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The mechanism of photoinduced hydrogen transfer during photoreduction of carbonyl compounds

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Abstract

A model reaction of hydrogen transfer has been proposed that describes well the results of kinetic studies of the photoreduction of o- and p-quinones and fluorenone in the presence of para-substituted N,N-dimethylanilines and polyalkylbenzenes in various solvents.

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Authors and Affiliations

  1. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, ul. Tropinina 49, Nizhni Novgorod, 603950, Russia

    S. A. Chesnokov, M. P. Shurygina & G. A. Abakumov

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  1. S. A. Chesnokov
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  2. M. P. Shurygina
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  3. G. A. Abakumov
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Correspondence to S. A. Chesnokov.

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Original Russian Text © S.A. Chesnokov, M.P. Shurygina, G.A. Abakumov, 2011, published in Khimiya Vysokikh Energii, 2011, Vol. 45, No. 4, pp. 319–331.

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Chesnokov, S.A., Shurygina, M.P. & Abakumov, G.A. The mechanism of photoinduced hydrogen transfer during photoreduction of carbonyl compounds. High Energy Chem 45, 287–299 (2011). https://doi.org/10.1134/S0018143911040059

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  • DOI: https://doi.org/10.1134/S0018143911040059

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