##############################################################################
#                                                                            #
# This CIF contains the data for a data article accepted for                 #
# publication in IUCrData. It conforms to the requirements of                #
# Notes for Authors for IUCrData, and has been                               #
# peer reviewed under the auspices of IUCrData.                              #
#                                                                            #
# Full details of the Crystallographic Information File format               #
# are given in the paper "The Crystallographic Information File (CIF):       #
# a New Standard Archive File for Crystallography" by S. R. Hall, F. H.      #
# Allen and I. D. Brown [Acta Cryst. (1991), A47, 655-685].                  #
#                                                                            #
# The current version of the core CIF dictionary is obtainable from          #
# ftp://ftp.iucr.org/pub/cif_core.dic.                                       #
#                                                                            #
# Software is freely available for graphical display of the structure(s)     #
# in this CIF. For information consult the CIF software page                 #
# http://www.iucr.org/resources/cif/software.                                #
#                                                                            #
# This file may be used for bona fide research purposes within the           #
# scientific community so long as proper attribution is given to the data    # 
# article from which it was obtained.                                        #
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data_I
_database_code_depnum_ccdc_archive 'CCDC 1841174'
_audit_creation_method     'SHELXL-2014/7'
_journal_date_recd_electronic     2018-04-27
_journal_date_accepted     2018-05-03
_journal_name_full     'IUCrData'
_journal_year     2018
_journal_volume     3
_journal_issue      5
_journal_page_first     0
_journal_page_last     0
_journal_paper_category     HO
_journal_paper_doi     10.1107/S241431461800679X
_journal_coeditor_code     RZ4023
_publ_contact_author_name     'Rosenthal, Uwe'
_publ_contact_author_address
;
Leibniz-Institut für Katalyse e. V. an der Universität Rostock
Albert-Einstein-Strasse 29a
18059 Rostock
Germany
;
_publ_contact_author_email     'uwe.rosenthal@catalysis.de'
_publ_contact_author_fax     '+49 381 1281 5000'
_publ_contact_author_phone     '+49 381 1281 176'
_publ_section_title
;
1,1-Bis(diphenylphosphoryl)hydrazine
;
_publ_section_title_footnote     .
loop_
    _publ_author_name
    _publ_author_footnote
    _publ_author_address
    'Höhne, Martha' .
;
Leibniz-Institut für Katalyse e. V. an der Universität Rostock
Albert-Einstein-Strasse 29a
18059 Rostock
Germany
;
    'Aluri, Bhaskar R.' .
;
Leibniz-Institut für Katalyse e. V. an der Universität Rostock
Albert-Einstein-Strasse 29a
18059 Rostock
Germany
;
    'Spannenberg, Anke' .
;
Leibniz-Institut für Katalyse e. V. an der Universität Rostock
Albert-Einstein-Strasse 29a
18059 Rostock
Germany
;
    'Müller, Bernd H.' .
;
Leibniz-Institut für Katalyse e. V. an der Universität Rostock
Albert-Einstein-Strasse 29a
18059 Rostock
Germany
;
    'Peulecke, Normen' .
;
Leibniz-Institut für Katalyse e. V. an der Universität Rostock
Albert-Einstein-Strasse 29a
18059 Rostock
Germany
;
    'Rosenthal, Uwe' .
;
Leibniz-Institut für Katalyse e. V. an der Universität Rostock
Albert-Einstein-Strasse 29a
18059 Rostock
Germany
;
_publ_section_synopsis
;
The title compound OPPh₂---N(NH₂)-Ph₂PO contains a diphosphazane
backbone, as well as a hydrazine entity which are nearly planar.
;
_chemical_name_systematic
;
1,1-Bis(diphenylphosphoryl)hydrazine
;
_chemical_name_common     ?
_chemical_formula_moiety     'C24 H22 N2 O2 P2'
_chemical_formula_sum     'C24 H22 N2 O2 P2'
_chemical_formula_iupac     'C24 H22 N2 O2 P2'
_chemical_formula_weight     432.37
_chemical_melting_point     ?
