##############################################################################
#                                                                            #
# This CIF contains the data for a data article accepted for                 #
# publication in IUCrData. It conforms to the requirements of                #
# Notes for Authors for IUCrData, and has been                               #
# peer reviewed under the auspices of IUCrData.                              #
#                                                                            #
# Full details of the Crystallographic Information File format               #
# are given in the paper "The Crystallographic Information File (CIF):       #
# a New Standard Archive File for Crystallography" by S. R. Hall, F. H.      #
# Allen and I. D. Brown [Acta Cryst. (1991), A47, 655-685].                  #
#                                                                            #
# The current version of the core CIF dictionary is obtainable from          #
# ftp://ftp.iucr.org/pub/cif_core.dic.                                       #
#                                                                            #
# Software is freely available for graphical display of the structure(s)     #
# in this CIF. For information consult the CIF software page                 #
# http://www.iucr.org/resources/cif/software.                                #
#                                                                            #
# This file may be used for bona fide research purposes within the           #
# scientific community so long as proper attribution is given to the data    # 
# article from which it was obtained.                                        #
#                                                                            #
##############################################################################
data_I
_audit_creation_method
;
Olex2 1.3-ac4
(compiled 2018.12.18 svn.r3554 for Rigaku Oxford Diffraction, GUI svn.r1)
;
_journal_date_recd_electronic     2022-09-27
_journal_date_accepted     2022-11-30
_journal_name_full     'IUCrData'
_journal_year     2022
_journal_volume     7
_journal_issue     12
_journal_page_first     0
_journal_page_last     0
_journal_paper_category     HM
_journal_paper_doi     10.1107/S2414314622011476
_journal_coeditor_code     WM4175
_publ_contact_author_name     'Reinout Meijboom'
_publ_contact_author_address
;
Department of Chemical Sciences
University of Johannesburg
PO Box 524
Auckland Park
2006
Johannesburg
South Africa
;
_publ_contact_author_email     'rmeijboom@uj.ac.za'
_publ_contact_author_fax     '+27115592819'
_publ_contact_author_phone     '+27115592367'
_publ_section_title
;
Tris(benzyldiphenylphosphane-κP)(nitrato-κO)silver(I)
;
loop_
    _publ_author_name
    _publ_author_footnote
    _publ_author_address
    'Potgieter, Kariska' .
;
Department of Chemical Sciences
University of Johannesburg
PO Box 524
Auckland Park
2006
Johannesburg
South Africa
;
    'Malan, Frederick P.' .
;
Department of Chemistry
University of Pretoria
Lynnwood Road
Hatfield
Pretoria
0002
South Africa
;
    'Alimi, Oyekunle Azeez' .
;
Department of Chemical Sciences
University of Johannesburg
PO Box 524
Auckland Park
2006
Johannesburg
South Africa
;
    'Meijboom, Reinout' .
;
Department of Chemical Sciences
University of Johannesburg
PO Box 524
Auckland Park
2006
Johannesburg
South Africa
;
_publ_section_synopsis
;
The central AgI atom exhibits a distorted tetrahedral coordination
environment, defined by three P atoms of three benzyl-diphenylphosphane
ligands and one O atom of a nitrato ligand.
;
_chemical_name_systematic
;
Tris(benzyldiphenylphosphane-κP)(nitrato-κO)silver(I)
;
_chemical_name_common     ?
_chemical_formula_moiety     'C57 H51 Ag N O3 P3'
_chemical_formula_sum     'C57 H51 Ag N O3 P3'
_chemical_formula_iupac     '[Ag (N O3) (C19 H17 P1)3]'
_chemical_formula_weight     998.76
_chemical_melting_point     ?
_space_group_crystal_system     monoclinic
_space_group_name_H-M_alt     'P 1 21/c 1'
_space_group_name_Hall     '-P 2ybc'
loop_
    _space_group_symop_operation_xyz
    'x, y, z'
    '-x, y+1/2, -z+1/2'
    '-x, -y, -z'
    'x, -y-1/2, z-1/2'
_cell_length_a     13.5643(2)
_cell_length_b     9.9979(2)
_cell_length_c     35.4391(6)
_cell_angle_alpha     90
_cell_angle_beta     99.248(2)
_cell_angle_gamma     90
_cell_volume     4743.59(15)
_cell_formula_units_Z     4
_cell_measurement_reflns_used     49121
_cell_measurement_theta_min     2.6180
_cell_measurement_theta_max     31.2530
_cell_measurement_temperature     150.00(10)
_exptl_crystal_description     block
_exptl_crystal_colour     colourless
_exptl_crystal_size_max     0.210
_exptl_crystal_size_mid     0.177
_exptl_crystal_size_min     0.155
_exptl_crystal_density_diffrn     1.399
_exptl_crystal_density_meas     ?
_exptl_crystal_density_method     ?
_exptl_crystal_F_000     2064
_exptl_absorpt_coefficient_mu     0.573
_exptl_absorpt_correction_type     multi-scan
_exptl_absorpt_process_details
;
(CrysAlisPro; Rigaku OD, 2022)
;
_exptl_absorpt_correction_T_min     0.26845
_exptl_absorpt_correction_T_max     1.00000
_exptl_special_details     ?
_diffrn_ambient_temperature     150.00(10)
_diffrn_source     'Rotating-anode X-ray tube'
_diffrn_radiation_type     MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_monochromator     mirror
_diffrn_measurement_device_type     'XtaLAB Synergy R, DW system, HyPix'
_diffrn_measurement_device     'four-circle diffractometer'
_diffrn_measurement_method     'ω scans'
_diffrn_detector     'Hybrid Pixel Array Detector'
_diffrn_detector_area_resol_mean     10.0000
_diffrn_reflns_number     77751
_diffrn_reflns_av_R_equivalents     0.0512
_diffrn_reflns_av_unetI/netI     0.0327
_diffrn_reflns_theta_min     2.346
_diffrn_reflns_theta_max     31.107
_diffrn_reflns_theta_full     25.242
_diffrn_measured_fraction_theta_max     0.845
_diffrn_measured_fraction_theta_full     0.999
_diffrn_reflns_limit_h_min     -18
_diffrn_reflns_limit_h_max     15
_diffrn_reflns_limit_k_min     -14
_diffrn_reflns_limit_k_max     14
_diffrn_reflns_limit_l_min     -43
_diffrn_reflns_limit_l_max     49
_diffrn_radiation_probe     x-ray
_refine_special_details     ?
