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Luminescence of metal complexes of chelate-substituted tetraphenylporphyrin

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Abstract

The luminescence and absorption spectra of some metal complexes of new tetraphenylporphyrin derivatives containing a chelating group with a heavy atom in the ligand structure were studied and compared with the properties of the zinc complex of unsubstituted tetraphenylporphyrin. The quantum yields of fluorescence and phosphorescence of liquid and frozen solutions of these compounds were measured. The life-times of delayed emission have been estimated, and the nature of bands in the absorption and luminescence spectra of the complexes and their relation with the structure are discussed.

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Authors and Affiliations

  1. Tomsk State University, Tomsk, 654050, Russia

    R. T. Kuznetsova, E. G. Ermolina, R. M. Gadirov & G. V. Mayer

  2. Bogatskii Physicochemical Institute, National Academy of Sciences of Ukraine, Odessa, 65080, Ukraine

    N. N. Semenishin, N. V. Rusakova & Yu. V. Korovin

Authors
  1. R. T. Kuznetsova
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  2. E. G. Ermolina
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  3. R. M. Gadirov
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  4. G. V. Mayer
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  5. N. N. Semenishin
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  6. N. V. Rusakova
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  7. Yu. V. Korovin
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Corresponding author

Correspondence to R. T. Kuznetsova.

Additional information

Original Russian Text © R.T. Kuznetsova, E.G. Ermolina, R.M. Gadirov, G.V. Mayer, N.N. Semenishin, N.V. Rusakova, Yu.V. Korovin, 2010, published in Khimiya Vysokikh Energii, 2010, Vol. 44, No. 2, pp. 168–172.

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Kuznetsova, R.T., Ermolina, E.G., Gadirov, R.M. et al. Luminescence of metal complexes of chelate-substituted tetraphenylporphyrin. High Energy Chem 44, 134–138 (2010). https://doi.org/10.1134/S0018143910020098

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  • DOI: https://doi.org/10.1134/S0018143910020098

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