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system     triclinic
_space_group_name_H-M_alt     'P -1'
_space_group_name_Hall     '-P 1'
loop_
    _space_group_symop_operation_xyz
    'x, y, z'
    '-x, -y, -z'
_cell_length_a     8.6901(5)
_cell_length_b     10.1547(5)
_cell_length_c     12.6282(7)
_cell_angle_alpha     71.352(4)
_cell_angle_beta     84.442(4)
_cell_angle_gamma     81.817(4)
_cell_volume     1043.56(10)
_cell_formula_units_Z     2
_cell_measurement_reflns_used     5988
_cell_measurement_theta_min     2.06
_cell_measurement_theta_max     29.68
_cell_measurement_temperature     200(2)
_exptl_crystal_description     prism
_exptl_crystal_colour     colourless
_exptl_crystal_size_max     0.50
_exptl_crystal_size_mid     0.30
_exptl_crystal_size_min     0.25
_exptl_crystal_density_diffrn     1.376
_exptl_crystal_density_meas     ?
_exptl_crystal_density_method     ?
_exptl_crystal_F_000     452
_exptl_absorpt_coefficient_mu     0.233
_exptl_absorpt_correction_type     none
_exptl_absorpt_process_details     ?
_exptl_absorpt_correction_T_min     ?
_exptl_absorpt_correction_T_max     ?
_diffrn_ambient_temperature     200(2)
_diffrn_radiation_type     MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_source     'fine-focus sealed tube'
_diffrn_radiation_monochromator     graphite
_diffrn_measurement_device_type     'Stoe IPDS II'
_diffrn_measurement_method     'ω'
_diffrn_detector_area_resol_mean     ?
_diffrn_reflns_number     15868
_diffrn_reflns_av_R_equivalents     0.0140
_diffrn_reflns_theta_min     2.132
_diffrn_reflns_theta_max     27.998
_diffrn_reflns_theta_full     25.242
_diffrn_measured_fraction_theta_max     0.998
_diffrn_measured_fraction_theta_full     0.998
_diffrn_reflns_limit_h_min     -11
_diffrn_reflns_limit_h_max     11
_diffrn_reflns_limit_k_min     -13
_diffrn_reflns_limit_k_max     13
_diffrn_reflns_limit_l_min     -16
_diffrn_reflns_limit_l_max     16
_refine_special_details     ?
_reflns_number_total     5037
_reflns_number_gt     4301
_reflns_threshold_expression     'I > 2σ(I)'
_refine_ls_structure_factor_coef     Fsqd
_refine_ls_matrix_type     full
_refine_ls_R_factor_all     0.0359
_refine_ls_R_factor_gt     0.0291
_refine_ls_wR_factor_gt     0.0786
_refine_ls_wR_factor_ref     0.0807
_refine_ls_goodness_of_fit_ref     1.053
_refine_ls_restrained_S_all     1.053
_refine_ls_number_reflns     5037
_refine_ls_number_parameters     279
_refine_ls_number_restraints     0
_refine_ls_hydrogen_treatment     mixed
_refine_ls_weighting_scheme     calc
_refine_ls_weighting_details
              'w=1/[σ²(Fo²)+(0.0504P)²+0.1335P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_hydrogens     mixed
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary     ?
_refine_ls_shift/su_max     0.001
_refine_ls_shift/su_mean     0.000
_refine_diff_density_max     0.354
_refine_diff_density_min     -0.279
_refine_ls_extinction_method     none
_refine_ls_extinction_coef     .
loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
    'C' 'C' 0.0033 0.0016
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'H' 'H' 0.0000 0.0000
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'N' 'N' 0.0061 0.0033
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'O' 'O' 0.0106 0.0060
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'P' 'P' 0.1023 0.0942
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_computing_data_collection
;
X-AREA (Stoe & Cie, 2005)
;
_computing_cell_refinement
;
X-AREA (Stoe & Cie, 2005)
;
_computing_data_reduction
;
X-AREA (Stoe & Cie, 2005)
;
_computing_structure_solution
;
SHELXS97 (Sheldrick, 2008)
;
_computing_structure_refinement
;
SHELXL2014 (Sheldrick, 2015)
;
_computing_molecular_graphics
;
XP in SHELXTL (Sheldrick, 2008)
;
_computing_publication_material
;
publCIF (Westrip, 2010)
;
loop_
    _atom_site_type_symbol
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_adp_type
    _atom_site_calc_flag
    _atom_site_occupancy
    _atom_site_disorder_assembly
    _atom_site_disorder_group
    C C1 0.89750(13) 0.48325(12) 0.26480(10) 0.0223(2) Uani d 1 . .
    C C2 0.77523(15) 0.55487(13) 0.19719(11) 0.0274(2) Uani d 1 . .
    H H2C 0.7771 0.5531 0.1223 0.033 Uiso calc 1 . .
    C C3 0.65113(16) 0.62857(15) 0.23907(12) 0.0331(3) Uani d 1 . .
    H H3 0.5681 0.6775 0.1928 0.040 Uiso calc 1 . .
    C C4 0.64754(17) 0.63124(15) 0.34843(13) 0.0349(3) Uani d 1 . .
    H H4 0.5619 0.6814 0.3771 0.042 Uiso calc 1 . .
    C C5 0.76835(17) 0.56106(16) 0.41553(12) 0.0360(3) Uani d 1 . .
    H H5 0.7660 0.5630 0.4904 0.043 Uiso calc 1 . .
    C C6 0.89352(16) 0.48747(14) 0.37381(11) 0.0308(3) Uani d 1 . .
    H H6 0.9769 0.4398 0.4201 0.037 Uiso calc 1 . .
    C C7 1.20749(13) 0.32186(12) 0.29927(10) 0.0209(2) Uani d 1 . .
    C C8 1.35584(14) 0.36535(13) 0.27120(10) 0.0258(2) Uani d 1 . .
    H H8 1.3740 0.4382 0.2037 0.031 Uiso calc 1 . .
    C C9 1.47602(14) 0.30254(14) 0.34133(12) 0.0296(3) Uani d 1 . .
    H H9 1.5761 0.3337 0.3228 0.036 Uiso calc 1 . .
    C C10 1.45090(15) 0.19430(14) 0.43856(11) 0.0296(3) Uani d 1 . .
    H H10 1.5346 0.1495 0.4854 0.036 Uiso calc 1 . .
    C C11 1.30418(16) 0.15118(14) 0.46774(11) 0.0287(3) Uani d 1 . .
    H H11 1.2871 0.0776 0.5350 0.034 Uiso calc 1 . .
    C C12 1.18228(14) 0.21521(13) 0.39899(10) 0.0245(2) Uani d 1 . .
    H H12 1.0814 0.1865 0.4197 0.029 Uiso calc 1 . .
    C C13 1.01250(14) -0.02059(12) 0.25987(10) 0.0231(2) Uani d 1 . .
    C C14 1.08887(15) -0.08649(13) 0.35836(10) 0.0266(2) Uani d 1 . .
    H H14 1.0739 -0.0463 0.4175 0.032 Uiso calc 1 . .
    C C15 1.18663(16) -0.21031(14) 0.37088(12) 0.0341(3) Uani d 1 . .
    H H15 1.2391 -0.2543 0.4381 0.041 Uiso calc 1 . .
    C C16 1.20760(17) -0.26968(15) 0.28517(14) 0.0387(3) Uani d 1 . .
    H H16 1.2745 -0.3545 0.2936 0.046 Uiso calc 1 . .
    C C17 1.13138(19) -0.20583(16) 0.18727(13) 0.0388(3) Uani d 1 . .
    H H17 1.1457 -0.2473 0.1289 0.047 Uiso calc 1 . .