_reflns_number_total     12895
_reflns_number_gt     10926
_reflns_threshold_expression     'I > 2σ(I)'
_refine_ls_structure_factor_coef     Fsqd
_refine_ls_matrix_type     full
_refine_ls_R_factor_all     0.0510
_refine_ls_R_factor_gt     0.0404
_refine_ls_wR_factor_gt     0.0917
_refine_ls_wR_factor_ref     0.0955
_refine_ls_goodness_of_fit_ref     1.065
_refine_ls_restrained_S_all     1.065
_refine_ls_number_reflns     12895
_refine_ls_number_parameters     586
_refine_ls_number_restraints     0
_refine_ls_hydrogen_treatment     constr
_refine_ls_weighting_scheme     calc
_refine_ls_weighting_details
              'w=1/[σ²(Fo²)+(0.0341P)²+5.9508P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_hydrogens     geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary     ?
_refine_ls_shift/su_max     0.002
_refine_ls_shift/su_mean     0.000
_refine_diff_density_max     0.900
_refine_diff_density_min     -0.782
_refine_ls_extinction_method     none
_refine_ls_extinction_coef     .
loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
    'C' 'C' 0.0033 0.0016
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'H' 'H' 0.0000 0.0000
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Ag' 'Ag' -0.8971 1.1015
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'N' 'N' 0.0061 0.0033
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'O' 'O' 0.0106 0.0060
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'P' 'P' 0.1023 0.0942
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_computing_data_collection
;
CrysAlisPro (Rigaku OD, 2022)
;
_computing_cell_refinement
;
CrysAlisPro (Rigaku OD, 2022)
;
_computing_data_reduction
;
CrysAlisPro (Rigaku OD, 2022)
;
_computing_structure_solution
;
SHELXT (Sheldrick, 2015a)
;
_computing_structure_refinement
;
SHELXL (Sheldrick, 2015b)
;
_computing_molecular_graphics
;
Olex2 (Dolomanov et al.,  2009)
;
_computing_publication_material
;
Olex2 (Dolomanov et al.,  2009)
;
loop_
    _atom_site_type_symbol
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_adp_type
    _atom_site_calc_flag
    _atom_site_occupancy
    _atom_site_disorder_assembly
    _atom_site_disorder_group
    Ag Ag1 0.74798(2) 0.69605(2) 0.37571(2) 0.02091(5) Uani d 1 . .
    P P1 0.58242(4) 0.59000(6) 0.37839(2) 0.02200(11) Uani d 1 . .
    P P2 0.83407(4) 0.68482(5) 0.31933(2) 0.02064(11) Uani d 1 . .
    P P3 0.83722(4) 0.70570(5) 0.44299(2) 0.02071(11) Uani d 1 . .
    N N1 0.72422(15) 1.0224(2) 0.36449(6) 0.0296(4) Uani d 1 . .
    C C7 0.59306(15) 0.4655(2) 0.41680(6) 0.0229(4) Uani d 1 . .
    O O2 0.70309(18) 0.9312(2) 0.34174(8) 0.0674(8) Uani d 1 . .
    C C45 0.75566(16) 0.7562(2) 0.47712(6) 0.0235(4) Uani d 1 . .
    O O3 0.7075(3) 1.1395(2) 0.35565(8) 0.0745(8) Uani d 1 . .
    C C52 0.93733(16) 0.4638(2) 0.43405(6) 0.0234(4) Uani d 1 . .
    C C20 0.95104(16) 0.7790(2) 0.32598(6) 0.0229(4) Uani d 1 . .
    C C39 0.95066(15) 0.8048(2) 0.45606(6) 0.0218(4) Uani d 1 . .
    C C26 0.86546(17) 0.5186(2) 0.30363(6) 0.0244(4) Uani d 1 . .
    C C40 0.98711(17) 0.8780(2) 0.42795(7) 0.0268(5) Uani d 1 . .
    H H40 0.9504 0.8811 0.4028 0.032 Uiso calc 1 . .
    C C8 0.62320(17) 0.3353(2) 0.41041(7) 0.0288(5) Uani d 1 . .
    H H8 0.6300 0.3083 0.3853 0.035 Uiso calc 1 . .
    C C12 0.58538(17) 0.5036(2) 0.45431(6) 0.0257(4) Uani d 1 . .
    H H12 0.5659 0.5922 0.4594 0.031 Uiso calc 1 . .
    C C32 0.77378(17) 0.7596(2) 0.27341(6) 0.0263(4) Uani d 1 . .
    H H32A 0.7634 0.8561 0.2776 0.032 Uiso calc 1 . .
    H H32B 0.8207 0.7520 0.2548 0.032 Uiso calc 1 . .
    C C27 0.8137(2) 0.4102(2) 0.31479(7) 0.0326(5) Uani d 1 . .
    H H27 0.7700 0.4221 0.3330 0.039 Uiso calc 1 . .
    C C51 0.87716(17) 0.5366(2) 0.46029(6) 0.0251(4) Uani d 1 . .
    H H51A 0.9180 0.5442 0.4860 0.030 Uiso calc 1 . .
    H H51B 0.8172 0.4828 0.4628 0.030 Uiso calc 1 . .
    C C1 0.48491(16) 0.7039(2) 0.38875(6) 0.0243(4) Uani d 1 . .
