Infrared Fourier Transform Emission Spectroscopy of CuH and NeH

R. S. Ram; P. F. Bernath; J. W. Brault

doi:10.1117/12.970862

20 December 1985 Infrared Fourier Transform Emission Spectroscopy of CuH and NeH

R. S. Ram, P. F. Bernath, J. W. Brault

Proceedings Volume 0553, Fourier and Computerized Infrared Spectroscopy; (1985) https://doi.org/10.1117/12.970862
Event: 1985 International Conference on Fourier and Computerized Infrared Spectroscopy, 1985, Ottawa, Canada

Abstract

The vibration-rotation spectra of CuH and Nee were detected by infrared emission from a copper hollow cathode lamp with the Kitt Peak Fourier transform spectrometer. The (1,0), (2,1) and (2,0) bands of °3CuH and 65CuH were found as well as the (1,0), 2,1) and (3,2) bands of NeH+. The Ne and H2 pressures in the lamp were 2 torr and 30 mtorr, respectively. By replacing the H2 with D2 the (1,0) and (2,1) bands of NeD+ were observed. CuH is the first metal hydride for which a vibration-rotation emission spectrum has been detected. Dunham coefficients, including the effects of Born-Oppenheimer breakdown, were extracted from the data.

Citation Download Citation

R. S. Ram, P. F. Bernath, and J. W. Brault "Infrared Fourier Transform Emission Spectroscopy of CuH and NeH", Proc. SPIE 0553, Fourier and Computerized Infrared Spectroscopy, (20 December 1985); https://doi.org/10.1117/12.970862

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