    C C18 1.03422(17) -0.08176(14) 0.17395(11) 0.0318(3) Uani d 1 . .
    H H18 0.9823 -0.0382 0.1064 0.038 Uiso calc 1 . .
    C C19 0.72636(14) 0.14265(13) 0.17142(10) 0.0247(2) Uani d 1 . .
    C C20 0.64662(18) 0.02528(17) 0.20351(13) 0.0375(3) Uani d 1 . .
    H H20 0.6832 -0.0558 0.2616 0.045 Uiso calc 1 . .
    C C21 0.51300(19) 0.0271(2) 0.15020(16) 0.0476(4) Uani d 1 . .
    H H21 0.4577 -0.0525 0.1725 0.057 Uiso calc 1 . .
    C C22 0.46105(17) 0.1442(2) 0.06523(15) 0.0462(4) Uani d 1 . .
    H H22 0.3717 0.1442 0.0275 0.055 Uiso calc 1 . .
    C C23 0.53780(18) 0.26136(19) 0.03472(13) 0.0415(3) Uani d 1 . .
    H H23 0.4994 0.3428 -0.0225 0.050 Uiso calc 1 . .
    C C24 0.67102(15) 0.26122(15) 0.08710(11) 0.0305(3) Uani d 1 . .
    H H24 0.7243 0.3420 0.0653 0.037 Uiso calc 1 . .
    N N1 0.98664(11) 0.27181(10) 0.16766(8) 0.02110(19) Uani d 1 . .
    N N2 1.03825(14) 0.24976(12) 0.06221(9) 0.0270(2) Uani d 1 . .
    O O1 1.12316(11) 0.49585(9) 0.09599(7) 0.02781(19) Uani d 1 . .
    O O2 0.84523(10) 0.16030(9) 0.36001(7) 0.02361(17) Uani d 1 . .
    P P1 1.05904(3) 0.39960(3) 0.20082(2) 0.02008(8) Uani d 1 . .
    P P2 0.88965(3) 0.14098(3) 0.24925(2) 0.01921(8) Uani d 1 . .
    H H2A 1.0080(19) 0.3320(18) 0.0093(14) 0.031(4) Uiso d 1 . .
    H H2B 1.146(2) 0.2365(19) 0.0615(15) 0.042(5) Uiso d 1 . .
loop_
    _atom_site_aniso_label
    _atom_site_aniso_U_11
    _atom_site_aniso_U_22
    _atom_site_aniso_U_33
    _atom_site_aniso_U_12
    _atom_site_aniso_U_13
    _atom_site_aniso_U_23
    C1 0.0234(5) 0.0172(5) 0.0260(6) -0.0025(4) -0.0035(4) -0.0057(4)
    C2 0.0285(6) 0.0265(6) 0.0254(6) -0.0006(5) -0.0057(5) -0.0055(5)
    C3 0.0296(6) 0.0318(7) 0.0359(7) 0.0049(5) -0.0089(5) -0.0093(6)
    C4 0.0321(7) 0.0331(7) 0.0418(8) 0.0063(5) -0.0050(6) -0.0183(6)
    C5 0.0406(7) 0.0387(8) 0.0330(7) 0.0060(6) -0.0076(6) -0.0199(6)
    C6 0.0320(6) 0.0309(7) 0.0312(6) 0.0053(5) -0.0106(5) -0.0132(5)
    C7 0.0204(5) 0.0200(5) 0.0225(5) -0.0009(4) -0.0032(4) -0.0070(4)
    C8 0.0244(6) 0.0244(6) 0.0273(6) -0.0036(5) 0.0010(5) -0.0065(5)
    C9 0.0200(5) 0.0321(7) 0.0385(7) -0.0019(5) -0.0009(5) -0.0142(5)
    C10 0.0268(6) 0.0292(6) 0.0340(6) 0.0061(5) -0.0110(5) -0.0128(5)
    C11 0.0329(6) 0.0250(6) 0.0253(6) -0.0006(5) -0.0071(5) -0.0033(5)