    C C25 1.04431(18) 0.7184(2) 0.33519(7) 0.0287(5) Uani d 1 . .
    H H25 1.0486 0.6241 0.3382 0.034 Uiso calc 1 . .
    C C13 0.52699(17) 0.5003(2) 0.33411(6) 0.0279(5) Uani d 1 . .
    H H13A 0.5334 0.5586 0.3120 0.034 Uiso calc 1 . .
    H H13B 0.5677 0.4193 0.3318 0.034 Uiso calc 1 . .
    C C33 0.67541(18) 0.6995(2) 0.25573(6) 0.0288(5) Uani d 1 . .
    C C14 0.41952(17) 0.4579(2) 0.33067(6) 0.0265(5) Uani d 1 . .
    C C9 0.64343(18) 0.2446(3) 0.44029(8) 0.0334(5) Uani d 1 . .
    H H9 0.6632 0.1560 0.4354 0.040 Uiso calc 1 . .
    C C21 0.94684(18) 0.9193(2) 0.32359(7) 0.0273(5) Uani d 1 . .
    H H21 0.8839 0.9630 0.3185 0.033 Uiso calc 1 . .
    C C53 1.03062(17) 0.5100(2) 0.42783(7) 0.0283(5) Uani d 1 . .
    H H53 1.0562 0.5917 0.4391 0.034 Uiso calc 1 . .
    C C57 0.90097(18) 0.3451(2) 0.41677(7) 0.0290(5) Uani d 1 . .
    H H57 0.8365 0.3145 0.4199 0.035 Uiso calc 1 . .
    C C54 1.08633(18) 0.4372(2) 0.40518(7) 0.0300(5) Uani d 1 . .
    H H54 1.1489 0.4704 0.4005 0.036 Uiso calc 1 . .
    C C44 1.00465(17) 0.8037(2) 0.49331(6) 0.0268(4) Uani d 1 . .
    H H44 0.9797 0.7556 0.5129 0.032 Uiso calc 1 . .
    C C22 1.03420(19) 0.9945(3) 0.32863(7) 0.0330(5) Uani d 1 . .
    H H22 1.0306 1.0892 0.3266 0.040 Uiso calc 1 . .
    C C31 0.93097(18) 0.4982(3) 0.27725(7) 0.0301(5) Uani d 1 . .
    H H31 0.9665 0.5718 0.2691 0.036 Uiso calc 1 . .
    C C6 0.40306(18) 0.6613(3) 0.40516(7) 0.0307(5) Uani d 1 . .
    H H6 0.3940 0.5689 0.4098 0.037 Uiso calc 1 . .
    C C46 0.67781(17) 0.8448(2) 0.46439(7) 0.0288(5) Uani d 1 . .
    H H46 0.6711 0.8810 0.4393 0.035 Uiso calc 1 . .
    C C19 0.39218(19) 0.3394(3) 0.34654(8) 0.0339(5) Uani d 1 . .
    H H19 0.4421 0.2833 0.3603 0.041 Uiso calc 1 . .
    C C50 0.76469(19) 0.7058(3) 0.51408(7) 0.0315(5) Uani d 1 . .
    H H50 0.8178 0.6463 0.5232 0.038 Uiso calc 1 . .
    C C41 1.07705(19) 0.9469(3) 0.43651(7) 0.0321(5) Uani d 1 . .
    H H41 1.1016 0.9966 0.4171 0.039 Uiso calc 1 . .
    C C5 0.33482(18) 0.7550(3) 0.41466(7) 0.0363(6) Uani d 1 . .
    H H5 0.2800 0.7264 0.4263 0.044 Uiso calc 1 . .
    C C56 0.9573(2) 0.2707(3) 0.39504(8) 0.0347(5) Uani d 1 . .
    H H56 0.9321 0.1886 0.3840 0.042 Uiso calc 1 . .
    C C2 0.49522(19) 0.8392(2) 0.38089(7) 0.0311(5) Uani d 1 . .
    H H2 0.5499 0.8687 0.3693 0.037 Uiso calc 1 . .
    C C42 1.13090(18) 0.9434(3) 0.47317(7) 0.0323(5) Uani d 1 . .
    H H42 1.1928 0.9893 0.4788 0.039 Uiso calc 1 . .
    O O1 0.7673(3) 0.9985(4) 0.39716(8) 0.0922(11) Uani d 1 . .
    C C55 1.0505(2) 0.3162(3) 0.38947(7) 0.0336(5) Uani d 1 . .
    H H55 1.0896 0.2646 0.3749 0.040 Uiso calc 1 . .
    C C38 0.5872(2) 0.7659(3) 0.25900(8) 0.0385(6) Uani d 1 . .
    H H38 0.5893 0.8438 0.2745 0.046 Uiso calc 1 . .
    C C11 0.60614(19) 0.4122(3) 0.48413(7) 0.0325(5) Uani d 1 . .
    H H11 0.6005 0.4388 0.5094 0.039 Uiso calc 1 . .
    C C43 1.09414(18) 0.8724(3) 0.50165(7) 0.0306(5) Uani d 1 . .
    H H43 1.1305 0.8711 0.5269 0.037 Uiso calc 1 . .
    C C10 0.63498(19) 0.2827(3) 0.47725(8) 0.0341(5) Uani d 1 . .
    H H10 0.6488 0.2206 0.4977 0.041 Uiso calc 1 . .
    C C23 1.1262(2) 0.9324(3) 0.33650(7) 0.0360(6) Uani d 1 . .
    H H23 1.1857 0.9839 0.3395 0.043 Uiso calc 1 . .
    C C28 0.8251(2) 0.2829(3) 0.29945(9) 0.0432(7) Uani d 1 . .
    H H28 0.7878 0.2094 0.3066 0.052 Uiso calc 1 . .
    C C48 0.61863(19) 0.8284(3) 0.52465(8) 0.0360(6) Uani d 1 . .
    H H48 0.5714 0.8520 0.5406 0.043 Uiso calc 1 . .
