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Synthesis and crystal structures of lithium polyphosphates, LiPO3, Li4H(PO3)5, and LiMn(PO3)3

  • Structure of Inorganic Compounds
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Abstract

Polyphosphates of the compositions LiPO3, Li4H(PO3)5, and LiMn(PO3)3 were prepared by the reactions of Li2CO3 and MnO2 with melts of polyphosphoric acids at 240–350°C, and their crystal structures were established. The unit-cell parameters are a = 13.074 Å, b = 5.4068 Å, c = 16.452 Å, β = 99.00°, sp. gr. P2/n; a = 6.6434 Å, b = 7.253 Å, c = 11.399 Å, α = 72.60°, β = 83.36°, γ = 85.32°, sp. gr.; \(P\bar 1\); a = 8.364 Å, b = 8.561 Å, c = 8.6600 Å, sp. gr. P212121, respectively. The influence of cations on the structures of the compounds is discussed.

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References

  1. N. N. Chudinova, E. V. Murashova, and B. S. Zakharova, Zh. Neorg. Khim. 43(6), 885 (1998).

    Google Scholar 

  2. E. V. Murashova and N. N. Chudinova, Neorg. Mater. 36(12), 1507 (2000); 36 (12), 1512 (2000).

    Google Scholar 

  3. M. Bagieu-Beucher, Acta Crystallogr., Sect. B: Struct. Crystallogr. Cryst. Chem. B34, 1443 (1978).

    Google Scholar 

  4. J. C. Guintel and I. Tordjman, Acta Crystallogr., Sect. B: Struct. Crystallogr. Cryst. Chem. B32, 2960 (1976).

    Google Scholar 

  5. G. M. Sheldrick, SHELXS97: Program for the Solution of Crystal Structures (Univ. of Göttingen, Göttingen, 1997).

    Google Scholar 

  6. G. M. Sheldrick, SHELXL97: Program for the Refinement of Crystal Structures (Univ. of Göttingen, Göttingen, 1997).

    Google Scholar 

  7. M. Laugt, I. Tordjman, J. C. Guintel, and M. Roudaut, Acta Crystallogr., Sect. B: Struct. Crystallogr. Cryst. Chem. B28, 2352 (1972).

    Google Scholar 

  8. E. A. Genkina, B. A. Maksimov, Yu. K. Kabalov, and O. K. Mel’nikov, Dokl. Akad. Nauk SSSR 270(6), 1113 (1983) [Sov. Phys. Dokl. 28, 426 (1983)].

    Google Scholar 

  9. I. Grunze, N. N. Chudinova, and H. Grunze, Izv. Akad. Nauk SSSR, Neorg. Mater. 25(6), 886 (1989).

    Google Scholar 

  10. N. N. Chudinova and N. V. Vinogradova, Izv. Akad. Nauk SSSR, Neorg. Mater. 15(12), 2171 (1979).

    Google Scholar 

  11. B. Bruehne and M. Jansen, Z. Anorg. Allg. Chem. 620, 1409 (1994).

    Google Scholar 

  12. K. K. Palkina, S. I. Maksimova, and N. T. Chibiskova, Izv. Akad. Nauk SSSR, Neorg. Mater. 17(1), 95 (1981).

    Google Scholar 

  13. H.-Y.-P. Hong, Mater. Res. Bull. 10, 635 (1975).

    Google Scholar 

  14. J.-C. Liu and D.-Y. Li, Acta Phys. Sin. 32, 786 (1983).

    ADS  Google Scholar 

  15. E. V. Murashova and N. N. Chudinova, Neorg. Mater. 36(12), 1512 (2000).

    Google Scholar 

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 117907, Russia

    E. V. Murashova & N. N. Chudinova

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  1. E. V. Murashova
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  2. N. N. Chudinova
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Translated from Kristallografiya, Vol. 46, No. 6, 2001, pp. 1024–1029.

Original Russian Text Copyright © 2001 by Murashova, Chudinova.

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Murashova, E.V., Chudinova, N.N. Synthesis and crystal structures of lithium polyphosphates, LiPO3, Li4H(PO3)5, and LiMn(PO3)3 . Crystallogr. Rep. 46, 942–947 (2001). https://doi.org/10.1134/1.1420823

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