    C12 0.0247(6) 0.0239(6) 0.0239(5) -0.0044(4) -0.0032(4) -0.0047(5)
    C13 0.0265(6) 0.0189(5) 0.0232(5) -0.0035(4) -0.0005(4) -0.0055(4)
    C14 0.0312(6) 0.0221(6) 0.0248(6) -0.0037(5) -0.0026(5) -0.0045(5)
    C15 0.0341(7) 0.0242(6) 0.0400(7) -0.0009(5) -0.0071(6) -0.0038(5)
    C16 0.0355(7) 0.0236(6) 0.0560(9) 0.0010(5) 0.0013(6) -0.0141(6)
    C17 0.0470(8) 0.0319(7) 0.0424(8) -0.0034(6) 0.0043(6) -0.0208(6)
    C18 0.0417(7) 0.0283(6) 0.0274(6) -0.0043(5) -0.0019(5) -0.0116(5)
    C19 0.0234(5) 0.0299(6) 0.0231(5) -0.0042(5) -0.0027(4) -0.0108(5)
    C20 0.0374(7) 0.0380(8) 0.0402(8) -0.0138(6) -0.0055(6) -0.0113(6)
    C21 0.0359(8) 0.0553(10) 0.0637(11) -0.0171(7) -0.0041(7) -0.0300(9)
    C22 0.0263(7) 0.0692(11) 0.0568(10) 0.0029(7) -0.0128(6) -0.0395(9)
    C23 0.0345(7) 0.0535(9) 0.0387(8) 0.0101(7) -0.0147(6) -0.0203(7)
    C24 0.0294(6) 0.0346(7) 0.0279(6) 0.0004(5) -0.0057(5) -0.0108(5)
    N1 0.0246(5) 0.0213(5) 0.0170(4) -0.0044(4) 0.0001(4) -0.0050(4)
    N2 0.0331(6) 0.0269(6) 0.0195(5) -0.0014(4) 0.0033(4) -0.0073(4)
    O1 0.0303(4) 0.0240(4) 0.0244(4) -0.0070(3) -0.0025(3) 0.0009(3)
    O2 0.0250(4) 0.0263(4) 0.0199(4) -0.0039(3) -0.0005(3) -0.0076(3)
    P1 0.02100(14) 0.01798(14) 0.01910(14) -0.00280(10) -0.00280(10)
                                                                    -0.00205(11)
    P2 0.02125(14) 0.01898(14) 0.01705(14) -0.00319(10) -0.00204(10)
                                                                    -0.00449(10)
_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
    _geom_bond_atom_site_label_1
    _geom_bond_atom_site_label_2
    _geom_bond_site_symmetry_2
    _geom_bond_distance
    _geom_bond_publ_flag
    C1 C6 . 1.3879(17) ?
    C1 C2 . 1.3948(17) ?
    C1 P1 . 1.7957(12) ?
    C2 C3 . 1.3841(19) ?
    C2 H2C . 0.9500 ?
    C3 C4 . 1.387(2) ?
    C3 H3 . 0.9500 ?
    C4 C5 . 1.379(2) ?
    C4 H4 . 0.9500 ?
    C5 C6 . 1.3887(19) ?
    C5 H5 . 0.9500 ?
    C6 H6 . 0.9500 ?
    C7 C12 . 1.3959(16) ?
    C7 C8 . 1.3987(16) ?
    C7 P1 . 1.7961(12) ?
    C8 C9 . 1.3821(18) ?
    C8 H8 . 0.9500 ?
    C9 C10 . 1.384(2) ?
    C9 H9 . 0.9500 ?
    C10 C11 . 1.3848(19) ?
    C10 H10 . 0.9500 ?
    C11 C12 . 1.3857(17) ?
    C11 H11 . 0.9500 ?
    C12 H12 . 0.9500 ?
    C13 C14 . 1.3916(17) ?
    C13 C18 . 1.3988(17) ?
    C13 P2 . 1.7994(12) ?