    C C24 1.13108(19) 0.7946(3) 0.34007(8) 0.0351(5) Uani d 1 . .
    H H24 1.1942 0.7518 0.3459 0.042 Uiso calc 1 . .
    C C15 0.3448(2) 0.5380(3) 0.31089(8) 0.0361(5) Uani d 1 . .
    H H15 0.3619 0.6201 0.3001 0.043 Uiso calc 1 . .
    C C47 0.61029(19) 0.8801(3) 0.48816(8) 0.0348(6) Uani d 1 . .
    H H47 0.5577 0.9406 0.4792 0.042 Uiso calc 1 . .
    C C30 0.9440(2) 0.3715(3) 0.26309(7) 0.0371(6) Uani d 1 . .
    H H30 0.9899 0.3580 0.2458 0.045 Uiso calc 1 . .
    C C49 0.6962(2) 0.7419(3) 0.53789(8) 0.0367(6) Uani d 1 . .
    H H49 0.7029 0.7072 0.5631 0.044 Uiso calc 1 . .
    C C29 0.8905(2) 0.2646(3) 0.27398(8) 0.0413(6) Uani d 1 . .
    H H29 0.8988 0.1782 0.2638 0.050 Uiso calc 1 . .
    C C18 0.2920(2) 0.3019(3) 0.34248(8) 0.0437(7) Uani d 1 . .
    H H18 0.2741 0.2207 0.3536 0.052 Uiso calc 1 . .
    C C17 0.2190(2) 0.3817(3) 0.32255(8) 0.0416(7) Uani d 1 . .
    H H17 0.1508 0.3556 0.3198 0.050 Uiso calc 1 . .
    C C34 0.6704(2) 0.5834(3) 0.23413(8) 0.0424(6) Uani d 1 . .
    H H34 0.7296 0.5353 0.2320 0.051 Uiso calc 1 . .
    C C16 0.2450(2) 0.4988(3) 0.30674(8) 0.0412(6) Uani d 1 . .
    H H16 0.1947 0.5538 0.2928 0.049 Uiso calc 1 . .
    C C4 0.3467(2) 0.8895(3) 0.40719(8) 0.0411(6) Uani d 1 . .
    H H4 0.3004 0.9529 0.4140 0.049 Uiso calc 1 . .
    C C3 0.4257(2) 0.9316(3) 0.38990(9) 0.0420(6) Uani d 1 . .
    H H3 0.4326 1.0236 0.3842 0.050 Uiso calc 1 . .
    C C37 0.4957(2) 0.7200(4) 0.23997(10) 0.0534(9) Uani d 1 . .
    H H37 0.4361 0.7674 0.2420 0.064 Uiso calc 1 . .
    C C36 0.4922(3) 0.6057(4) 0.21824(10) 0.0627(11) Uani d 1 . .
    H H36 0.4300 0.5741 0.2051 0.075 Uiso calc 1 . .
    C C35 0.5782(3) 0.5373(4) 0.21551(10) 0.0596(9) Uani d 1 . .
    H H35 0.5750 0.4576 0.2008 0.072 Uiso calc 1 . .
_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
    _geom_bond_atom_site_label_1
    _geom_bond_atom_site_label_2
    _geom_bond_site_symmetry_2
    _geom_bond_distance
    _geom_bond_publ_flag
    Ag1 P1 . 2.4990(6) ?
    Ag1 P2 . 2.4737(5) ?
    Ag1 P3 . 2.4964(6) ?
    Ag1 O2 . 2.667(3) ?
    Ag1 O1 . 3.118(4) ?
    P1 C1 . 1.827(2) ?
    P1 C7 . 1.833(2) ?
    P1 C13 . 1.858(2) ?
    P2 C26 . 1.824(2) ?
    P2 C20 . 1.827(2) ?
    P2 C32 . 1.857(2) ?
    P3 C39 . 1.826(2) ?
    P3 C45 . 1.836(2) ?
    P3 C51 . 1.850(2) ?
    N1 O2 . 1.221(3) ?
    N1 O3 . 1.224(3) ?
    N1 O1 . 1.233(3) ?
    C7 C8 . 1.394(3) ?
    C7 C12 . 1.403(3) ?
    C45 C50 . 1.390(3) ?
    C45 C46 . 1.396(3) ?
    C52 C57 . 1.389(3) ?
    C52 C53 . 1.397(3) ?
    C52 C51 . 1.518(3) ?
    C20 C25 . 1.393(3) ?
    C20 C21 . 1.407(3) ?
    C39 C40 . 1.390(3) ?
    C39 C44 . 1.403(3) ?
    C26 C27 . 1.383(3) ?
    C26 C31 . 1.404(3) ?
    C40 C41 . 1.391(3) ?
    C40 H40 . 0.9500 ?
    C8 C9 . 1.388(4) ?
    C8 H8 . 0.9500 ?
    C12 C11 . 1.391(3) ?
    C12 H12 . 0.9500 ?
    C32 C33 . 1.505(3) ?
    C32 H32A . 0.9900 ?
    C32 H32B . 0.9900 ?
    C27 C28 . 1.402(4) ?
    C27 H27 . 0.9500 ?
    C51 H51A . 0.9900 ?
    C51 H51B . 0.9900 ?
    C1 C2 . 1.393(3) ?
    C1 C6 . 1.400(3) ?
    C25 C24 . 1.389(3) ?
    C25 H25 . 0.9500 ?
    C13 C14 . 1.504(3) ?
    C13 H13A . 0.9900 ?
    C13 H13B . 0.9900 ?
    C33 C34 . 1.386(4) ?
    C33 C38 . 1.390(4) ?
    C14 C19 . 1.388(4) ?
    C14 C15 . 1.389(4) ?
    C9 C10 . 1.387(4) ?
    C9 H9 . 0.9500 ?
    C21 C22 . 1.390(3) ?
    C21 H21 . 0.9500 ?
