Abstract
Correlations between the density, elastic properties, and hardness of the carbon phases prepared from C60 at a high pressure are studied. By varying the high pressure and temperature properly, one can obtain from C60 a broad class of ordered polymerized and disordered phases, for which the fraction of the sp 2 and sp 3 states, the characteristic dimensionality of the structure, the degree of covalent bonding, etc. can be varied successfully. 3D-bonded carbon structures are shown to exhibit a clearly pronounced correlation between the hardness or bulk modulus and the density, with these correlations also apparently applying to the carbon phases in a general case. At the same time, the mechanical characteristics of structures with a lower dimension covalent bonding are worse than those of 3D-bonded phases with similar values of the density.
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References
I. N. Frantsevich, G. G. Gnesin, A. V. Kurdyumov, G. G. Karyuk, A. V. Bochko, and N. P. Semenenko, in Superhard Materials, Ed. by I. N. Frantsevich (Naukova Dumka, Kiev, 1980).
I. N. Frantsevich, F. F. Voronov, and S. A. Bokuta, Elastic Constants and Elastic Moduli of Metals and Insulators: Handbook (Naukova Dumka, Kiev, 1982).
P. S. Kislyi, in Superhard and Refractory Materials, Ed. by P. S. Kislyi (Inst. Sverkhtverdykh Materialov, Kiev, 1985), p. 86.
M. L. Cohen, Phys. Rev. B 32, 7988 (1985).
J. M. Léger, J. Haines, and B. Blanzat, J. Mater. Sci. Lett. 13, 1688 (1994).
J. J. Gilman, Mater. Sci. Eng. A 209, 74 (1996).
J. M. Léger and J. Haines, Endeavour 21(3), 121 (1997).
D. G. Clerc and H. M. Ledbetter, J. Phys. Chem. Solids 59(6–7), 1071 (1998).
D. M. Teter, MRS Bull. 23, 22 (1998).
V. V. Brazhkin, A. G. Lyapin, and R. J. Hemley, Philos. Mag. A 82, 231 (2002).
D. A. Young, Phase Diagrams of Elements (Univ. of California Press, Berkley, 1991).
M. W. Guinan and D. J. Steinberg, J. Phys. Chem. Solids 35, 1501 (1974).
A. Y. Liu, M. L. Cohen, K. C. Hass, and M. A. Tamor, Phys. Rev. B 43(8), 6742 (1991).
G. Jungnickel, P. K. Sitch, Th. Frauenheim, et al., Phys. Rev. B 57(2), 661 (1998).
M. Côté, J. C. Grossman, M. L. Cohen, and S. G. Louie, Phys. Rev. B 58(2), 664 (1998).
S. J. Townsend, T. J. Lenosky, D. A. Muller, et al., Phys. Rev. Lett. 69(6), 921 (1992).
V. Rosato, M. Celino, G. Benedek, and S. Gaito, Phys. Rev. B 60, 16928 (1999).
F. Diederich, Nature 369, 199 (1994).
R. H. Baughman, D. S. Galvão, C. Cui, and S. O. Dantas, Chem. Phys. Lett. 269, 356 (1997).
H. W. Kroto, J. R. Heath, S. C. O’Brien, et al., Nature 318, 162 (1985).
S. Iijima, Nature 354, 56 (1991); T. W. Ebbesen and P. M. Ajayan, Nature 358, 220 (1992).
Yu. P. Kudryavtsev, R. B. Heimann, and S. E. Evsyukov, J. Mater. Sci. 31, 557 (1996).
J. Robertson, Adv. Phys. 35, 317 (1986).
D. R. McKenzie, D. Muller, and B. A. Pailthorpe, Phys. Rev. Lett. 67, 773 (1991).
M. Weiler, S. Sattel, T. Giessen, et al., Phys. Rev. B 53, 1594 (1996).
Y. Iwasa, T. Arima, R. M. Fleming, et al., Science 264, 1570 (1994).
M. Núñez-Rogueiro, L. Marques, J.-L. Hodeau, et al., Phys. Rev. Lett. 74(2), 278 (1995).
L. Marques, J.-L. Hodeau, M. Núñez-Rogueiro, and M. Perroux, Phys. Rev. B 54(18), R12633 (1996).
V. A. Davydov, L. S. Kashevarova, A. V. Rakhmanina, et al., Phys. Rev. B 58(22), 14786 (1998).
M. E. Kozlov, M. Hirabayashi, K. Nozaki, et al., Appl. Phys. Lett. 66(10), 1199 (1995).
A. G. Lyapin, V. V. Brazhkin, E. L. Gromnitskaya, et al., Appl. Phys. Lett. 76(6), 712 (2000).
V. V. Brazhkin, A. G. Lyapin, Yu. V. Antonov, et al., Pis’ma Zh. Éksp. Teor. Fiz. 62(4), 328 (1995) [JETP Lett. 62, 350 (1995)].
V. D. Blank, S. G. Buga, N. R. Serebryanaya, et al., Phys. Lett. A 205, 208 (1995).
V. V. Brazhkin, A. G. Lyapin, and S. V. Popova, Pis’ma Zh. Éksp. Teor. Fiz. 64(11), 755 (1996) [JETP Lett. 64, 802 (1996)].
V. D. Blank, S. G. Buga, N. R. Serebryanaya, et al., Phys. Lett. A 220, 149 (1996).
V. V. Brazhkin, A. G. Lyapin, S. V. Popova, et al., Phys. Rev. B 56(18), 11465 (1997).
V. V. Brazhkin, A. G. Lyapin, S. V. Popova, et al., J. Appl. Phys. 84(1), 219 (1998).
H. Hirai, K. Kondo, N. Yoshizava, and M. Shiraishi, Appl. Phys. Lett. 64(14), 1797 (1994).
H. Hirai, Y. Tabira, K. Kondo, et al., Phys. Rev. B 52(9), 6162 (1995).
V. V. Brazhkin, A. G. Lyapin, R. N. Voloshin, et al., Pis’ma Zh. Éksp. Teor. Fiz. 69(11), 822 (1999) [JETP Lett. 69, 869 (1999)].
A. G. Lyapin, V. V. Brazhkin, S. G. Lyapin, et al., Phys. Status Solidi B 211, 401 (1999).
A. G. Glazov, V. V. Mukhamad’yarov, V. V. Brazhkin, et al., Pis’ma Zh. Éksp. Teor. Fiz. 73(10), 621 (2001) [JETP Lett. 73, 552 (2001)].
M. H. Manghnani, S. Tkachev, P. V. Zinin, et al., Phys. Rev. B 64, 121403(R) (2001).
P. C. Kelires, Phys. Rev. Lett. 73, 2460 (1994).
E. Burgos, E. Halac, R. Weht, et al., Phys. Rev. Lett. 85, 2328 (2000).
C. Mailhiot and A. K. McMahan, Phys. Rev. B 44(21), 11578 (1991).
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Translated from Fizika Tverdogo Tela, Vol. 44, No. 3, 2002, pp. 393–397.
Original Russian Text Copyright © 2002 by Lyapin, Brazhkin.
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Lyapin, A.G., Brazhkin, V.V. Correlations between the physical properties of the carbon phases obtained at a high pressure from C60 fullerite. Phys. Solid State 44, 405–409 (2002). https://doi.org/10.1134/1.1462656
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DOI: https://doi.org/10.1134/1.1462656