    C14 C15 . 1.3866(19) ?
    C14 H14 . 0.9500 ?
    C15 C16 . 1.384(2) ?
    C15 H15 . 0.9500 ?
    C16 C17 . 1.383(2) ?
    C16 H16 . 0.9500 ?
    C17 C18 . 1.385(2) ?
    C17 H17 . 0.9500 ?
    C18 H18 . 0.9500 ?
    C19 C24 . 1.3890(18) ?
    C19 C20 . 1.3916(18) ?
    C19 P2 . 1.7980(12) ?
    C20 C21 . 1.393(2) ?
    C20 H20 . 0.9500 ?
    C21 C22 . 1.377(3) ?
    C21 H21 . 0.9500 ?
    C22 C23 . 1.375(3) ?
    C22 H22 . 0.9500 ?
    C23 C24 . 1.3875(19) ?
    C23 H23 . 0.9500 ?
    C24 H24 . 0.9500 ?
    N1 N2 . 1.4391(13) ?
    N1 P2 . 1.6769(10) ?
    N1 P1 . 1.6989(10) ?
    N2 H2A . 0.909(17) ?
    N2 H2B . 0.927(19) ?
    O1 P1 . 1.4843(9) ?
    O2 P2 . 1.4810(8) ?
loop_
    _geom_angle_atom_site_label_1
    _geom_angle_atom_site_label_2
    _geom_angle_atom_site_label_3
    _geom_angle_site_symmetry_1
    _geom_angle_site_symmetry_3
    _geom_angle
    _geom_angle_publ_flag
    C6 C1 C2 . . 119.31(11) ?
    C6 C1 P1 . . 123.61(9) ?
    C2 C1 P1 . . 116.94(9) ?
    C3 C2 C1 . . 120.08(12) ?
    C3 C2 H2C . . 120.0 ?
    C1 C2 H2C . . 120.0 ?
    C2 C3 C4 . . 120.20(12) ?
    C2 C3 H3 . . 119.9 ?
    C4 C3 H3 . . 119.9 ?
    C5 C4 C3 . . 119.98(13) ?
    C5 C4 H4 . . 120.0 ?
    C3 C4 H4 . . 120.0 ?
    C4 C5 C6 . . 120.07(13) ?
    C4 C5 H5 . . 120.0 ?
    C6 C5 H5 . . 120.0 ?
    C1 C6 C5 . . 120.35(12) ?
    C1 C6 H6 . . 119.8 ?
    C5 C6 H6 . . 119.8 ?
    C12 C7 C8 . . 119.26(11) ?
    C12 C7 P1 . . 122.47(9) ?
    C8 C7 P1 . . 118.17(9) ?
    C9 C8 C7 . . 120.17(12) ?
    C9 C8 H8 . . 119.9 ?
    C7 C8 H8 . . 119.9 ?
    C8 C9 C10 . . 120.14(12) ?
    C8 C9 H9 . . 119.9 ?
    C10 C9 H9 . . 119.9 ?
    C9 C10 C11 . . 120.20(12) ?
    C9 C10 H10 . . 119.9 ?
    C11 C10 H10 . . 119.9 ?
    C10 C11 C12 . . 120.08(12) ?
    C10 C11 H11 . . 120.0 ?
    C12 C11 H11 . . 120.0 ?
    C11 C12 C7 . . 120.12(11) ?
    C11 C12 H12 . . 119.9 ?
    C7 C12 H12 . . 119.9 ?
    C14 C13 C18 . . 119.11(12) ?
    C14 C13 P2 . . 117.92(9) ?
    C18 C13 P2 . . 122.96(10) ?
    C15 C14 C13 . . 120.55(12) ?
    C15 C14 H14 . . 119.7 ?
    C13 C14 H14 . . 119.7 ?
    C16 C15 C14 . . 119.83(13) ?
    C16 C15 H15 . . 120.1 ?
    C14 C15 H15 . . 120.1 ?