    C53 C54 . 1.393(3) ?
    C53 H53 . 0.9500 ?
    C57 C56 . 1.385(3) ?
    C57 H57 . 0.9500 ?
    C54 C55 . 1.387(4) ?
    C54 H54 . 0.9500 ?
    C44 C43 . 1.385(3) ?
    C44 H44 . 0.9500 ?
    C22 C23 . 1.381(4) ?
    C22 H22 . 0.9500 ?
    C31 C30 . 1.384(4) ?
    C31 H31 . 0.9500 ?
    C6 C5 . 1.395(3) ?
    C6 H6 . 0.9500 ?
    C46 C47 . 1.386(3) ?
    C46 H46 . 0.9500 ?
    C19 C18 . 1.395(4) ?
    C19 H19 . 0.9500 ?
    C50 C49 . 1.399(3) ?
    C50 H50 . 0.9500 ?
    C41 C42 . 1.385(4) ?
    C41 H41 . 0.9500 ?
    C5 C4 . 1.385(4) ?
    C5 H5 . 0.9500 ?
    C56 C55 . 1.386(4) ?
    C56 H56 . 0.9500 ?
    C2 C3 . 1.393(4) ?
    C2 H2 . 0.9500 ?
    C42 C43 . 1.390(4) ?
    C42 H42 . 0.9500 ?
    C55 H55 . 0.9500 ?
    C38 C37 . 1.391(4) ?
    C38 H38 . 0.9500 ?
    C11 C10 . 1.385(4) ?
    C11 H11 . 0.9500 ?
    C43 H43 . 0.9500 ?
    C10 H10 . 0.9500 ?
    C23 C24 . 1.384(4) ?
    C23 H23 . 0.9500 ?
    C28 C29 . 1.375(4) ?
    C28 H28 . 0.9500 ?
    C48 C47 . 1.381(4) ?
    C48 C49 . 1.384(4) ?
    C48 H48 . 0.9500 ?
    C24 H24 . 0.9500 ?
    C15 C16 . 1.395(4) ?
    C15 H15 . 0.9500 ?
    C47 H47 . 0.9500 ?
    C30 C29 . 1.381(4) ?
    C30 H30 . 0.9500 ?
    C49 H49 . 0.9500 ?
    C29 H29 . 0.9500 ?
    C18 C17 . 1.376(4) ?
    C18 H18 . 0.9500 ?
    C17 C16 . 1.369(4) ?
    C17 H17 . 0.9500 ?
    C34 C35 . 1.395(4) ?
    C34 H34 . 0.9500 ?
    C16 H16 . 0.9500 ?
    C4 C3 . 1.383(4) ?
    C4 H4 . 0.9500 ?
    C3 H3 . 0.9500 ?
    C37 C36 . 1.375(6) ?
    C37 H37 . 0.9500 ?
    C36 C35 . 1.368(6) ?
    C36 H36 . 0.9500 ?
    C35 H35 . 0.9500 ?
loop_
    _geom_angle_atom_site_label_1
    _geom_angle_atom_site_label_2
    _geom_angle_atom_site_label_3
    _geom_angle_site_symmetry_1
    _geom_angle_site_symmetry_3
    _geom_angle
    _geom_angle_publ_flag
    P2 Ag1 P3 . . 123.634(19) ?
    P2 Ag1 P1 . . 123.727(19) ?
    P3 Ag1 P1 . . 106.310(19) ?
    C1 P1 C7 . . 104.31(10) ?
    C1 P1 C13 . . 105.23(10) ?
    C7 P1 C13 . . 105.80(11) ?
    C1 P1 Ag1 . . 115.30(8) ?
    C7 P1 Ag1 . . 110.64(7) ?
    C13 P1 Ag1 . . 114.63(7) ?
    C26 P2 C20 . . 105.56(10) ?
    C26 P2 C32 . . 101.02(10) ?
    C20 P2 C32 . . 99.02(10) ?
    C26 P2 Ag1 . . 116.82(7) ?
    C20 P2 Ag1 . . 112.65(7) ?
    C32 P2 Ag1 . . 119.40(8) ?
    C39 P3 C45 . . 104.83(10) ?
    C39 P3 C51 . . 102.82(10) ?
    C45 P3 C51 . . 102.03(10) ?
    C39 P3 Ag1 . . 121.52(7) ?
    C45 P3 Ag1 . . 112.88(7) ?
    C51 P3 Ag1 . . 110.63(8) ?
    O2 N1 O3 . . 122.1(3) ?
    O2 N1 O1 . . 120.1(3) ?
    O3 N1 O1 . . 117.8(3) ?
    C8 C7 C12 . . 118.4(2) ?
    C8 C7 P1 . . 120.24(17) ?
    C12 C7 P1 . . 120.70(17) ?
    C50 C45 C46 . . 118.8(2) ?
    C50 C45 P3 . . 123.34(17) ?
    C46 C45 P3 . . 117.77(17) ?
    C57 C52 C53 . . 118.6(2) ?
    C57 C52 C51 . . 119.4(2) ?
    C53 C52 C51 . . 121.9(2) ?
    C25 C20 C21 . . 118.3(2) ?
    C25 C20 P2 . . 122.93(17) ?
    C21 C20 P2 . . 118.70(17) ?
    C40 C39 C44 . . 119.1(2) ?
    C40 C39 P3 . . 119.10(16) ?
    C44 C39 P3 . . 121.72(17) ?
    C27 C26 C31 . . 118.8(2) ?
    C27 C26 P2 . . 118.20(17) ?
    C31 C26 P2 . . 122.59(18) ?
    C39 C40 C41 . . 120.3(2) ?
    C39 C40 H40 . . 119.8 ?
    C41 C40 H40 . . 119.8 ?
    C9 C8 C7 . . 120.9(2) ?
    C9 C8 H8 . . 119.6 ?
    C7 C8 H8 . . 119.6 ?
