyanova, L.I., and Marenkin, S.F., Synthesis and structure of Mn-doped CdGeAs2 single crystals, Inorg. Mater., 2005, vol. 41, no. 5, pp. 439–442.https://doi.org/10.1007/s10789-005-0149-2

    Article  CAS  Google Scholar 

  7. Lee, W.-Y., Yun, H.J., and Yoon, J.-W., Characterization and magnetic properties of LaFeO3 nanofibers synthesized by electrospinning, J. Alloys Compd., 2014, vol. 583, pp. 320–324.https://doi.org/10.1016/j.jallcom.2013.08.191

    Article  CAS  Google Scholar 

  8. Sendil, K.A., Manivel, R.M., and Bhatnagar, A.K., Surface driven effects on magnetic properties of antiferromagnetic LaFeO3 nanocrystalline ferrite, J. Appl. Phys., 2014, vol. 116, no. 11, paper 113912.https://doi.org/10.1063/1.4896191

  9. Phokha, S., Pinitsoontorn, S., Maensiri, S., and Rujirawat, S., Structure, optical and magnetic properties of LaFeO3 nanoparticles prepared by polymerized complex method, J. Sol–Gel Sci. Technol., 2014, vol. 71, no. 2, pp. 333–341.https://doi.org/10.1007/s10971-014-3383-8

    Article  CAS  Google Scholar 

  10. Kundu, S.K., Rana, D.K., Banerjee, A., Das, D., and Basu, S., Influence of manganese on multiferroic and electrical properties of lanthanum ferrite nanoparticles, Mater. Res. Express, 2019, vol. 6, no. 8, paper 085032.https://doi.org/10.1088/2053-1591/ab1db6

  11. Nguyen, A.T., Knurova, M.V., Nguyen, T.M., Mittova, V.O., and Mittova, I.Ya., Synthesis and the study of magnetic characteristics of nano La1 – xSrxFeO3 by co-precipitation method, Nanosyst.: Phys. Chem. Math., 2014, vol. 5, no. 5, pp. 692–702.

    Google Scholar 

  12. Lin, Q., Xu, J., Yang, F., Yang, X., and He, Y., The influence of Ca substitution on LaFeO3 nanoparticles in terms of structural and magnetic properties, J. Appl. Biomater. Funct. Mater., 2018, vol. 16, no. 1S, pp. 17–25.https://doi.org/10.1177/2280800017753948

    Article  CAS  PubMed  Google Scholar 

  13. Nguyen, A.T., Mittova, V.O., Mittova, I.Ya., and Dinh, V.T., Synthesis of La1 – xSr(Ca)xFeO3 (x = 0, 0.1, 0.2, 0.3) nanopowders by a sol–gel process, Kondens. Sredy Mezhfaznye Granitsy, 2010, vol. 12, no. 1, pp. 56–60.

    CAS  Google Scholar 

  14. Tret’yakov, Yu.D., Neorganicheskaya khimiya (Inorganic Chemistry), Moscow: Akademkniga, 2007, vol. 3.

  15. Sutka, A. and Mezinskis, G., Sol–gel auto-combustion synthesis of spinel-type ferrite nanomaterials, Front. Mater. Sci., 2012, vol. 6, no. 2, pp. 128–141. https://doi.org/10.1007/s11706-012-0167-3

    Article  Google Scholar 

  16. Zhang, W., Fang, C., Yin, W., and Zeng, Y., One-step synthesis of yttrium orthoferrite nanocrystals via sol–gel auto-combustion and their structural and magnetic characteristics, Mater. Chem. Phys., 2013, vol. 137, no. 3, pp. 877–883.https://doi.org/10.1016/j.matchemphys.2012.10.029

    Article  CAS  Google Scholar 

  17. Shen, H., Xu, J., and Wu, A., Preparation and characterization of perovskite ReFeO3 nanocrystalline powders, J. Rare Earths, 2010, vol. 28, no. 3, pp. 416–419.https://doi.org/10.1016/s1002-0721(09)60124-1

    Article  CAS  Google Scholar 

  18. Dinh Van Tac, Mittova, V.O., Almjasheva, O.V., and Mittova, I.Ya., Synthesis and Magnetic Properties of Nanocrystalline Y1 – xCdxFeO3 – δ (0 ≤ x ≤ 0.2), Inorg. Mater., 2011, vol. 47, no. 10, pp. 1141–1146.https://doi.org/10.1134/s0020168511100037

    Article  Google Scholar 

  19. Nguyen, A.T., Mittova, I.Ya., Almjasheva, O.V., Kirillova, S.A., and Gusarov, V.V., Influence of the preparation conditions on the size and morphology of nanocrystalline lanthanum orthoferrite, Glass Phys. Chem., 2008, vol. 34, no. 6, pp. 756–761.https://doi.org/10.1134/s1087659608060138

    Article  Google Scholar 

  20. JCPDS PCPDFWIN: A Windows Retrieval/Display program for Accessing the ICDD PDF-2 Database, International Centre for Diffraction Data, 1997.

  21. Almjasheva, O.V., Heat-stimulated transformation of zirconium dioxide nanocrystals produced under hydrothermal conditions, Nanosyst.: Phys. Chem. Math., 2015, vol. 6, no. 5, pp. 697–703.https://doi.org/10.17586/2220-8054-2015-6-5-697-703

    Article  CAS  Google Scholar 

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ACKNOWLEDGMENTS

In our work, we used equipment at the Shared Research Facilities Center, Voronezh State University, and at the Department of Magnetism, Moscow State University.

Funding

This study was supported by the Russian Foundation for Basic Research (scientific project no. 20-33-90048 Aspiranty) and through the Development of Moscow State University Program.

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Correspondence to E. I. Kopeychenko.

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Kopeychenko, E.I., Mittova, I.Y., Perov, N.S. et al. Synthesis, Composition, and Magnetic Properties of Cadmium-Doped Lanthanum Ferrite Nanopowders. Inorg Mater 57, 367–371 (2021). https://doi.org/10.1134/S0020168521040075

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