    C17 C16 C15 . . 120.17(13) ?
    C17 C16 H16 . . 119.9 ?
    C15 C16 H16 . . 119.9 ?
    C16 C17 C18 . . 120.31(13) ?
    C16 C17 H17 . . 119.8 ?
    C18 C17 H17 . . 119.8 ?
    C17 C18 C13 . . 120.02(13) ?
    C17 C18 H18 . . 120.0 ?
    C13 C18 H18 . . 120.0 ?
    C24 C19 C20 . . 119.65(12) ?
    C24 C19 P2 . . 121.71(10) ?
    C20 C19 P2 . . 118.42(10) ?
    C19 C20 C21 . . 119.81(15) ?
    C19 C20 H20 . . 120.1 ?
    C21 C20 H20 . . 120.1 ?
    C22 C21 C20 . . 120.01(15) ?
    C22 C21 H21 . . 120.0 ?
    C20 C21 H21 . . 120.0 ?
    C23 C22 C21 . . 120.35(14) ?
    C23 C22 H22 . . 119.8 ?
    C21 C22 H22 . . 119.8 ?
    C22 C23 C24 . . 120.31(15) ?
    C22 C23 H23 . . 119.8 ?
    C24 C23 H23 . . 119.8 ?
    C23 C24 C19 . . 119.85(14) ?
    C23 C24 H24 . . 120.1 ?
    C19 C24 H24 . . 120.1 ?
    N2 N1 P2 . . 111.01(7) ?
    N2 N1 P1 . . 118.03(8) ?
    P2 N1 P1 . . 129.68(6) ?
    N1 N2 H2A . . 105.2(10) ?
    N1 N2 H2B . . 105.7(11) ?
    H2A N2 H2B . . 108.7(15) ?
    O1 P1 N1 . . 107.98(5) ?
    O1 P1 C1 . . 112.80(6) ?
    N1 P1 C1 . . 105.50(5) ?
    O1 P1 C7 . . 111.04(5) ?
    N1 P1 C7 . . 109.40(5) ?
    C1 P1 C7 . . 109.90(5) ?
    O2 P2 N1 . . 110.58(5) ?
    O2 P2 C19 . . 113.78(5) ?
    N1 P2 C19 . . 105.17(5) ?
    O2 P2 C13 . . 112.32(5) ?
    N1 P2 C13 . . 107.58(5) ?
    C19 P2 C13 . . 106.97(6) ?
loop_
    _geom_torsion_atom_site_label_1
    _geom_torsion_atom_site_label_2
    _geom_torsion_atom_site_label_3
    _geom_torsion_atom_site_label_4
    _geom_torsion_site_symmetry_1
    _geom_torsion_site_symmetry_2
    _geom_torsion_site_symmetry_3
    _geom_torsion_site_symmetry_4
    _geom_torsion
    _geom_torsion_publ_flag
    C6 C1 C2 C3 . . . . -0.35(19) ?
    P1 C1 C2 C3 . . . . -176.26(10) ?
    C1 C2 C3 C4 . . . . -0.2(2) ?
    C2 C3 C4 C5 . . . . 0.4(2) ?
    C3 C4 C5 C6 . . . . -0.1(2) ?
    C2 C1 C6 C5 . . . . 0.6(2) ?
    P1 C1 C6 C5 . . . . 176.27(11) ?
    C4 C5 C6 C1 . . . . -0.4(2) ?
    C12 C7 C8 C9 . . . . 0.39(18) ?
    P1 C7 C8 C9 . . . . -176.16(9) ?
    C7 C8 C9 C10 . . . . 1.34(19) ?
    C8 C9 C10 C11 . . . . -1.92(19) ?
    C9 C10 C11 C12 . . . . 0.75(19) ?
    C10 C11 C12 C7 . . . . 0.99(19) ?
    C8 C7 C12 C11 . . . . -1.55(18) ?
    P1 C7 C12 C11 . . . . 174.85(9) ?
    C18 C13 C14 C15 . . . . 0.72(19) ?