    C11 C12 C7 . . 120.3(2) ?
    C11 C12 H12 . . 119.8 ?
    C7 C12 H12 . . 119.8 ?
    C33 C32 P2 . . 116.14(16) ?
    C33 C32 H32A . . 108.3 ?
    P2 C32 H32A . . 108.3 ?
    C33 C32 H32B . . 108.3 ?
    P2 C32 H32B . . 108.3 ?
    H32A C32 H32B . . 107.4 ?
    C26 C27 C28 . . 120.5(2) ?
    C26 C27 H27 . . 119.7 ?
    C28 C27 H27 . . 119.7 ?
    C52 C51 P3 . . 113.11(15) ?
    C52 C51 H51A . . 109.0 ?
    P3 C51 H51A . . 109.0 ?
    C52 C51 H51B . . 109.0 ?
    P3 C51 H51B . . 109.0 ?
    H51A C51 H51B . . 107.8 ?
    C2 C1 C6 . . 119.4(2) ?
    C2 C1 P1 . . 117.77(18) ?
    C6 C1 P1 . . 122.84(18) ?
    C24 C25 C20 . . 120.7(2) ?
    C24 C25 H25 . . 119.6 ?
    C20 C25 H25 . . 119.6 ?
    C14 C13 P1 . . 117.38(16) ?
    C14 C13 H13A . . 108.0 ?
    P1 C13 H13A . . 108.0 ?
    C14 C13 H13B . . 108.0 ?
    P1 C13 H13B . . 108.0 ?
    H13A C13 H13B . . 107.2 ?
    C34 C33 C38 . . 118.7(2) ?
    C34 C33 C32 . . 121.7(2) ?
    C38 C33 C32 . . 119.5(2) ?
    C19 C14 C15 . . 118.4(2) ?
    C19 C14 C13 . . 121.8(2) ?
    C15 C14 C13 . . 119.8(2) ?
    C10 C9 C8 . . 120.3(2) ?
    C10 C9 H9 . . 119.8 ?
    C8 C9 H9 . . 119.8 ?
    C22 C21 C20 . . 120.4(2) ?
    C22 C21 H21 . . 119.8 ?
    C20 C21 H21 . . 119.8 ?
    C54 C53 C52 . . 120.5(2) ?
    C54 C53 H53 . . 119.8 ?
    C52 C53 H53 . . 119.8 ?
    C56 C57 C52 . . 121.0(2) ?
    C56 C57 H57 . . 119.5 ?
    C52 C57 H57 . . 119.5 ?
    C55 C54 C53 . . 120.0(2) ?
    C55 C54 H54 . . 120.0 ?
    C53 C54 H54 . . 120.0 ?
    C43 C44 C39 . . 120.3(2) ?
    C43 C44 H44 . . 119.9 ?
    C39 C44 H44 . . 119.9 ?
    C23 C22 C21 . . 120.4(2) ?
    C23 C22 H22 . . 119.8 ?
    C21 C22 H22 . . 119.8 ?
    C30 C31 C26 . . 120.3(2) ?
    C30 C31 H31 . . 119.8 ?
    C26 C31 H31 . . 119.8 ?
    C5 C6 C1 . . 119.8(2) ?
    C5 C6 H6 . . 120.1 ?
    C1 C6 H6 . . 120.1 ?
    C47 C46 C45 . . 120.3(2) ?
    C47 C46 H46 . . 119.8 ?
    C45 C46 H46 . . 119.8 ?
    C14 C19 C18 . . 120.5(3) ?
    C14 C19 H19 . . 119.8 ?
    C18 C19 H19 . . 119.8 ?
    C45 C50 C49 . . 120.5(2) ?
    C45 C50 H50 . . 119.7 ?
    C49 C50 H50 . . 119.7 ?
    C42 C41 C40 . . 120.2(2) ?
    C42 C41 H41 . . 119.9 ?
    C40 C41 H41 . . 119.9 ?
    C4 C5 C6 . . 120.2(3) ?
    C4 C5 H5 . . 119.9 ?
    C6 C5 H5 . . 119.9 ?
    C57 C56 C55 . . 120.0(2) ?
    C57 C56 H56 . . 120.0 ?
    C55 C56 H56 . . 120.0 ?
    C1 C2 C3 . . 120.3(3) ?
    C1 C2 H2 . . 119.9 ?
    C3 C2 H2 . . 119.9 ?
    C41 C42 C43 . . 119.9(2) ?
    C41 C42 H42 . . 120.1 ?
    C43 C42 H42 . . 120.1 ?
    C56 C55 C54 . . 119.9(2) ?
    C56 C55 H55 . . 120.1 ?
    C54 C55 H55 . . 120.1 ?
    C33 C38 C37 . . 121.0(3) ?
    C33 C38 H38 . . 119.5 ?
    C37 C38 H38 . . 119.5 ?
    C10 C11 C12 . . 120.6(2) ?
    C10 C11 H11 . . 119.7 ?
    C12 C11 H11 . . 119.7 ?
    C44 C43 C42 . . 120.2(2) ?
    C44 C43 H43 . . 119.9 ?
    C42 C43 H43 . . 119.9 ?
    C11 C10 C9 . . 119.4(2) ?
    C11 C10 H10 . . 120.3 ?
    C9 C10 H10 . . 120.3 ?
    C22 C23 C24 . . 119.7(2) ?
    C22 C23 H23 . . 120.2 ?
    C24 C23 H23 . . 120.2 ?
    C29 C28 C27 . . 119.8(3) ?
    C29 C28 H28 . . 120.1 ?
    C27 C28 H28 . . 120.1 ?
    C47 C48 C49 . . 119.7(2) ?
    C47 C48 H48 . . 120.2 ?
    C49 C48 H48 . . 120.2 ?
    C23 C24 C25 . . 120.4(2) ?
    C23 C24 H24 . . 119.8 ?
    C25 C24 H24 . . 119.8 ?
