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On the appearance of ions near the charged surface of an intensely evaporating electrolyte

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Abstract

Two mechanisms behind the appearance of ions in the vapor-gas sheath around a hot electrode immersed in an electrolyte, electrolyte surface instability against the surface charge and field evaporation, are considered. It is shown that the concept of the thermally activated field evaporation of ions provides a better approximation to experimental conditions. A dispersion relation for capillary-barogravity waves at the electrolyte-saturated vapor charged interface is derived. Critical conditions for the instability of these waves are found.

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References

  1. P. Ludewig, Ann. Phys. (Leipzig), No. 25, 467 (1908).

  2. H. H. Kellog, J. Electrochem. Soc. 97(4), 133 (1950).

    Google Scholar 

  3. V. S. Vanin, Elektrotermiya, No. 55, 18 (1967).

  4. K. Jnoue and U. Shima, J. Jpn. Inst. Met. 32, 755 (1969).

    Google Scholar 

  5. O. J. Garbarz and C. Guilpin, J. Chem. Phys. 72, 207 (1975).

    Google Scholar 

  6. P. N. Belkin, E. A. Pasinkovskii, and A. A. Faktorovich, Izv. Akad. Nauk Mold. SSR, Ser. Fiz.-Tekh. Mat. Nauk, No. 1, 82 (1977).

  7. P. N. Belkin, V. I. Ganchar, and Yu. N. Petrov, Dokl. Akad. Nauk SSSR 291, 1116 (1986) [Sov. Phys. Dokl. 31, 1001 (1986)].

    Google Scholar 

  8. P. N. Belkin and V. I. Ganchar, Élektron. Obrab. Mater., No. 5, 59 (1988).

  9. P. N. Belkin and S. N. Belkin, Inzh.-Fiz. Zh. 57, 159 (1989).

    Google Scholar 

  10. V. I. Ganchar, Inzh.-Fiz. Zh. 60, 92 (1991).

    Google Scholar 

  11. P. N. Belkin and A. K. Tovarkov, Vestn. Kostromsk. Gos. Univ., No. 3, 8 (2001).

  12. S. Yu. Shadrin and P. N. Belkin, Élektron. Obrab. Mater., No. 3, 24 (2002).

  13. A. I. Grigor’ev, O. A. Grigor’ev, and S. O. Shiryaeva, Zh. Tekh. Fiz. 62(9), 12 (1992) [Sov. Phys. Tech. Phys. 37, 904 (1992)].

    Google Scholar 

  14. O. A. Grigor’ev and S. O. Shiryaeva, Zh. Tekh. Fiz. 66(2), 23 (1996) [Tech. Phys. 41, 124 (1996)].

    Google Scholar 

  15. A. I. Grigor’ev, Pis’ma Zh. Tekh. Fiz. 27(7), 89 (2001) [Tech. Phys. Lett. 27, 305 (2001)].

    Google Scholar 

  16. A. I. Grigor’ev, V. V. Morozov, and S. O. Shiryaeva, Zh. Tekh. Fiz. 72(10), 33 (2002) [Tech. Phys. 47, 1237 (2002)].

    Google Scholar 

  17. L. D. Landau and E. M. Lifshitz, Course of Theoretical Physics, Vol. 8: Electrodynamics of Continuous Media (Nauka, Moscow, 1982; Pergamon, New York, 1984).

    Google Scholar 

  18. P. Reist, Introduction to Aerosol Science (Macmillan, New York, 1984; Mir, Moscow, 1987).

    Google Scholar 

  19. S. O. Shiryaeva, Pis’ma Zh. Tekh. Fiz. 22(13), 43 (1996) [Tech. Phys. Lett. 22, 540 (1996)].

    Google Scholar 

  20. V. G. Levich, Physicochemical Hydrodynamics (Fizmatgiz, Moscow, 1959).

    Google Scholar 

  21. L. D. Landau and E. M. Lifshitz, Course of Theoretical Physics, Vol. 6: Fluid Mechanics (Nauka, Moscow, 1986; Pergamon, New York, 1987).

    Google Scholar 

  22. A. P. Babichev, N. A. Babushkina, A. M. Bratkovskii, et al., Handbook of Physical Quantities, Ed. by I. S. Grigoriev and E. Z. Meilikhov (Énergoatomizdat, Moscow, 1991; CRC, Boca Raton, 1997).

    Google Scholar 

  23. J. V. Iribarne and B. A. Thomson, J. Chem. Phys. 64, 2287 (1976).

    Article  ADS  Google Scholar 

  24. E. W. Muller and T. T. Tsong, Field Ion Microscopy: An Introduction to Principles, Experiments, and Applications (Elsevier, New York, 1969; Metallurgiya, Moscow, 1972).

    Google Scholar 

  25. R. Gomer, Appl. Phys. 19, 365 (1979).

    Article  Google Scholar 

  26. N. B. Zolotoi, Zh. Tekh. Fiz. 65(11), 159 (1995) [Tech. Phys. 40, 1175 (1995)].

    Google Scholar 

  27. A. I. Grigor’ev, Pis’ma Zh. Tekh. Fiz. 27(7), 89 (2001) [Tech. Phys. Lett. 27, 305 (2001)].

    Google Scholar 

  28. L. V. Gurvich, I. V. Veits, V. A. Medvedev, et al., Thermodynamic Properties of Substances: A Reference Book (Nauka, Moscow, 1982), Vol. 4, Part 1.

    Google Scholar 

  29. V. S. Fomenko, Emissive Properties of Materials: A Handbook (Naukova Dumka, Kiev, 1981).

    Google Scholar 

  30. M. M. Viktorov, Calculation of Physicochemical Quantities: Methods and Applications (Khimiya, Leningrad, 1977).

    Google Scholar 

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Authors and Affiliations

  1. Demidov State University, Sovetskaya ul. 14, Yaroslavl, 150000, Russia

    S. O. Shiryaeva, A. I. Grigor’ev & V. V. Morozov

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  1. S. O. Shiryaeva
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  2. A. I. Grigor’ev
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  3. V. V. Morozov
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__________

Translated from Zhurnal Tekhnichesko\(\overset{\lower0.5em\hbox{$\smash{\scriptscriptstyle\smile}$}}{l} \) Fiziki, Vol. 73, No. 7, 2003, pp. 21–27.

Original Russian Text Copyright © 2003 by Shiryaeva, Grigor’ev, Morozov.

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Shiryaeva, S.O., Grigor’ev, A.I. & Morozov, V.V. On the appearance of ions near the charged surface of an intensely evaporating electrolyte. Tech. Phys. 48, 822–828 (2003). https://doi.org/10.1134/1.1593186

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