    P2 C13 C14 C15 . . . . -179.18(10) ?
    C13 C14 C15 C16 . . . . -0.5(2) ?
    C14 C15 C16 C17 . . . . 0.0(2) ?
    C15 C16 C17 C18 . . . . 0.3(2) ?
    C16 C17 C18 C13 . . . . -0.2(2) ?
    C14 C13 C18 C17 . . . . -0.4(2) ?
    P2 C13 C18 C17 . . . . 179.52(11) ?
    C24 C19 C20 C21 . . . . 0.6(2) ?
    P2 C19 C20 C21 . . . . 175.37(12) ?
    C19 C20 C21 C22 . . . . 0.7(2) ?
    C20 C21 C22 C23 . . . . -1.9(2) ?
    C21 C22 C23 C24 . . . . 1.9(2) ?
    C22 C23 C24 C19 . . . . -0.6(2) ?
    C20 C19 C24 C23 . . . . -0.7(2) ?
    P2 C19 C24 C23 . . . . -175.25(10) ?
    N2 N1 P1 O1 . . . . 18.81(10) ?
    P2 N1 P1 O1 . . . . -175.40(7) ?
    N2 N1 P1 C1 . . . . 139.66(9) ?
    P2 N1 P1 C1 . . . . -54.55(9) ?
    N2 N1 P1 C7 . . . . -102.16(9) ?
    P2 N1 P1 C7 . . . . 63.63(9) ?
    C6 C1 P1 O1 . . . . -123.31(11) ?
    C2 C1 P1 O1 . . . . 52.41(11) ?
    C6 C1 P1 N1 . . . . 119.04(11) ?
    C2 C1 P1 N1 . . . . -65.25(10) ?
    C6 C1 P1 C7 . . . . 1.19(12) ?
    C2 C1 P1 C7 . . . . 176.91(9) ?
    C12 C7 P1 O1 . . . . -172.27(9) ?
    C8 C7 P1 O1 . . . . 4.17(11) ?
    C12 C7 P1 N1 . . . . -53.18(11) ?
    C8 C7 P1 N1 . . . . 123.26(9) ?
    C12 C7 P1 C1 . . . . 62.22(11) ?
    C8 C7 P1 C1 . . . . -121.35(10) ?
    N2 N1 P2 O2 . . . . 176.63(8) ?
    P1 N1 P2 O2 . . . . 10.06(10) ?
    N2 N1 P2 C19 . . . . -60.13(9) ?
    P1 N1 P2 C19 . . . . 133.29(8) ?
    N2 N1 P2 C13 . . . . 53.64(9) ?
    P1 N1 P2 C13 . . . . -112.94(8) ?
    C24 C19 P2 O2 . . . . 99.51(11) ?
    C20 C19 P2 O2 . . . . -75.13(12) ?
    C24 C19 P2 N1 . . . . -21.65(12) ?
    C20 C19 P2 N1 . . . . 163.71(11) ?
    C24 C19 P2 C13 . . . . -135.85(10) ?
    C20 C19 P2 C13 . . . . 49.51(12) ?
    C14 C13 P2 O2 . . . . -18.63(11) ?
    C18 C13 P2 O2 . . . . 161.48(10) ?
    C14 C13 P2 N1 . . . . 103.29(10) ?
    C18 C13 P2 N1 . . . . -76.60(11) ?
    C14 C13 P2 C19 . . . . -144.15(10) ?
    C18 C13 P2 C19 . . . . 35.95(12) ?
loop_
    _geom_hbond_atom_site_label_D
    _geom_hbond_atom_site_label_H
    _geom_hbond_atom_site_label_A
    _geom_hbond_site_symmetry_A
    _geom_hbond_distance_DH
    _geom_hbond_distance_HA
    _geom_hbond_distance_DA
    _geom_hbond_angle_DHA
    N2 H2A O1 2_765 0.909(17) 2.089(18) 2.9737(15) 164.0(14)