    C14 C15 C16 . . 120.6(3) ?
    C14 C15 H15 . . 119.7 ?
    C16 C15 H15 . . 119.7 ?
    C48 C47 C46 . . 120.7(2) ?
    C48 C47 H47 . . 119.6 ?
    C46 C47 H47 . . 119.6 ?
    C29 C30 C31 . . 120.2(2) ?
    C29 C30 H30 . . 119.9 ?
    C31 C30 H30 . . 119.9 ?
    C48 C49 C50 . . 119.9(2) ?
    C48 C49 H49 . . 120.0 ?
    C50 C49 H49 . . 120.0 ?
    C28 C29 C30 . . 120.3(2) ?
    C28 C29 H29 . . 119.9 ?
    C30 C29 H29 . . 119.9 ?
    C17 C18 C19 . . 120.4(3) ?
    C17 C18 H18 . . 119.8 ?
    C19 C18 H18 . . 119.8 ?
    C16 C17 C18 . . 119.6(3) ?
    C16 C17 H17 . . 120.2 ?
    C18 C17 H17 . . 120.2 ?
    C33 C34 C35 . . 119.9(3) ?
    C33 C34 H34 . . 120.0 ?
    C35 C34 H34 . . 120.0 ?
    C17 C16 C15 . . 120.5(3) ?
    C17 C16 H16 . . 119.8 ?
    C15 C16 H16 . . 119.8 ?
    C3 C4 C5 . . 120.2(2) ?
    C3 C4 H4 . . 119.9 ?
    C5 C4 H4 . . 119.9 ?
    C4 C3 C2 . . 120.1(3) ?
    C4 C3 H3 . . 120.0 ?
    C2 C3 H3 . . 120.0 ?
    C36 C37 C38 . . 119.6(3) ?
    C36 C37 H37 . . 120.2 ?
    C38 C37 H37 . . 120.2 ?
    C35 C36 C37 . . 120.1(3) ?
    C35 C36 H36 . . 119.9 ?
    C37 C36 H36 . . 119.9 ?
    C36 C35 C34 . . 120.7(3) ?
    C36 C35 H35 . . 119.6 ?
    C34 C35 H35 . . 119.6 ?
loop_
    _geom_torsion_atom_site_label_1
    _geom_torsion_atom_site_label_2
    _geom_torsion_atom_site_label_3
    _geom_torsion_atom_site_label_4
    _geom_torsion_site_symmetry_1
    _geom_torsion_site_symmetry_2
    _geom_torsion_site_symmetry_3
    _geom_torsion_site_symmetry_4
    _geom_torsion
    _geom_torsion_publ_flag
    C1 P1 C7 C8 . . . . 150.85(18) ?
    C13 P1 C7 C8 . . . . 40.1(2) ?
    Ag1 P1 C7 C8 . . . . -84.58(18) ?
    C1 P1 C7 C12 . . . . -38.5(2) ?
    C13 P1 C7 C12 . . . . -149.21(18) ?
    Ag1 P1 C7 C12 . . . . 86.08(18) ?
    C39 P3 C45 C50 . . . . -81.0(2) ?
    C51 P3 C45 C50 . . . . 25.9(2) ?
    Ag1 P3 C45 C50 . . . . 144.65(18) ?
    C39 P3 C45 C46 . . . . 102.23(19) ?
    C51 P3 C45 C46 . . . . -150.84(18) ?
    Ag1 P3 C45 C46 . . . . -32.1(2) ?
    C26 P2 C20 C25 . . . . -27.4(2) ?
    C32 P2 C20 C25 . . . . -131.61(19) ?
    Ag1 P2 C20 C25 . . . . 101.16(18) ?
    C26 P2 C20 C21 . . . . 155.82(18) ?
    C32 P2 C20 C21 . . . . 51.63(19) ?
    Ag1 P2 C20 C21 . . . . -75.59(18) ?
    C45 P3 C39 C40 . . . . -128.35(18) ?
    C51 P3 C39 C40 . . . . 125.31(18) ?
    Ag1 P3 C39 C40 . . . . 1.0(2) ?
    C45 P3 C39 C44 . . . . 54.8(2) ?
    C51 P3 C39 C44 . . . . -51.5(2) ?
    Ag1 P3 C39 C44 . . . . -175.81(15) ?
    C20 P2 C26 C27 . . . . 146.77(19) ?
    C32 P2 C26 C27 . . . . -110.5(2) ?
    Ag1 P2 C26 C27 . . . . 20.7(2) ?
    C20 P2 C26 C31 . . . . -40.9(2) ?
    C32 P2 C26 C31 . . . . 61.8(2) ?
    Ag1 P2 C26 C31 . . . . -167.02(17) ?
    C44 C39 C40 C41 . . . . 1.4(3) ?
    P3 C39 C40 C41 . . . . -175.52(18) ?
    C12 C7 C8 C9 . . . . 1.2(3) ?
    P1 C7 C8 C9 . . . . 172.02(18) ?
    C8 C7 C12 C11 . . . . -0.9(3) ?
    P1 C7 C12 C11 . . . . -171.74(18) ?
    C26 P2 C32 C33 . . . . 67.3(2) ?
    C20 P2 C32 C33 . . . . 175.23(19) ?
    Ag1 P2 C32 C33 . . . . -62.3(2) ?
    C31 C26 C27 C28 . . . . -1.2(4) ?
    P2 C26 C27 C28 . . . . 171.4(2) ?
    C57 C52 C51 P3 . . . . -118.1(2) ?
    C53 C52 C51 P3 . . . . 64.4(3) ?
    C39 P3 C51 C52 . . . . -78.03(18) ?
    C45 P3 C51 C52 . . . . 173.49(16) ?
    Ag1 P3 C51 C52 . . . . 53.16(17) ?
    C7 P1 C1 C2 . . . . 144.10(18) ?
    C13 P1 C1 C2 . . . . -104.76(19) ?
