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Effect of bombardment with helium ions on the molecular-topological structure and elemental composition of the surface of Kynar polyvinylidene fluoride resin

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Abstract

A polyvinylidene fluoride film has been bombarded with accelerated (1–5 MeV) helium ions at a fluence of 1015 ion/cm2. Unlike the completely amorphous structure of the unirradiated polymer, the weight fraction of the crystalline modification in the irradiated polymer is 0.86–0.90, which is indicative of the efficient conversion of the amorphous structures of the polymer pseudo-network into the crystalline ones. Irradiation with 1-MeV ions leads to the greatest changes in the fraction of the crystalline modification and the glass-transition and flow temperatures of the polymer. The detachment of fluorine and the surface carbonization of the irradiated polymer occur under the ion beam.

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, pr. Akademika Semenova 1, Chernogolovka, Moscow oblast, 142432, Russia

    Yu. A. Ol’khov & S. R. Allayarov

  2. Howard J. Foster Center for Irradiation of Materials, Alabama A&M University, 4900 Meridian street, PO Box 1447, Normal, AL, 35762, USA

    K. I. Muntele

  3. Department of Chemistry, the University of Alabama, Box 870336, Tuscaloosa, Alabama, AL, 35487-0336, USA

    D. A. Dixon

Authors
  1. Yu. A. Ol’khov
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  2. S. R. Allayarov
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  3. K. I. Muntele
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  4. D. A. Dixon
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Corresponding author

Correspondence to Yu. A. Ol’khov.

Additional information

Original Russian Text © Yu.A. Ol’khov, S.R. Allayarov, K.I. Muntele, D.A. Dixon, 2014, published in Khimiya Vysokikh Energii, 2014, Vol. 48, No. 3, pp. 183–190.

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Ol’khov, Y.A., Allayarov, S.R., Muntele, K.I. et al. Effect of bombardment with helium ions on the molecular-topological structure and elemental composition of the surface of Kynar polyvinylidene fluoride resin. High Energy Chem 48, 144–151 (2014). https://doi.org/10.1134/S0018143914030114

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  • DOI: https://doi.org/10.1134/S0018143914030114

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