    Ag1 P1 C1 C2 . . . . 22.6(2) ?
    C7 P1 C1 C6 . . . . -33.9(2) ?
    C13 P1 C1 C6 . . . . 77.3(2) ?
    Ag1 P1 C1 C6 . . . . -155.40(17) ?
    C21 C20 C25 C24 . . . . -3.0(3) ?
    P2 C20 C25 C24 . . . . -179.79(19) ?
    C1 P1 C13 C14 . . . . -40.4(2) ?
    C7 P1 C13 C14 . . . . 69.7(2) ?
    Ag1 P1 C13 C14 . . . . -168.14(16) ?
    P2 C32 C33 C34 . . . . -81.8(3) ?
    P2 C32 C33 C38 . . . . 102.3(2) ?
    P1 C13 C14 C19 . . . . -84.4(3) ?
    P1 C13 C14 C15 . . . . 96.2(2) ?
    C7 C8 C9 C10 . . . . -0.7(4) ?
    C25 C20 C21 C22 . . . . 2.9(3) ?
    P2 C20 C21 C22 . . . . 179.77(18) ?
    C57 C52 C53 C54 . . . . -0.9(3) ?
    C51 C52 C53 C54 . . . . 176.6(2) ?
    C53 C52 C57 C56 . . . . 2.6(3) ?
    C51 C52 C57 C56 . . . . -175.0(2) ?
    C52 C53 C54 C55 . . . . -1.7(4) ?
    C40 C39 C44 C43 . . . . -1.4(3) ?
    P3 C39 C44 C43 . . . . 175.40(18) ?
    C20 C21 C22 C23 . . . . -0.8(4) ?
    C27 C26 C31 C30 . . . . -0.7(4) ?
    P2 C26 C31 C30 . . . . -172.94(19) ?
    C2 C1 C6 C5 . . . . -2.2(3) ?
    P1 C1 C6 C5 . . . . 175.73(18) ?
    C50 C45 C46 C47 . . . . -0.8(4) ?
    P3 C45 C46 C47 . . . . 176.11(19) ?
    C15 C14 C19 C18 . . . . 0.3(4) ?
    C13 C14 C19 C18 . . . . -179.2(2) ?
    C46 C45 C50 C49 . . . . 0.8(4) ?
    P3 C45 C50 C49 . . . . -175.9(2) ?
    C39 C40 C41 C42 . . . . -0.2(4) ?
    C1 C6 C5 C4 . . . . 1.3(4) ?
    C52 C57 C56 C55 . . . . -1.6(4) ?
    C6 C1 C2 C3 . . . . 1.1(4) ?
    P1 C1 C2 C3 . . . . -176.9(2) ?
    C40 C41 C42 C43 . . . . -1.0(4) ?
    C57 C56 C55 C54 . . . . -1.0(4) ?
    C53 C54 C55 C56 . . . . 2.7(4) ?
    C34 C33 C38 C37 . . . . -2.2(4) ?
    C32 C33 C38 C37 . . . . 173.8(2) ?
    C7 C12 C11 C10 . . . . 0.2(4) ?
    C39 C44 C43 C42 . . . . 0.2(4) ?
    C41 C42 C43 C44 . . . . 1.0(4) ?
    C12 C11 C10 C9 . . . . 0.2(4) ?
    C8 C9 C10 C11 . . . . 0.0(4) ?
    C21 C22 C23 C24 . . . . -1.2(4) ?
    C26 C27 C28 C29 . . . . 1.9(4) ?
    C22 C23 C24 C25 . . . . 1.0(4) ?
    C20 C25 C24 C23 . . . . 1.1(4) ?
    C19 C14 C15 C16 . . . . -0.8(4) ?
    C13 C14 C15 C16 . . . . 178.6(2) ?
    C49 C48 C47 C46 . . . . 1.0(4) ?
    C45 C46 C47 C48 . . . . -0.1(4) ?
    C26 C31 C30 C29 . . . . 1.9(4) ?
    C47 C48 C49 C50 . . . . -1.0(4) ?
    C45 C50 C49 C48 . . . . 0.1(4) ?
    C27 C28 C29 C30 . . . . -0.8(4) ?
    C31 C30 C29 C28 . . . . -1.1(4) ?
    C14 C19 C18 C17 . . . . 0.3(4) ?
    C19 C18 C17 C16 . . . . -0.2(4) ?
    C38 C33 C34 C35 . . . . 1.5(4) ?
    C32 C33 C34 C35 . . . . -174.5(3) ?
    C18 C17 C16 C15 . . . . -0.4(4) ?
    C14 C15 C16 C17 . . . . 0.9(4) ?
    C6 C5 C4 C3 . . . . 0.7(4) ?
    C5 C4 C3 C2 . . . . -1.8(4) ?
    C1 C2 C3 C4 . . . . 0.9(4) ?
    C33 C38 C37 C36 . . . . 1.4(4) ?
    C38 C37 C36 C35 . . . . 0.3(5) ?
    C37 C36 C35 C34 . . . . -1.0(5) ?
    C33 C34 C35 C36 . . . . 0.1(5) ?
loop_
    _geom_hbond_atom_site_label_D
    _geom_hbond_atom_site_label_H
    _geom_hbond_atom_site_label_A
    _geom_hbond_site_symmetry_A
    _geom_hbond_distance_DH
    _geom_hbond_distance_HA
    _geom_hbond_distance_DA
    _geom_hbond_angle_DHA
    _geom_hbond_publ_flag
    C2 H2 O2 . 0.95 2.51 3.4612(4) 175 yes
    C8 H8 O3 1_545 0.95 2.33 3.102(4) 139 yes
    C28 H28 O3 1_545 0.95 2.30 3.096(4) 141 yes
    C46 H46 O1 . 0.95 2.44 3.231(4) 141 yes
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_T_min     ?
_shelx_estimated_absorpt_T_max     ?
_shelxl_version_number        2.013
